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三氟化磷

三氟化磷名称

[ CAS 号 ]:
7783-55-3

[ 中文名 ]:
三氟化磷

[ 英文名 ]:
phosphorus trifluoride

[英文别名 ]:

trifluorophosphane
phosphorus trfluoride
TL 75
Phosphorus fluoride
phosphorus(III) fluoride
Trifluorophosphine
phosphorous trifluoride
Phosphorous fluoride
EINECS 232-008-7
Trifluorophosphin

三氟化磷物理化学性质

[ 密度 ]:
3.907g/l

[ 沸点 ]:
-95 ºC

[ 熔点 ]:
-90--88 ºC

[ 分子式 ]:
F₃P

[ 分子量 ]:
87.96900

[ 闪点 ]:
-101.5°C

[ 精确质量 ]:
87.96900

[ PSA ]:
13.59000

[ LogP ]:
2.12180

[ 外观性状 ]:
Gas,Colorless

[ 储存条件 ]:
库房通风低温干燥; 与碱、含水物品分开存放

[ 水溶解性 ]:
Slightly soluble (1.1 g/L) (25 ºC)

三氟化磷MSDS

三氟化磷毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: TH3850000

CHEMICAL NAME :: Phosphorus fluoride

CAS REGISTRY NUMBER :: 7783-55-3

LAST UPDATED :: 199712

DATA ITEMS CITED :: 27

MOLECULAR FORMULA :: F3-P

MOLECULAR WEIGHT :: 87.97

WISWESSER LINE NOTATION :: P F3

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LCLo - Lowest published lethal concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 1900 mg/m3/10M

REFERENCE :: NDRC** National Defense Research Committee, Office of Scientific Research and Development, Progress Report. Volume(issue)/page/year: NDCrc-132,JUN1942 *** REVIEWS *** ACGIH TLV-TWA 2.5 mg(F)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 ACGIH TLV-Not classifiable as a human carcinogen DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 2.5 mg(F)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,116,1971 OSHA PEL (Gen Indu):8H TWA 2.5 mg(F)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 2.5 mg(F)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 2.5 mg(F)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 2.5 mg(F)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 2.5 mg(F)/m3 JAN 1993 OEL-BELGIUM:TWA 2.5 mg(F)/m3 JAN 1993 OEL-DENMARK:TWA 2.5 mg(F)/m3 JAN 1993 OEL-FINLAND:TWA 2.5 mg(F)/m3 JAN 1993 OEL-FRANCE:TWA 2.5 mg(F)/m3 JAN 1993 OEL-GERMANY:TWA 2.5 mg(F)/m3 JAN 1993 OEL-HUNGARY:TWA 1 mg(F)/m3;STEL 2 mg(F)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 2.5 mg(F)/m3 JAN 1993 OEL-THE PHILIPPINES:TWA 2.5 mg(F)/m3 JAN 1993 OEL-POLAND:TWA 1 mg(F)/m3 JAN 1993 OEL-SWEDEN:TWA 2 mg(F)/m3 JAN 1993 OEL-SWITZERLAND:TWA 1.8 ppm (1.5 mg(F)/m3);STEL 9.0 ppm JAN 1993 OEL-THAILAND:TWA 2.5 mg(F)/m3 JAN 1993 OEL-TURKEY:TWA 2.5 mg(F)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 2.5 mg(F)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO FLUORIDES, INORGANIC-air:10H TWA 2.5 mg(F)/m3 REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992

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三氟化磷安全信息

[ 危害码 (欧洲) ]:
T

[ 风险声明 (欧洲) ]:
R14;R32;R34

[ 安全声明 (欧洲) ]:
S9;S38;S45

[ 危险品运输编码 ]:
UN 3308

[ RTECS号 ]:
TH3850000

[ 危险类别 ]:
2.3

三氟化磷合成路线

三氟化磷上下游产品

三氟化磷上游产品

三氟化磷下游产品

三氟化磷制备

将在140～150℃下干燥过夜的热的无水氟化锌粉末50～60g放在500mL双颈圆底烧瓶中，装上滴液漏斗和导管，后者依次连接安全瓶、盛有浓硫酸的洗气瓶，和两个干冰丙酮冷冻的捕集器。从滴液漏斗中将45mL三氯化磷滴入烧瓶中。本反应是有一较长诱发期的强烈的放热反应，开始的1～2min内以每秒钟1滴的速度加入。然后调节三氯化磷的加入速度，并将烧瓶浸入冷水浴中，使三氯化磷的小液滴凝聚在烧瓶的冷部位上。以控制产生三氟化磷的速度(从硫酸洗瓶中也可以观察出来)。约1.5～2h滴完三氯化磷。反应的最后阶段可改为热水浴，使反应完全。