过硫酸钠
过硫酸钠用途
用于医药、漂白、电池,并用作化学试剂
【用途二】
用作氧化剂、漂白剂和电池去极剂
【用途三】
用于照相业的废液处理,用作印刷电路板表面金属的软蚀剂及纺织用脱浆剂、硫化染料发色剂等
【用途四】
氧化剂。电池去极剂。聚合反应促进剂。用作漂白剂、氧化剂、乳液聚合促进剂。
过硫酸钠名称
[ CAS 号 ]:
7775-27-1
[ 中文名 ]:
过硫酸钠
[ 英文名 ]:
sodium persulfate
[中文别名 ]:
[英文别名 ]:
- disodium,sulfonatooxy sulfate
- MFCD00003501
- EINECS 231-892-1
过硫酸钠物理化学性质
[ 密度 ]:
2.4 g/cm3
[ 熔点 ]:
100ºC
[ 分子式 ]:
Na2O8S2
[ 分子量 ]:
238.105
[ 闪点 ]:
180ºC
[ 精确质量 ]:
237.882996
[ PSA ]:
149.62000
[ LogP ]:
0.01660
[ 外观性状 ]:
白色结晶粉末
[ 储存条件 ]:
库房通风低温干燥,轻装轻卸,与有机物、还原剂、硫、磷易燃物,食品原料分开存放
[ 稳定性 ]:
Stability Unstable. Strong oxidizer. Contact with combustible material may cause fire. Incompatible with combustible material, strong reducing agents, strong bases, alcohols, aluminium, magnesium. Protect from moisture.
[ 水溶解性 ]:
H2O: 1 M at 20 °C, clear, colorless | 550 g/L (20 ºC)
过硫酸钠MSDS
过硫酸钠毒性和生态
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- SE0525000
- CHEMICAL NAME :
- Peroxydisulfuric acid, disodium salt
- CAS REGISTRY NUMBER :
- 7775-27-1
- LAST UPDATED :
- 199712
- DATA ITEMS CITED :
- 9
- MOLECULAR FORMULA :
- O8-S2.2Na
- MOLECULAR WEIGHT :
- 238.10
- WISWESSER LINE NOTATION :
- NA2 S2-O8
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 226 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- COREAF Comptes Rendus Hebdomadaires des Seances, Academie des Sciences. (Paris, France) V.1-261, 1835-1965. For publisher information, see CRASEV. Volume(issue)/page/year: 257,791,1963
- TYPE OF TEST :
- LDLo - Lowest published lethal dose
- ROUTE OF EXPOSURE :
- Intravenous
- SPECIES OBSERVED :
- Rodent - rabbit
- DOSE/DURATION :
- 178 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- 85KYAH "Merck Index; an Encyclopedia of Chemicals, Drugs, and Biologicals", 11th ed., Rahway, NJ 07065, Merck & Co., Inc. 1989 Volume(issue)/page/year: 11,1366,1989 *** REVIEWS *** ACGIH TLV-TWA 0.1 mg/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-DENMARK:TWA 2 mg/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 1 mg/m3 JAN 1993 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 69330 No. of Facilities: 230 (estimated) No. of Industries: 5 No. of Occupations: 10 No. of Employees: 8750 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 69330 No. of Facilities: 1466 (estimated) No. of Industries: 16 No. of Occupations: 16 No. of Employees: 30135 (estimated) No. of Female Employees: 8003 (estimated)
过硫酸钠安全信息
[ 符号 ]:
GHS03, GHS07, GHS08
[ 信号词 ]:
Danger
[ 危害声明 ]:
H272-H302-H315-H317-H319-H334-H335
[ 警示性声明 ]:
P220-P261-P280-P305 + P351 + P338-P342 + P311
[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges
[ 危害码 (欧洲) ]:
O:Oxidizing agent; Xn:Harmful;
[ 风险声明 (欧洲) ]:
R22;R36/37/38;R42/43;R8
[ 安全声明 (欧洲) ]:
S17-S26-S36/37/39-S45
[ 危险品运输编码 ]:
UN 1505
[ WGK德国 ]:
1
[ RTECS号 ]:
SE0525000
[ 包装等级 ]:
III
[ 危险类别 ]:
5.1
[ 海关编码 ]:
2833400000
过硫酸钠制备
1.用过硫酸铵与硫酸钠和硫酸进行复分解反应制得。
2.用碳酸钠来处理过二硫酸铵可制得过二硫酸钠。在通风柜中,将43g Na2CO3·10H2O与34g (NH4)2S2O8混合并研磨成糊状体,为了除去氨,可将混合物加热至40~50℃,或者通入不含CO2的空气。然后用玻璃砂芯漏斗将结晶体抽干,并放在暗处干燥。用氢氧化钠代替碳酸钠可以制得更纯的产品。在500mL的圆底烧瓶中放入122g(NH4)2S2O8和100mL浓度为33%的NaOH溶液。将烧瓶与真空泵相连,稍稍加热,在30~40℃的温度下使氨和水蒸出。在溶液体积减至原来的一半后,将溶液冷却,用玻璃砂芯漏斗将结晶抽干,并在30~40℃下干燥1~2h。
过硫酸钠海关
[ 海关编码 ]: 2833400000
过硫酸钠文献
Bioorg. Med. Chem. Lett. 21 , 3591-5, (2011)
Two new β-carbonic anhydrases (CAs, EC 4.2.1.1) from the bacterial pathogen Salmonella enterica serovar Typhimurium, stCA 1 and stCA 2, were characterized kinetically. The two enzymes possess apprecia...
Anion inhibition studies of an α-carbonic anhydrase from the living fossil Astrosclera willeyana.Bioorg. Med. Chem. Lett. 22 , 1314-6, (2012)
An α-carbonic anhydrase (CA, EC 4.2.1.1) isolated from the living fossil sponge Astrosclera willeyana, Astrosclerin, was investigated for its inhibition profile with simple inorganic anions, complex a...
Inhibition of the β-carbonic anhydrase from Streptococcus pneumoniae by inorganic anions and small molecules: Toward innovative drug design of antiinfectives?Bioorg. Med. Chem. 19 , 243-8, (2011)
The Gram-positive bacterium Streptococcus pneumoniae is a human respiratory tract pathogen that contributes significantly to global mortality and morbidity. It was recently shown that this bacterial p...
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相关化合物
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