三偏磷酸钠
三偏磷酸钠用途
用作淀粉改良剂,食品工业用于面粉、糕点制品等
【用途二】
淀粉改性剂;果汁浑浊防止剂;保水剂;水质软化剂;肉类粘结剂;分散剂;稳定剂(用于冰淇淋、干酪等);能防止食品变色与维生素C分解等。
【用途三】
在食品工业中用作淀粉改性剂,果汁混浊防止剂,肉类黏结剂,分散剂,稳定剂(用于冰淇淋、干酪等)。能防止食品变色与防止维生素C分解。也用作水质软化剂。
【用途四】
鉴定方法:本品呈钠离子反应和磷酸盐反应。 ①钠盐反应:将铂丝用浓盐酸湿润后,蘸取本品少许,在无色火焰上燃烧,火焰呈鲜艳黄色(钠离子)。 ②磷酸盐反应:取本品中性溶液,加硝酸银溶液(20g/L),有浅黄色沉淀生成,分离沉淀,沉淀在氨溶液(2+3)或硝酸溶液(6 mol/L)中易溶解。
三偏磷酸钠名称
[ CAS 号 ]:
7785-84-4
[ 中文名 ]:
三偏磷酸钠
[ 英文名 ]:
SODIUM TRIMETAPHOSPHATE
[中文别名 ]:
[英文别名 ]:
- EINECS 232-088-3
- MFCD00867826
- Sodium trimetaphosphate
三偏磷酸钠物理化学性质
[ 密度 ]:
2.49
[ 熔点 ]:
588ºC
[ 分子式 ]:
Na3O9P3
[ 分子量 ]:
305.88500
[ 精确质量 ]:
305.84500
[ PSA ]:
177.51000
[ LogP ]:
1.66560
[ 外观性状 ]:
白色结晶粉末
[ 储存条件 ]:
室温
三偏磷酸钠MSDS
三偏磷酸钠毒性和生态
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- OY4025000
- CHEMICAL NAME :
- Metaphosphoric acid, trisodium salt
- CAS REGISTRY NUMBER :
- 7785-84-4
- LAST UPDATED :
- 199710
- DATA ITEMS CITED :
- 9
- MOLECULAR FORMULA :
- H3-O9-P3.3Na
- MOLECULAR WEIGHT :
- 308.91
- WISWESSER LINE NOTATION :
- NA3 P-O3*3
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 3650 mg/kg
- TOXIC EFFECTS :
- Behavioral - excitement Nutritional and Gross Metabolic - weight loss or decreased weight gain
- REFERENCE :
- JPETAB Journal of Pharmacology and Experimental Therapeutics. (Williams & Wilkins Co., 428 E. Preston St., Baltimore, MD 21202) V.1- 1909/10- Volume(issue)/page/year: 108,117,1953
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 10300 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- ARZNAD Arzneimittel-Forschung. Drug Research. (Editio Cantor Verlag, Postfach 1255, W-7960 Aulendorf, Fed. Rep. Ger.) V.1- 1951- Volume(issue)/page/year: 7,445,1957
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Subcutaneous
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 5940 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- ARZNAD Arzneimittel-Forschung. Drug Research. (Editio Cantor Verlag, Postfach 1255, W-7960 Aulendorf, Fed. Rep. Ger.) V.1- 1951- Volume(issue)/page/year: 7,445,1957
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intravenous
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 1165 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- ARZNAD Arzneimittel-Forschung. Drug Research. (Editio Cantor Verlag, Postfach 1255, W-7960 Aulendorf, Fed. Rep. Ger.) V.1- 1951- Volume(issue)/page/year: 7,445,1957
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - rabbit
- DOSE/DURATION :
- >4640 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0571153
- TYPE OF TEST :
- LDLo - Lowest published lethal dose
- ROUTE OF EXPOSURE :
- Intravenous
- SPECIES OBSERVED :
- Rodent - rabbit
- DOSE/DURATION :
- 240 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- AEPPAE Naunyn-Schmiedeberg's Archiv fuer Experimentelle Pathologie und Pharmakologie. (Berlin, Ger.) V.110-253, 1925-66. For publisher information, see NSAPCC. Volume(issue)/page/year: 169,238,1933 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - T1866 No. of Facilities: 101 (estimated) No. of Industries: 2 No. of Occupations: 2 No. of Employees: 308 (estimated) No. of Female Employees: 260 (estimated)
三偏磷酸钠安全信息
[ 个人防护装备 ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter
[ 危害码 (欧洲) ]:
Xi
[ 危险品运输编码 ]:
UN 3077 9/PG 3
[ WGK德国 ]:
2
[ RTECS号 ]:
OY4025000
[ 海关编码 ]:
2835399000
三偏磷酸钠制备
磷酸二氢钠法将食用磷酸二氢钠加热,于95℃脱水成为无水磷酸二氢钠,然后送人箱式聚合炉中加热熔融聚合,当物料温度在140~200℃时,先转化成酸式焦磷酸钠,再加热至260℃时转化成环状偏磷酸钠,再加热至500℃时聚合成三偏磷酸钠,经冷却,粉碎,制得食用三偏磷酸钠成品。其
2.将60g磷酸二氢钠与17g硝酸铵的混合物在310~320℃加热6h,冷却后将混合物溶于冷水中,过滤,将滤液结晶,得到六水环三偏磷酸钠。 3. 由五氧化二磷与碳酸钠在4 7 5~5 0 0℃下共热制得。反应式如下: 3 P 2O 5+3 N a 2C O3 → 2 N a 3P 3O 9+3 C O 2
三偏磷酸钠海关
[ 海关编码 ]: 2835399000
三偏磷酸钠文献
Anal. Chim. Acta 842 , 35-41, (2014)
Sodium polyphosphate is commonly used to enhance chemiluminescence reactions with acidic potassium permanganate through a dual enhancement mechanism, but commercially available polyphosphates vary gre...
In situ evaluation of a low fluoride concentration gel with sodium trimetaphosphate in enamel remineralization.Am. J. Dent. 26(1) , 15-20, (2013)
To evaluate the capability of gels with low fluoride (F) concentration and supplemented with sodium trimetaphosphate (TMP) to promote in situ enamel remineralization.Bovine enamel blocks were selected...
Preparation of cross-linked carboxymethyl jackfruit starch and evaluation as a tablet disintegrant.Pak. J. Pharm. Sci. 24(4) , 415-20, (2011)
The main purposes of this study are to prepare cross-linked carboxymethyl jackfruit starch (CL-CMJF) and to evaluate its pharmaceutical property as a tablet disintegrant. CL-CMJF was prepared by a dua...
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