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过氧化氢异丙苯

过氧化氢异丙苯用途

用于乙烯裂解汽油脱砷和ABS接枝聚合引发剂

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过氧化氢异丙苯名称

[ CAS 号 ]:
80-15-9

[ 中文名 ]:
过氧化氢异丙苯

[ 英文名 ]:
Cumyl hydroperoxide

[中文别名 ]:

[英文别名 ]:

2-Phenyl-2-propyl hydroperoxide
Cumene hydroperoxide
2-Phenylpropan-2-yl hydroperoxide
MFCD00002129
2-hydroperoxypropan-2-ylbenzene
Hyperiz
Trigonox R 239A
a,a-Dimethylbenzyl Hydroperoxide
a-Cumyl Hydroperoxide
1-Methyl-1-phenylethylhydroperoxide

过氧化氢异丙苯物理化学性质

[ 密度 ]:
1.1±0.1 g/cm3

[ 沸点 ]:
225.1±0.0 °C at 760 mmHg

[ 熔点 ]:
-30 °C

[ 分子式 ]:
C₉H₁₂O₂

[ 分子量 ]:
152.190

[ 闪点 ]:
56.1±0.0 °C

[ 精确质量 ]:
152.083725

[ PSA ]:
29.46000

[ LogP ]:
2.63

[ 外观性状 ]:
略黄色液体

[ 蒸汽密度 ]:
5.4 (vs air)

[ 蒸汽压 ]:
0.1±0.4 mmHg at 25°C

[ 折射率 ]:
1.515

[ 储存条件 ]:
库房通风低温干燥,与有机物、还原物、易燃物、强酸分开存放

[ 稳定性 ]:
Stable. combustible. Strong oxidizer. Incompatible with a variety of organic materials, reacting vigorously or violently with acids, reducing agents, many metals, strong alkalies. Heat sensitive, decomposing explosively.

[ 水溶解性 ]:
Slightly soluble

过氧化氢异丙苯MSDS

详细MSDS(安全技术说明书)

过氧化氢异丙苯毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: MX2450000

CHEMICAL NAME :: Hydroperoxide, alpha,alpha-dimethylbenzyl-

CAS REGISTRY NUMBER :: 80-15-9

BEILSTEIN REFERENCE NO. :: 1908117

LAST UPDATED :: 199710

DATA ITEMS CITED :: 29

MOLECULAR FORMULA :: C9-H12-O2

MOLECULAR WEIGHT :: 152.21

WISWESSER LINE NOTATION :: QOX1&1&R

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration into the eye

SPECIES OBSERVED :: Rodent - rabbit

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 382 mg/kg

TOXIC EFFECTS :: Kidney, Ureter, Bladder - hematuria

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 220 ppm/4H

TOXIC EFFECTS :: Lungs, Thorax, or Respiration - dyspnea

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 500 mg/kg

TOXIC EFFECTS :: Behavioral - convulsions or effect on seizure threshold Kidney, Ureter, Bladder - hematuria

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 95 mg/kg

TOXIC EFFECTS :: Behavioral - muscle weakness Behavioral - ataxia

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Subcutaneous

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 382 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 5 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 200 ppm/4H

TOXIC EFFECTS :: Lungs, Thorax, or Respiration - dyspnea

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 270 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Subcutaneous

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 490 mg/kg

TOXIC EFFECTS :: Behavioral - somnolence (general depressed activity) Behavioral - excitement Lungs, Thorax, or Respiration - dyspnea

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 1200 mg/kg

TOXIC EFFECTS :: Cardiac - pulse rate increase, without fall in BP Blood - changes in erythrocyte (RBC) count Nutritional and Gross Metabolic - body temperature decrease

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 1604 mg/kg/7W-I

TOXIC EFFECTS :: Related to Chronic Data - death

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 50 ppm/4H/3D-I

TOXIC EFFECTS :: Lungs, Thorax, or Respiration - other changes Kidney, Ureter, Bladder - other changes Related to Chronic Data - death

