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亚膦酸三(1,1,1,3,3,3-六氟-2-丙基)酯

亚膦酸三(1,1,1,3,3,3-六氟-2-丙基)酯名称

[ CAS 号 ]:
66470-81-3

[ 中文名 ]:
三(1,1,1,3,3,3-六氟-2-丙基)亚磷酸

[ 英文名 ]:
tris(1,1,1,3,3,3-hexafluoro-2-propyl) phosphite

[中文别名 ]:

三(2H-全氟-2-丙基)亚磷酸酯

[英文别名 ]:

[(CF3)2CHO]3P
tris(1,1,1,3,3,3-hexafluoroisopropyl)phosphite
MFCD00192561
P(OiC3HF6)3
Tris(1,1,1,3,3,3-hexafluoro-2-propyl)phosphite

亚膦酸三(1,1,1,3,3,3-六氟-2-丙基)酯物理化学性质

[ 密度 ]:
1.69 g/mL at 25ºC(lit.)

[ 沸点 ]:
130ºC(lit.)

[ 分子式 ]:
C₉H₃F₁₈O₃P

[ 分子量 ]:
532.06300

[ 闪点 ]:
44.5ºC

[ 精确质量 ]:
531.95300

[ PSA ]:
41.28000

[ LogP ]:
6.74270

[ 折射率 ]:
n20/D 1.300(lit.)

[ 储存条件 ]:
室温，干燥

亚膦酸三(1,1,1,3,3,3-六氟-2-丙基)酯安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H315-H319-H335

[ 警示性声明 ]:
P261-P305 + P351 + P338

[ 个人防护装备 ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
Xi

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
S26;S36

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
3

[ 海关编码 ]:
2920901900

亚膦酸三(1,1,1,3,3,3-六氟-2-丙基)酯合成路线

详细合成路线

亚膦酸三(1,1,1,3,3,3-六氟-2-丙基)酯上下游产品

亚膦酸三(1,1,1,3,3,3-六氟-2-丙基)酯上游产品

亚膦酸三(1,1,1,3,3,3-六氟-2-丙基)酯下游产品

亚膦酸三(1,1,1,3,3,3-六氟-2-丙基)酯海关

[ 海关编码 ]: 2920901900

[ 中文概述 ]:
2920901900 亚磷酸酯。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:6.5%。普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2920901900 VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

亚膦酸三(1,1,1,3,3,3-六氟-2-丙基)酯文献

Solid phase synthesis of oligoribonucleotides using the 1-[(2-chloro-4-methyl)phenyl]-4-methoxypiperidin-4-yl (Ctmp) group for the protection of the 2'-hydroxy functions and the H-phosphonate approach.

Nucleic Acids Res. 17(10) , 3689-97, (1989)

The solid phase synthesis of oligoribonucleotides using the H-phosphonate approach and the 1-[(2-chloro-4-methyl)phenyl]-4-methoxypiperidin-4-yl (Ctmp) and dimethoxytrityl (DMTr) groups, respectively,...

Use of new phosphonylating and coupling agents in the synthesis of oligodeoxyribonucleotides via the H-phosphonate approach.

Nucleic Acids Res. 18(11) , 3327-31, (1990)

New phosphonylating and coupling agents for the synthesis of oligodeoxyribonucleotides via H-phosphonate approach have been developed. Tris(1,1,1,3,3,3-hexafluoro-2-propyl) phosphite, prepared by the ...

Stereoselective propargylation mediated by a chiral metal cluster: reactions of [(propargylium)Co₂ (CO)₅{P(OR)₃}][BF₄] with carbon nucleophiles. Caffyn AJM and Nicholas KM.

J. Am. Chem. Soc. 115(14) , 6438-6439, (1993)

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