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S-(-)-1,1'-联萘-2,2'-双二苯膦

S-(-)-1,1'-联萘-2,2'-双二苯膦用途

(S)-BINAP 是 (R)-BINAP (HY-W017757) 的非活性异构体,可作为实验中的对照化合物。(R)-BINAP 是一种生化试剂,可作为生物材料或有机化合物,用于生命科学相关研究。

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S-(-)-1,1'-联萘-2,2'-双二苯膦名称

[ CAS 号 ]:
76189-56-5

[ 中文名 ]:
S-(-)-1,1'-联萘-2,2'-双二苯膦

[ 英文名 ]:
(S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl

[中文别名 ]:

[英文别名 ]:

2,2'-Bis(diphenylphosphanyl)-1,1'-binaphthalene
rac-2,2'-Bis-(diphenylphosphino)-1,1'-binaphthyl
1,1'-binaphthalene-2,2'-diylbis(diphenylphosphane)
(±)-BINAP
1,1'-Binaphthalen-2,2'-diylbis(diphenylphosphan)
1,1'-Binaphthalene-2,2'-diylbis(diphenylphosphine)
rac-binap
UNII:OX12238KWH
BINAP
MFCD00010805

S-(-)-1,1'-联萘-2,2'-双二苯膦生物活性

[ 描述 ]:

[ 相关类别 ]:

研究领域 >> 其他

信号通路 >> 其他 >> 其他

[参考文献]

[1]. Nathalia Azevedo Portilho, et al. The DNMT1 inhibitor GSK-3484862 mediates global demethylation in murine embryonic stem cells.

[2]. Keystone Symposia 2019 - Epigenetics and Human Disease

S-(-)-1,1'-联萘-2,2'-双二苯膦物理化学性质

[ 沸点 ]:
724.3±55.0 °C at 760 mmHg

[ 熔点 ]:
239-242ºC

[ 分子式 ]:
C₄₄H₃₂P₂

[ 分子量 ]:
622.67

[ 闪点 ]:
419.0±37.8 °C

[ 精确质量 ]:
622.197937

[ PSA ]:
27.18000

[ LogP ]:
13.38

[ 外观性状 ]:
白色至淡黄色结晶粉末

[ 蒸汽压 ]:
0.0±2.3 mmHg at 25°C

[ 折射率 ]:
-235 ° (C=0.3， Toluene)

[ 储存条件 ]:
存放于惰性气体之中;避免空气

S-(-)-1,1'-联萘-2,2'-双二苯膦MSDS

详细MSDS(安全技术说明书)

S-(-)-1,1'-联萘-2,2'-双二苯膦安全信息

[ 个人防护装备 ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ 危害码 (欧洲) ]:
Xi:Irritant

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
S26-S37/39

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
3

S-(-)-1,1'-联萘-2,2'-双二苯膦文献

On the mechanism of an asymmetric alpha,beta-unsaturated carboxylic acid hydrogenation: application to the synthesis of a PGD2 receptor antagonist.

J. Am. Chem. Soc. 128 , 17063, (2006)

Ruthenium complexes employing axially chiral ligands were found to be effective asymmetric hydrogenation catalysts for the reduction of alpha,beta-unsaturated ene acid 1-E to give 2, a prostaglandin D...

The preparation of bi-functional organophosphine oxides as potential antitumor agents.

Eur. J. Med. Chem. 45 , 5527-30, (2010)

Following our previously reported pyridinyl phosphine oxides as antitumor agents, we targeted the commercially available C(2)-axial chiral organophosphine ligand catalysts, such as 2,2'-bis(diphenylph...

Ohkuma, T. et al.

J. Am. Chem. Soc. 117 , 2675, (1995)

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