< 生产厂家价格 >

1,1'-联萘-2,2'-双二苯膦

1,1'-联萘-2,2'-双二苯膦用途

【用途一】
用于不对称氢化催化，羰基还原等。

点击显示

1,1'-联萘-2,2'-双二苯膦名称

[ CAS 号 ]:
98327-87-8

[ 中文名 ]:
2,2'-双(二苯基膦)-1,1'-联萘

[ 英文名 ]:
(+/-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl

[中文别名 ]:

[英文别名 ]:

L66J CPR&R& B- BL66J CPR&R
2,2'-Bis(diphenylphosphanyl)-1,1'-binaphthalene
rac-2,2'-Bis-(diphenylphosphino)-1,1'-binaphthyl
1,1'-binaphthalene-2,2'-diylbis(diphenylphosphane)
(±)-BINAP
1,1'-Binaphthalen-2,2'-diylbis(diphenylphosphan)
1,1'-Binaphthalene-2,2'-diylbis(diphenylphosphine)
rac-binap
DL-2,2'-Bis(diphenylphosphino)-1,1'-dinaphthalene
UNII:OX12238KWH

1,1'-联萘-2,2'-双二苯膦生物活性

[ 描述 ]:

(Rac)-BINAP 是 (R)-BINAP (HY-W017757) 的非活性异构体,可作为实验中的对照化合物。(R)-BINAP 是一种生化试剂,可作为生物材料或有机化合物,用于生命科学相关研究。

[ 相关类别 ]:

研究领域 >> 其他

信号通路 >> 其他 >> 其他

[参考文献]

[1]. Xue CB, et al. Discovery of INCB8761/PF-4136309, a Potent, Selective, and Orally Bioavailable CCR2 Antagonist. ACS Med. Chem. Lett., 2011, 2 (12), pp 913-918.

1,1'-联萘-2,2'-双二苯膦物理化学性质

[ 沸点 ]:
724.3±55.0 °C at 760 mmHg

[ 熔点 ]:
280-285ºC

[ 分子式 ]:
C₄₄H₃₂P₂

[ 分子量 ]:
622.67

[ 闪点 ]:
419.0±37.8 °C

[ 精确质量 ]:
622.197937

[ PSA ]:
27.18000

[ LogP ]:
13.38

[ 外观性状 ]:
白色至淡黄色晶体

[ 蒸汽压 ]:
0.0±2.3 mmHg at 25°C

[ 储存条件 ]:
存放于惰性气体之中;避免光,空气

1,1'-联萘-2,2'-双二苯膦MSDS

详细MSDS(安全技术说明书)

1,1'-联萘-2,2'-双二苯膦安全信息

[ 个人防护装备 ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ 危害码 (欧洲) ]:
Xi:Irritant;

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
S26-S37/39

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
3

1,1'-联萘-2,2'-双二苯膦文献

3-demethoxy-3-glycosylaminothiocolchicines: Synthesis of a new class of putative muscle relaxant compounds.

J. Med. Chem. 49 , 5571, (2006)

A novel class of 3-demethoxy-3-glycosylaminothiocolchicines (7) was prepared and tested for muscle relaxant activity. The syntheses were performed starting from the new 3-amino-3-demethoxythiocolchici...

The preparation of bi-functional organophosphine oxides as potential antitumor agents.

Eur. J. Med. Chem. 45 , 5527-30, (2010)

Following our previously reported pyridinyl phosphine oxides as antitumor agents, we targeted the commercially available C(2)-axial chiral organophosphine ligand catalysts, such as 2,2'-bis(diphenylph...

Organometallics 23 , 3398-3416, (2004)

更多文献