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 399 mg/kg/7W-I

TOXIC EFFECTS :: Related to Chronic Data - death

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Subcutaneous

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 8844 mg/kg/67W-I

TOXIC EFFECTS :: Tumorigenic - equivocal tumorigenic agent by RTECS criteria Tumorigenic - tumors at site of application

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Unreported

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 304 mg/kg

TOXIC EFFECTS :: Tumorigenic - equivocal tumorigenic agent by RTECS criteria Blood - lymphoma, including Hodgkin's disease Skin and Appendages - tumors

MUTATION DATA

TYPE OF TEST :: Gene conversion and mitotic recombination

TEST SYSTEM :: Yeast - Saccharomyces cerevisiae

DOSE/DURATION :: 47 mg/L

REFERENCE :: MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 308,159,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-RUSSIA:STEL 1 mg/m3 JAN 1993 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - A1346 No. of Facilities: 4311 (estimated) No. of Industries: 80 No. of Occupations: 53 No. of Employees: 95676 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - A1346 No. of Facilities: 10989 (estimated) No. of Industries: 125 No. of Occupations: 85 No. of Employees: 234305 (estimated) No. of Female Employees: 69933 (estimated)

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过氧化氢异丙苯安全信息

[ 符号 ]:

GHS02, GHS05, GHS06, GHS08, GHS09

[ 信号词 ]:
Danger

[ 危害声明 ]:
H226-H242-H302 + H312-H304-H314-H331-H335-H373-H411

[ 警示性声明 ]:
P210-P260-P280-P304 + P340 + P310-P305 + P351 + P338 + P310-P370 + P378

[ 个人防护装备 ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
T:Toxic

[ 风险声明 (欧洲) ]:
R21/22;R23;R34;R48/20/22;R51/53;R7

[ 安全声明 (欧洲) ]:
S14-S3/7-S36/37/39-S45-S50-S61-S14A-S26

[ 危险品运输编码 ]:
UN 3109 5.2

[ WGK德国 ]:
3

[ RTECS号 ]:
MX2450000

[ 包装等级 ]:
II

[ 危险类别 ]:
5.2

[ 海关编码 ]:
2909600000

过氧化氢异丙苯合成路线

详细合成路线

过氧化氢异丙苯上下游产品

过氧化氢异丙苯上游产品

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过氧化氢异丙苯海关

[ 海关编码 ]: 2909600000

[ 中文概述 ]:
2909600000 过氧化醇、过氧化醚、过氧化酮及其卤化、磺化、硝化、亚硝化衍生物。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:5.5%。普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2909600000 alcohol peroxides, ether peroxides, ketone peroxides and their halogenated, sulphonated, nitrated or nitrosated derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

过氧化氢异丙苯文献

Effects of curcumin and tannic acid on the aluminum- and lead-induced oxidative neurotoxicity and alterations in NMDA receptors.

Toxicol. Mech. Methods 25(2) , 120-7, (2015)

Exposure to aluminum (Al) and lead (Pb) can cause brain damage. Also, Pb and Al exposure alters N-methyl-d-aspartate receptor (NMDAR) subunit expression. Polyphenols such as tannic acid and curcumin a...

In vitro/in vivo screening of oxidative homeostasis and damage to DNA, protein, and lipids using UPLC/MS-MS.

Anal. Bioanal. Chem 406(22) , 5465-76, (2014)

Multiple analytical methods are required to comprehensively assess oxidative homeostasis and specific damage to macromolecules. Our aim was to develop a straightforward strategy for the fast assessmen...

Role of oxidative stress in Sclerotial differentiation and aflatoxin B1 biosynthesis in Aspergillus flavus.

Appl. Environ. Microbiol. 80(18) , 5561-71, (2014)

We show here that oxidative stress is involved in both sclerotial differentiation (SD) and aflatoxin B1 biosynthesis in Aspergillus flavus. Specifically, we observed that (i) oxidative stress regulate...

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