六氟丙酮
六氟丙酮用途
用于医药、农药和有机化学品的合成
【用途二】
主要用作有机溶剂，与环氯乙烷共聚可得到耐高温、耐腐蚀涂料及粘着剂。还是合成医药、农药、高分子材料及有机化学品的原料。
六氟丙酮名称
[ CAS 号 ]:
684-16-2
[ 中文名 ]:
六氟丙酮
[ 英文名 ]:
Hexafluoroacetone
[英文别名 ]:
- Perfluoroacetone
- 1,1,1,3,3,3-hexafluoro-2-propanone
- 1,1,1,3,3,3-Hexafluoroacetone
- 2-Propanone, 1,1,1,3,3,3-hexafluoro-
- GC 7887
- 1,1,1,3,3,3-hexafluoropropan-2-one
- 2-Propanone,1,1,1,3,3,3-hexafluoro
- EINECS 211-676-3
- tri-fluoromethyl ketone
- Hexafluoroacetone
六氟丙酮物理化学性质
[ 密度 ]:
1.5±0.1 g/cm3
[ 沸点 ]:
-28.0±0.0 °C at 760 mmHg
[ 熔点 ]:
−129 °C(lit.)
[ 分子式 ]:
C3F6O
[ 分子量 ]:
166.022
[ 闪点 ]:
-23.6±20.1 °C
[ 精确质量 ]:
165.985336
[ PSA ]:
17.07000
[ LogP ]:
1.89
[ 外观性状 ]:
通常在压力下作为液体供应
[ 蒸汽密度 ]:
1.65 (vs air)
[ 蒸汽压 ]:
5006.3±0.1 mmHg at 25°C
[ 折射率 ]:
1.248
[ 储存条件 ]:
库房通风低温干燥,与氧化剂,及食品分开储运
六氟丙酮MSDS
六氟丙酮毒性和生态
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- UC2450000
- CHEMICAL NAME :
- 2-Propanone, 1,1,1,3,3,3-hexafluoro-
- CAS REGISTRY NUMBER :
- 684-16-2
- LAST UPDATED :
- 199712
- DATA ITEMS CITED :
- 20
- MOLECULAR FORMULA :
- C3-F6-O
- MOLECULAR WEIGHT :
- 166.03
- WISWESSER LINE NOTATION :
- FXFFVXFFF
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 191 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 6,341,1964
- TYPE OF TEST :
- LC50 - Lethal concentration, 50 percent kill
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 275 ppm/3H
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 6,341,1964 ** REPRODUCTIVE DATA **
- TYPE OF TEST :
- TCLo - Lowest published toxic concentration
- ROUTE OF EXPOSURE :
- Inhalation
- DOSE :
- 12 ppm/6H
- SEX/DURATION :
- male 30 day(s) pre-mating
- TOXIC EFFECTS :
- Reproductive - Paternal Effects - spermatogenesis (incl. genetic material, sperm morphology, motility, and count) Reproductive - Paternal Effects - testes, epididymis, sperm duct
- REFERENCE :
- TXCYAC Toxicology. (Elsevier Scientific Pub. Ireland, Ltd., POB 85, Limerick, Ireland) V.1- 1973- Volume(issue)/page/year: 67,249,1991
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Administration onto the skin
- DOSE :
- 100 mg/kg
- SEX/DURATION :
- female 6-15 day(s) after conception
- TOXIC EFFECTS :
- Reproductive - Fertility - post-implantation mortality (e.g. dead and/or resorbed implants per total number of implants)
- REFERENCE :
- FAATDF Fundamental and Applied Toxicology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1981- Volume(issue)/page/year: 2,73,1982
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Administration onto the skin
- DOSE :
- 55 mg/kg
- SEX/DURATION :
- female 6-16 day(s) after conception
- REFERENCE :
- TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 41,195,1977 *** REVIEWS *** ACGIH TLV-TWA 0.68 mg/m3 (0.1 ppm) (skin) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 0.1 ppm (0.7 mg/m3) DTLWS* "Documentation of the Threshold Limit Values for Substances in Workroom Air," Supplements. For publisher information, see 85INA8. Volume(issue)/page/year: 3,20,1973 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 0.1 ppm (0.7 mg/m3);Skin JAN 1993 OEL-BELGIUM:TWA 0.1 ppm (0.68 mg/m3);Skin JAN 1993 OEL-DENMARK:TWA 0.1 ppm (0.7 mg/m3) JAN 1993 OEL-FINLAND:TWA 0.1 ppm (0.7 mg/m3);STEL 0.3 ppm (2.1 mg/m3) JAN 1993 OEL-FRANCE:TWA 0.1 ppm (0.7 mg/m3) JAN 1993 OEL-THE NETHERLANDS:TWA 0.1 ppm (0.7 mg/m3) JAN 1993 OEL-SWITZERLAND:TWA 0.1 ppm (0.7 mg/m3);Skin JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO HEXAFLUOROACETONE-air:10H TWA 0.1 ppm (Sk) REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992 NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 83899 No. of Facilities: 14 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 141 (estimated)
六氟丙酮安全信息
[ 危害码 (欧洲) ]:
T:Toxic;
[ 风险声明 (欧洲) ]:
R60;R14;R23/24/25;R34;R63
[ 安全声明 (欧洲) ]:
S53-S26-S28-S36-S45-S7/9
[ 危险品运输编码 ]:
UN 2420 2.3
[ WGK德国 ]:
3
[ RTECS号 ]:
UC2450000
[ 危险类别 ]:
2.3
[ 海关编码 ]:
2914700090
六氟丙酮合成路线
六氟丙酮上下游产品
六氟丙酮上游产品
六氟丙酮下游产品
六氟丙酮制备
1.由全氟异丁烯经高锰酸钾氧化而得。全氟异丁烯由四氟乙烯裂解制得，氧化反应结束后，将温度降至30℃以下。所得产物经粗馏与钾盐分离，塔顶可得30%左右的全氟丙酮水合物，经粗馏可得95%以上的产品。
2.以六氟环氧丙烷在Sb2O5催化剂存在下，在＜200℃和0.103-14.179MPa下，进行异构化制取。
六氟丙酮海关
[ 海关编码 ]: 2914700090
[ 中文概述 ]:
2914700090 其他酮及醌的卤化、磺化衍生物（包括硝化和亚硝化衍生物）. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:5.5% 普通关税:30.0%
[ 申报要素 ]: 品名, 成分含量, 用途, 丙酮报明包装
[ Summary ]:
HS: 2914700090 halogenated, sulphonated, nitrated or nitrosated derivatives of ketones and quinones, whether or not with other oxygen function Tax rebate rate:9.0% Supervision conditions:none VAT:17.0% MFN tariff:5.5% General tariff:30.0%
推荐生产厂家/供应商：
公司名：上海阿拉丁生化科技股份有限公司
区域：上海市浦东新区
价格：
￥9650.0/25g
￥需询单/1g
￥需询单/1g
￥需询单/1g
联系人：阿拉丁李高志
产品详情：无水六氟丙酮
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相关化合物
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