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4-甲基噻唑

4-甲基噻唑用途

【用途一】
用作医药、香料中间体
【用途二】
医药、香料中间体。

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4-甲基噻唑名称

[ CAS 号 ]:
693-95-8

[ 中文名 ]:
4-甲基噻唑

[ 英文名 ]:
4-Methylthiazole

[中文别名 ]:

(1Α,3Α,5Α)-1,3,5-环己三腈

[英文别名 ]:

EINECS 211-764-1
MFCD00005340
4-Methyl-1,3-thiazole
4-Methylthiazole
Thiazole, 4-methyl-
T5N CSJ E1
4-Methyl thiazole
4 METHYL THIAZOLE

4-甲基噻唑物理化学性质

[ 密度 ]:
1.1±0.1 g/cm3

[ 沸点 ]:
134.3±9.0 °C at 760 mmHg

[ 分子式 ]:
C₄H₅NS

[ 分子量 ]:
99.154

[ 闪点 ]:
37.3±6.8 °C

[ 精确质量 ]:
99.014267

[ PSA ]:
41.13000

[ LogP ]:
0.90

[ 外观性状 ]:
透明无色至略黄色液体

[ 蒸汽压 ]:
10.0±0.2 mmHg at 25°C

[ 折射率 ]:
1.536

[ 储存条件 ]:
Flammables area

4-甲基噻唑MSDS

详细MSDS(安全技术说明书)

4-甲基噻唑毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: XJ5096000

CHEMICAL NAME :: Thiazole, 4-methyl-

CAS REGISTRY NUMBER :: 693-95-8

BEILSTEIN REFERENCE NO. :: 0105228

LAST UPDATED :: 199701

DATA ITEMS CITED :: 2

MOLECULAR FORMULA :: C4-H5-N-S

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 360 uL/kg

TOXIC EFFECTS :: Sense Organs and Special Senses (Eye) - ptosis Behavioral - altered sleep time (including change in righting reflex) Behavioral - ataxia

REFERENCE :: ATDAEI Acute Toxicity Data. Journal of the American College of Toxicology, Part B. (Mary Ann Liebert, Inc., 1651 Third Ave., New York, NY 10128) V.1- 1990- Volume(issue)/page/year: 1,182,1992

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4-甲基噻唑安全信息

[ 符号 ]:

GHS02, GHS05, GHS07

[ 信号词 ]:
Danger

[ 危害声明 ]:
H226-H302-H315-H318-H335

[ 警示性声明 ]:
P261-P280-P305 + P351 + P338

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
Xn:Harmful

[ 风险声明 (欧洲) ]:
R10;R22

[ 安全声明 (欧洲) ]:
S16-S26-S39

[ 危险品运输编码 ]:
UN 1993 3/PG 3

[ WGK德国 ]:
3

[ RTECS号 ]:
XJ5096000

[ 包装等级 ]:
III

[ 危险类别 ]:
3

[ 海关编码 ]:
2934100090

4-甲基噻唑上下游产品

4-甲基噻唑上游产品

4-甲基噻唑下游产品

4-甲基噻唑海关

[ 海关编码 ]: 2934100090

[ 中文概述 ]:
2934100090. 结构上含有一个非稠合噻唑环的化合物(不论是否氢化). 增值税率:17.0%. 退税率:9.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2934100090 other compounds containing an unfused thiazole ring (whether or not hydrogenated) in the structure VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%

4-甲基噻唑文献

Enzymatic assembly of epothilones: the EpoC subunit and reconstitution of the EpoA-ACP/B/C polyketide and nonribosomal peptide interfaces.

Biochemistry 41(17) , 5685-94, (2002)

The biosynthesis of epothilones, a family of hybrid polyketide (PK)/nonribosomal peptide (NRP) antitumor agents, provides an ideal system to study a hybrid PK/NRP natural product with significant biom...

Enhanced expression of rat hepatic microsomal epoxide hydrolase by methylthiazole in conjunction with liver injury.

Toxicology 146(2-3) , 111-22, (2000)

Microsomal epoxide hydrolase (mEH) is inducible by a number of xenobiotics. Induction of mEH by certain chemopreventive agents may implicate the protective effect. In contrast, many of carcinogenic ag...

Synthesis and pharmacological evaluation of a novel series of 3-aryl-2-(2-substituted-4-methylthiazole-5-yl)thiazolidin-4-one as possible anti-inflammatory and antimicrobial agents.

Bioorg. Med. Chem. Lett. 22(20) , 6373-6, (2012)

A new series of 3-aryl-2-(2-aryl/benzyl-4-methylthiazole-5-yl)thiazolidin-4-one was synthesized by condensation of 2-aryl/benzyl-4-methylthiazole-5-carbaldehyde, aromatic amines and thioglycolic acid ...

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