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反式-1-丙烯-1-基-硼酸

反式-1-丙烯-1-基-硼酸名称

[ CAS 号 ]:
7547-97-9

[ 中文名 ]:
反式-1--丙烯-1-基-硼酸

[ 英文名 ]:
(1E)-1-Propen-1-ylboronic acid

[中文别名 ]:

[英文别名 ]:

(1E)-1-Propen-1-ylboronic acid
[(E)-prop-1-enyl]boronic acid
Boronic acid, B-[(1E)-1-propen-1-yl]-

反式-1-丙烯-1-基-硼酸物理化学性质

[ 密度 ]:
1.0±0.1 g/cm3

[ 沸点 ]:
175.6±23.0 °C at 760 mmHg

[ 熔点 ]:
123-127ºC(lit.)

[ 分子式 ]:
C₃H₇BO₂

[ 分子量 ]:
85.897

[ 闪点 ]:
60.0±22.6 °C

[ 精确质量 ]:
86.053909

[ PSA ]:
40.46000

[ LogP ]:
0.96

[ 蒸汽压 ]:
0.4±0.7 mmHg at 25°C

[ 折射率 ]:
1.422

[ 储存条件 ]:
-20 °C

反式-1-丙烯-1-基-硼酸MSDS

详细MSDS(安全技术说明书)

反式-1-丙烯-1-基-硼酸安全信息

[ 个人防护装备 ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ 危害码 (欧洲) ]:
Xi

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
3

反式-1-丙烯-1-基-硼酸文献

Discovery of potent, selective, and orally bioavailable alkynylphenoxyacetic acid CRTH2 (DP2) receptor antagonists for the treatment of allergic inflammatory diseases.

J. Med. Chem. 20th ed., 54 , 7299-7317, (2011)

New phenoxyacetic acid antagonists of CRTH2 are described. Following the discovery of a hit compound by a focused screening, high protein binding was identified as its main weakness. Optimization aime...

Selective palladium-catalyzed C-F activation/carbon-carbon bond formation of polyfluoroaryl oxazolines.

J. Org. Chem. 4th ed., 77 , 1798-1804, (2012)

A selective palladium-catalyzed Suzuki-Miyaura coupling reaction of polyfluorophenyl oxazolines through ortho C-F activation is described. It was found that reactions with DPPF as the ligand occurred ...

Highly selective nickel-catalyzed three-component coupling of alkynes with enones and alkenyl boronic acids: a novel route to substituted 1,3-dienes.

Org. Lett. 12 , 3610-3613, (2010)

A highly regio- and stereoselective nickel-catalyzed three-component coupling of alkynes with enones and alkenyl boronic acids to afford highly substituted 1,3-dienes is described. The reaction can al...

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