三氯异氰脲酸
三氯异氰脲酸用途
用于饮用水、游泳池水、工业循环水、污水等各种水质的杀菌消毒处理
【用途二】
该品具有极强的杀菌、漂白作用，广泛用于民用卫生，畜牧养殖业以及植保等作高效杀菌消毒剂，棉、麻化纤织物的洗涤漂白剂，羊毛防缩剂，也可用于橡胶氯化，电池材料，有机合成工业以及衣物的干法漂白等。
三氯异氰脲酸名称
[ CAS 号 ]:
87-90-1
[ 中文名 ]:
三氯异氰尿酸
[ 英文名 ]:
symclosene
[中文别名 ]:
[英文别名 ]:
- MFCD00006553
- symclosene
- EINECS 201-782-8
- Trichloroisocyanuric Acid
三氯异氰脲酸物理化学性质
[ 密度 ]:
2.2±0.1 g/cm3
[ 沸点 ]:
272.3±23.0 °C at 760 mmHg
[ 熔点 ]:
249-251 °C(lit.)
[ 分子式 ]:
C3Cl3N3O3
[ 分子量 ]:
232.409
[ 闪点 ]:
118.5±22.6 °C
[ 精确质量 ]:
230.900528
[ PSA ]:
66.00000
[ LogP ]:
0.11
[ 外观性状 ]:
白色结晶粉末或片状
[ 蒸汽压 ]:
0.0±0.6 mmHg at 25°C
[ 折射率 ]:
1.686
[ 储存条件 ]:
库房通风低温干燥,与燃料、有机物、易氧化物分开存放
[ 稳定性 ]:
Stable. Hygroscopic, and may decompose in contact with moisture. Contact with combustible material may lead to fire. Incompatible with acids, reducing agents, water, strong oxidizing agents.
[ 水溶解性 ]:
1.2 g/100mL (25 ºC)
三氯异氰脲酸MSDS
三氯异氰脲酸毒性和生态
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- XZ1925000
- CHEMICAL NAME :
- s-Triazine-2,4,6(1H,3H,5H)-trione, 1,3,5-trichloro-
- CAS REGISTRY NUMBER :
- 87-90-1
- BEILSTEIN REFERENCE NO. :
- 0202022
- LAST UPDATED :
- 199710
- DATA ITEMS CITED :
- 15
- MOLECULAR FORMULA :
- C3-Cl3-N3-O3
- MOLECULAR WEIGHT :
- 232.41
- WISWESSER LINE NOTATION :
- T6NVNVNVJ AG CG EG
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- Standard Draize test
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - rabbit
- REFERENCE :
- 28ZPAK "Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku," Marhold, J.V., Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu Praha, Czechoslovakia, 1972 Volume(issue)/page/year: -,153,1972
- TYPE OF TEST :
- Standard Draize test
- ROUTE OF EXPOSURE :
- Administration into the eye
- SPECIES OBSERVED :
- Rodent - rabbit
- REFERENCE :
- NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0570617 ** ACUTE TOXICITY DATA **
- TYPE OF TEST :
- LDLo - Lowest published lethal dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Human
- DOSE/DURATION :
- 3570 mg/kg
- TOXIC EFFECTS :
- Gastrointestinal - ulceration or bleeding from stomach
- REFERENCE :
- 34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York, Academic Press, Inc., 1969 Volume(issue)/page/year: -,167,1969
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 406 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 42,417,1977
- TYPE OF TEST :
- LC - Lethal concentration
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- >2 gm/m3/1H
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- MONS** Monsanto Co. Toxicity Information. (Monsanto Industrial Chemicals Co., Bancroft Bldg., Suite 204, 3411 Silverside Rd., Wilmington, DE 19810) Volume(issue)/page/year: -,-,1972
- TYPE OF TEST :
- LDLo - Lowest published lethal dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rabbit
- DOSE/DURATION :
- 1900 mg/kg
- TOXIC EFFECTS :
- Behavioral - coma
- REFERENCE :
- MONS** Monsanto Co. Toxicity Information. (Monsanto Industrial Chemicals Co., Bancroft Bldg., Suite 204, 3411 Silverside Rd., Wilmington, DE 19810) Volume(issue)/page/year: -,-,1972
- TYPE OF TEST :
- LDLo - Lowest published lethal dose
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - rabbit
- DOSE/DURATION :
- 5010 mg/kg
- TOXIC EFFECTS :
- Behavioral - somnolence (general depressed activity) Behavioral - food intake (animal) Liver - other changes
- REFERENCE :
- NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0570617
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Mammal - species unspecified
- DOSE/DURATION :
- 750 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- YKYUA6 Yakkyoku. Pharmacy. (Nanzando, 4-1-11, Yushima, Bunkyo-ku, Tokyo, Japan) V.1- 1950- Volume(issue)/page/year: 31,959,1980 *** REVIEWS *** TOXICOLOGY REVIEW EVHPAZ EHP, Environmental Health Perspectives. (U.S. Government Printing Office, Supt of Documents, Washington, DC 20402) No.1- 1972- Volume(issue)/page/year: 69,287,1986 *** U.S. STANDARDS AND REGULATIONS *** EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION FEREAC Federal Register. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) V.1- 1936- Volume(issue)/page/year: 54,7740,1989 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 84386 No. of Facilities: 5356 (estimated) No. of Industries: 17 No. of Occupations: 12 No. of Employees: 19489 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 84386 No. of Facilities: 9856 (estimated) No. of Industries: 93 No. of Occupations: 67 No. of Employees: 171094 (estimated) No. of Female Employees: 73008 (estimated)
三氯异氰脲酸安全信息
[ 符号 ]:
GHS03, GHS07, GHS09
[ 信号词 ]:
Danger
[ 危害声明 ]:
H272-H302-H315-H319-H335-H410
[ 补充危害声明 ]:
Contact with acids liberates toxic gas.
