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铊用途

【用途一】
供提纯、制造合金,化学试剂,仪表及半导体掺杂等工业用。
【用途二】
用于ICP-AES、AAS、AFS、ICP-MS、离子色谱等。滴定分析用标准溶液。
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铊名称

[ CAS 号 ]:
7440-28-0

[ 中文名 ]:
硫酸铊

[ 英文名 ]:
thallium

[中文别名 ]:

[英文别名 ]:

铊物理化学性质

[ 密度 ]:
1.01 g/mL at 25 °C

[ 沸点 ]:
1457 °C(lit.)

[ 熔点 ]:
303 °C(lit.)

[ 分子式 ]:
Tl

[ 分子量 ]:
204.38300

[ 精确质量 ]:
204.97400

[ 外观性状 ]:
银色-灰色金属,在空气中锈蚀很快

[ 储存条件 ]:
库房通风低温干燥,与碱、酸类、食品添加剂分开存放

[ 稳定性 ]:
Stable.

铊MSDS

铊毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :
XG3425000
CHEMICAL NAME :
Thallium
CAS REGISTRY NUMBER :
7440-28-0
LAST UPDATED :
199712
DATA ITEMS CITED :
29
MOLECULAR FORMULA :
Tl
MOLECULAR WEIGHT :
204.37
WISWESSER LINE NOTATION :
.TL

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Human - man
DOSE/DURATION :
5714 ug/kg
TOXIC EFFECTS :
Peripheral Nerve and Sensation - structural change in nerve or sheath Sense Organs and Special Senses (Eye) - changes in extra-ocular muscles Skin and Appendages - hair
REFERENCE :
ATXKA8 Archiv fuer Toxikologie. (Berlin, Fed. Rep. Ger.) V.15-31, 1954-74. For publisher information, see ARTODN. Volume(issue)/page/year: 19,65,1961
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Unreported
SPECIES OBSERVED :
Human - man
DOSE/DURATION :
4412 ug/kg
REFERENCE :
85DCAI "Poisoning; Toxicology, Symptoms, Treatments," 2nd ed., Arena, J.M., Springfield, IL, C.C. Thomas, 1970 Volume(issue)/page/year: 2,73,1970 *** REVIEWS *** ACGIH TLV-TWA 0.1 mg/m3 (skin) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 0.1 mg/m3 (skin) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,256,1971 OSHA PEL (Gen Indu):8H TWA 0.1 mg(Tl)/m3 (skin) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 0.1 mg(Tl)/m3 (skin) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 0.1 mg(Tl)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 0.1 mg(Tl)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 0.1 mg/m3;Skin JAN 1993 OEL-BELGIUM:TWA 0.1 mg/m3;Skin JAN 1993 OEL-DENMARK:TWA 0.1 mg/m3;Skin JAN 1993 OEL-FINLAND:TWA 0.1 mg/m3;Skin JAN 1993 OEL-FRANCE:TWA 0.1 mg/m3 JAN 1993 OEL-GERMANY:TWA 0.1 mg/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 0.1 mg/m3;Skin JAN 1993 OEL-THE PHILIPPINES:TWA 0.1 mg/m3;Skin JAN 1993 OEL-SWITZERLAND:TWA 0.1 mg/m3;Skin JAN 1993 OEL-THAILAND:TWA 0.1 mg/m3 JAN 1993 OEL-TURKEY:TWA 0.1 mg/m3;Skin JAN 1993 OEL-UNITED KINGDOM:TWA 0.1 mg/m3;Skin JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO THALLIUM, soluble compounds-air:10H TWA 0.1 mg/m3 (Sk) REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992 NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X3172 No. of Facilities: 158 (estimated) No. of Industries: 3 No. of Occupations: 5 No. of Employees: 1662 (estimated) No. of Female Employees: 1308 (estimated)
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铊安全信息

[ 符号 ]:

GHS06, GHS08

[ 信号词 ]:
Danger

[ 危害声明 ]:
H300 + H330-H373-H413

[ 警示性声明 ]:
P260-P264-P284-P301 + P310-P310

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ 危害码 (欧洲) ]:
Xn,T+

[ 风险声明 (欧洲) ]:
26/28-33-53-36/37/38-20/22-36/38

[ 安全声明 (欧洲) ]:
S13-S28-S45-S61-S36/37/39-S36/37-S26

[ 危险品运输编码 ]:
UN 3288 6.1/PG 2

[ WGK德国 ]:
3

[ RTECS号 ]:
XG3425000

[ 包装等级 ]:
II

[ 危险类别 ]:
6.1

铊制备

【方法一】
工业上制造铊的原料除铊矿石外,尚利用处理铝、锌、铜、锰等金属冶炼过程的副产品作为原料,经湿法冶炼制得金属铊。
湿法将有色金属冶炼过程的副产品作为原料,加入硫酸进行抽提时生成硫酸铊,再用锌粉制成海绵状铊,加入硫酸溶解海绵铊,加入碳酸钠进行反应生成碳酸铊,向其中加入硫酸所制得的溶液,再用锌处理,得到纯度为99%的铊。向99%铊中加入氰化钾,用电炉熔融处理,制得纯度大于99.9%的铊成品。
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铊文献

Health risks of thallium in contaminated arable soils and food crops irrigated with wastewater from a sulfuric acid plant in western Guangdong province, China.

Ecotoxicol. Environ. Saf. 90 , 76-81, (2013)

Thallium (Tl) contamination in soils poses a significant threat to human health due to the high toxicity of Tl and its ready assimilation by crops. Consumption of food crops contaminated with Tl is a ...

A study of lipid- and water-soluble arsenic species in liver of Northeast Arctic cod (Gadus morhua) containing high levels of total arsenic.

J. Trace Elem. Med. Biol. 30 , 171-9, (2015)

In the present study liver samples (n=26) of Northeast Arctic cod (Gadus morhua), ranging in total arsenic concentrations from 2.1 to 240mg/kg liver wet weight (ww), were analysed for their content of...

Thallium in spawn, juveniles, and adult common toads (Bufo bufo) living in the vicinity of a zinc-mining complex, Poland.

Environ. Monit. Assess. 187(1) , 4141, (2015)

A breeding population of the common toad Bufo bufo living in the vicinity of a Zn-Pb smelting works in Bukowno, Poland was studied for the presence of thallium. Tl concentration was measured in the bo...


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【铊】化源网提供铊CAS号7440-28-0,铊MSDS及其说明、性质、英文名、生产厂家、作用/用途、分子量、密度、沸点、熔点、结构式等。CAS号查询铊上化源网,专业又轻松。>>电脑版:

标题:铊_MSDS_用途_密度_铊CAS号【7440-28-0】_化源网 地址:https://m.chemsrc.com/mip/cas/7440-28-0_958614.html