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1-金刚烷醇

1-金刚烷醇用途

【用途一】
用作合成金刚烷类的中间体
【用途二】
用作合成金刚烷类的中间体。

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1-金刚烷醇名称

[ CAS 号 ]:
768-95-6

[ 中文名 ]:
1-金刚烷醇

[ 英文名 ]:
Adamantan-1-ol

[中文别名 ]:

[英文别名 ]:

MFCD00074729
Tricyclo[3.3.1.1(3,7)]decan-1-ol
1-Hydroxyadamantane
Tricyclo[3.3.1.1]decan-1-ol
adamantanol
1-adamantyl alcohol
adamantan-1-ol
1-Adamantol
adamantyl alcohol
EINECS 212-202-8

1-金刚烷醇物理化学性质

[ 密度 ]:
1.2±0.1 g/cm3

[ 沸点 ]:
245.8±8.0 °C at 760 mmHg

[ 熔点 ]:
247 °C (subl.)(lit.)

[ 分子式 ]:
C₁₀H₁₆O

[ 分子量 ]:
152.233

[ 闪点 ]:
101.1±10.9 °C

[ 精确质量 ]:
152.120117

[ PSA ]:
20.23000

[ LogP ]:
2.16

[ 外观性状 ]:
白色至灰白色结晶粉末或针状

[ 蒸汽压 ]:
0.0±1.1 mmHg at 25°C

[ 折射率 ]:
1.581

[ 储存条件 ]:
2-8°C

[ 水溶解性 ]:
水溶性：不溶；可溶于：甲醇,乙醇

1-金刚烷醇MSDS

1-金刚烷醇毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: AU4980000

CHEMICAL NAME :: 1-Adamantanol

CAS REGISTRY NUMBER :: 768-95-6

LAST UPDATED :: 198201

DATA ITEMS CITED :: 1

MOLECULAR FORMULA :: C10-H16-O

MOLECULAR WEIGHT :: 152.26

WISWESSER LINE NOTATION :: L66 B6/B-H/DI A B- C 1B ITJ BQ

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 600 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: PCJOAU Pharmaceutical Chemistry Journal (English Translation). Translation of KHFZAN. (Plenum Pub. Corp., 233 Spring St., New York, NY 10013) No.1- 1967- Volume(issue)/page/year: 10,454,1976

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1-金刚烷醇安全信息

[ 个人防护装备 ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ 危害码 (欧洲) ]:
Xi

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
S22-S24/25

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
3

[ RTECS号 ]:
AU4980000

[ 海关编码 ]:
29061900

1-金刚烷醇合成路线

1-金刚烷醇上下游产品

1-金刚烷醇上游产品

1-金刚烷醇下游产品

1-金刚烷醇海关

[ 海关编码 ]: 2906199090

[ 中文概述 ]:
2906199090. 其他环烷醇，环烯醇及环萜烯醇. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:5.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2906199090. cyclanic, cyclenic or cyclotherpenic alcohols. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

1-金刚烷醇文献

Bioconversion of 1-adamantanol to 1,3-adamantanediol usingStreptomycessp. SA8 oxidation system

J. Biosci. Bioeng. 109(6) , 550-3, (2010)

To efficiently produce 1,3-adamantanediol (1,3-ad(OH) 2) from 1-adamantanol (1-adOH), our stocks of culture strains and soil microorganisms were surveyed for hydroxylation activity towards 1-adOH. Amo...

Syntheses, characterization, and catalytic ability in alkane oxygenation of chloro(dimethyl sulfoxide)ruthenium(II) complexes with tris(2-pyridylmethyl)amine and its derivatives.

Inorg. Chem. 45(20) , 8342-54, (2006)

New ruthenium(II) complexes having a tetradentate ligand such as tris(2-pyridylmethyl)amine (TPA), tris[2-(5-methoxycarbonyl)pyridylmethyl]amine [5-(MeOCO)3-TPA], tris(2-quinolylmethyl)amine (TQA), or...

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