[ 警示性声明 ]:
P210-P273-P280-P305 + P351 + P338-P370 + P378-P501
[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges
[ 危害码 (欧洲) ]:
Xn:Harmful
[ 风险声明 (欧洲) ]:
R22;R31;R36/37;R50/53;R8
[ 安全声明 (欧洲) ]:
S8-S26-S41-S60-S61
[ 危险品运输编码 ]:
UN 2468 5.1/PG 2
[ WGK德国 ]:
2
[ RTECS号 ]:
XZ1925000
[ 包装等级 ]:
II
[ 危险类别 ]:
5.1
[ 海关编码 ]:
2933692200
三氯异氰脲酸合成路线
三氯异氰脲酸上下游产品
三氯异氰脲酸上游产品
三氯异氰脲酸下游产品
三氯异氰脲酸制备
1.以尿素与氯化铵为主要原料，经热裂解制得三聚氰酸，再经氯化制取。三氯异氰尿酸生产工艺有固相法和液相法。固相法技术落后，成本高，环境条件恶劣，副产品不易处理，生产规模小。液相法生产工艺是在环丁砜、二甲基甲酰胺等高沸点溶剂中进行反应，产品随反应的进行而逐渐析出，冷却分离生成品，溶剂再生后循环使用。该法可连续生产，收率高，无废水排放。但是该法工艺复杂，投资较高。氯化方法主要有两种：一种是碱土金属法,Ca(OH)2水溶液与三聚氰酸水溶液混合，通氯反应，反应物经冷却过滤、水洗、干燥后得产品；另一种为次氯酸法，次氯酸水溶液与三聚氰酸浆液在低温下反应，沉淀过滤，水洗干燥后得产品。
异氰尿酸溶于氢氧化钠溶液中，再在低温下缓慢通入氯气，进行氯化反应，则沉淀出三氯异氰尿酸。经过滤、水洗、干燥后即为产品，其反应式如下：
三氯异氰脲酸海关
[ 海关编码 ]: 2933692200
[ 中文概述 ]:
2933692200 三氯异氰脲酸。监管条件:AB(入境货物通关单,出境货物通关单)。增值税率:17.0%。退税率:9.0%。最低关税:6.5%。普通关税:20.0%
[ 申报要素 ]: 品名, 成分含量, 用途, 乌洛托品请注明外观, 6－己内酰胺请注明外观, 签约日期
[ 监管条件 ]: A.入境货物通关单 B.出境货物通关单
[ 检验检疫 ]: M.进口商品检验 N.出口商品检验
[ Summary ]:
2933692200 1,3,5-trichloro-1,3,5-triazinane-2,4,6-trione。supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward)。VAT:17.0%。tax rebate rate:9.0%。MFN tarrif:6.5%。general tariff:20.0%
三氯异氰脲酸文献
Cytokine 74 , 293-304, (2015)
The P2X(7)R is a functionally distinct member of the P2X family of non-selective cation channels associated with rapid activation of the inflammasome complex and signalling interleukin (IL)-1β release...
Halonium ion mediated synthesis of 2-halomethylene-3-oxoketoxime derivatives from isoxazoline N-oxides.J. Org. Chem. 78(17) , 8872-9, (2013)
A protocol for the N-bromosuccinimide (NBS)- and trichloroisocyanuric acid (TCCA)-mediated synthesis of novel 2-halomethylene-3-oxoketoximes via one-pot halogenation/oxidation of isoxazoline N-oxide d...
Stability and toxicity of selected chlorinated benzophenone-type UV filters in waters.Acta Chim. Slov. 60(4) , 826-32, (2013)
In our study, the transformation of two most widely used UV filters, benzophenone-3 (BP3) and benzophenone-4 (BP4), in chlorinated water with disinfection reagents sodium hypochlorite (NaClO) and tric...
相关化工产品/化学物质：
推荐生产厂家/供应商：
公司名：上海吉至生化科技有限公司
区域：上海市奉贤区
价格：
￥198.0/500g
￥78.0/100g
联系人：刘佳
产品详情：三氯异氰脲酸
公司名：上海阿拉丁生化科技股份有限公司
区域：上海市浦东新区
价格：
￥159.0/500g
￥需询单/1g
￥47.0/100g
￥需询单/1g
联系人：阿拉丁
产品详情：三氯异氰脲酸
公司名：中山市迪欣化工有限公司
区域：中山市三角镇
价格：
￥10.0/1000kg
联系人：王洁
产品详情：三氯异氰尿酸
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相关化合物
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