杀螨酯
杀螨酯用途
杀螨酯名称
[ CAS 号 ]:
80-33-1
[ 中文名 ]:
杀螨酯
[ 英文名 ]:
ovex
[中文别名 ]:
[英文别名 ]:
- 4-chlorophenyl 4-chlorobenzene-1-sulfonate
- chlorofensone
- Chlorofenizon
- chlorofenson
- Difenson
- EINECS 201-270-4
- Ephirsulphonate
- p-chlorophenyl p-chlorobenzenesulfonate
- ovatron
- ovex
杀螨酯生物活性
[ 描述 ]:
[ 相关类别 ]:
[参考文献]
杀螨酯物理化学性质
[ 密度 ]:
1.464g/cm3
[ 沸点 ]:
429.6ºC at 760 mmHg
[ 熔点 ]:
86.5-86.8°
[ 分子式 ]:
C12H8Cl2O3S
[ 分子量 ]:
303.16100
[ 闪点 ]:
213.6ºC
[ 精确质量 ]:
301.95700
[ PSA ]:
51.75000
[ LogP ]:
4.84190
[ 外观性状 ]:
Crystalline
[ 折射率 ]:
1.609
[ 储存条件 ]:
库房通风低温干燥,与食品原料分开储运
杀螨酯MSDS
杀螨酯毒性和生态
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- DB5250000
- CHEMICAL NAME :
- Benzenesulfonic acid, 4-chloro-, 4-chlorophenyl ester
- CAS REGISTRY NUMBER :
- 80-33-1
- BEILSTEIN REFERENCE NO. :
- 2944674
- LAST UPDATED :
- 199612
- DATA ITEMS CITED :
- 12
- MOLECULAR FORMULA :
- C12-H8-Cl2-O3-S
- MOLECULAR WEIGHT :
- 303.16
- WISWESSER LINE NOTATION :
- GR DSWOR DG
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 2 gm/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- GUCHAZ Guide to the Chemicals Used in Crop Protection. (Information Canada, 171 Slater St., Ottawa, Ont., Canada) Volume(issue)/page/year: 6,381,1973
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- >10 gm/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 8,150,1987
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Unreported
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 2050 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- DABBBA Dissertation Abstracts International, B: The Sciences and Engineering. (University Microfilms International, 300 N. Zeeb Rd., Ann Arbor, MI 48106) V.30- 1969- Volume(issue)/page/year: 32,4116,1972
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 1475 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- 85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982 Volume(issue)/page/year: -,37,1982
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rabbit
- DOSE/DURATION :
- 5660 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- PCOC** Pesticide Chemicals Official Compendium, Association of the American Pesticide Control Officials, Inc., 1966. (Topeka, KS) Volume(issue)/page/year: -,841,1966
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - guinea pig
- DOSE/DURATION :
- 640 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- PCOC** Pesticide Chemicals Official Compendium, Association of the American Pesticide Control Officials, Inc., 1966. (Topeka, KS) Volume(issue)/page/year: -,841,1966
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Bird - chicken
- DOSE/DURATION :
- 3780 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- PCOC** Pesticide Chemicals Official Compendium, Association of the American Pesticide Control Officials, Inc., 1966. (Topeka, KS) Volume(issue)/page/year: -,841,1966
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Bird - quail
- DOSE/DURATION :
- 4600 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 8,150,1987 ** OTHER MULTIPLE DOSE TOXICITY DATA **
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 1008 mg/kg/12W-C
- TOXIC EFFECTS :
- Liver - changes in liver weight Endocrine - changes in thyroid weight Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - hepatic microsomal mixed oxidase (dealkylation, hydroxylation, etc.)
- REFERENCE :
- TXCYAC Toxicology. (Elsevier Scientific Pub. Ireland, Ltd., POB 85, Limerick, Ireland) V.1- 1973- Volume(issue)/page/year: 1,113,1973 ** TUMORIGENIC DATA **
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 115 gm/kg/78W-I
- TOXIC EFFECTS :
- Tumorigenic - equivocal tumorigenic agent by RTECS criteria Liver - tumors Blood - tumors
- REFERENCE :
- NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: PB223-159 *** REVIEWS *** TOXICOLOGY REVIEW RREVAH Residue Reviews. (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ 07094) V.1- 1962- Volume(issue)/page/year: 56,107,1975 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-RUSSIA:STEL 2 mg/m3 JAN 1993
杀螨酯安全信息
[ 符号 ]:
GHS07, GHS09
[ 信号词 ]:
Warning
[ 危害声明 ]:
H302-H315-H410
[ 警示性声明 ]:
P273-P501
[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves
[ 危害码 (欧洲) ]:
Xn: Harmful;N: Dangerous for the environment;
[ 风险声明 (欧洲) ]:
22-38-50/53
[ 安全声明 (欧洲) ]:
S37-S60-S61
[ 危险品运输编码 ]:
UN3077 9/PG 3
[ RTECS号 ]:
DB5250000
杀螨酯合成路线
杀螨酯制备
1.以对氯苯磺酸和氯磺酸为原料,经下列步骤生产杀螨酯。杀螨酯工业品含量95%以上。原料消耗定额:对氯苯磺酸(92%)1230kg/t、氯磺酸(95%)2100kg/t、苯酚(98%)310kg/t、氢氧化钠(95%)157kg/t、氯气(99.5%) 250kg/t、三氯化铁(99%)1.8kg/t。
2.以对氯苯磺酸和氯磺酸为原料,经下列步骤合成杀螨酯。
3.以对氯苯酚和对氯苯磺酰氯为原料,在碱性条件下合成杀螨酯。
杀螨酯文献
Sensors (Basel.) 11(4) , 3791-802, (2011)
An approach to an inhibition bioelectronic tongue is presented. The work is focused on development of an automated flow system to carry out experimental assays, a custom potentiostat to measure the re...
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联系人:徐经理
产品详情:杀螨酯
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区域:上海市浦东新区
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相关化合物
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