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四氟硼酸二叔丁基甲基膦鎓盐

四氟硼酸二叔丁基甲基膦鎓盐名称

[ CAS 号 ]:
870777-30-3

[ 中文名 ]:
四氟硼酸二叔丁基苯基膦盐

[ 英文名 ]:
di-tert-butylmethylphosphine tetrafluor&

[中文别名 ]:

[英文别名 ]:

MFCD03840579

四氟硼酸二叔丁基甲基膦鎓盐物理化学性质

[ 熔点 ]:
>230ºC(lit.)

[ 分子式 ]:
C₉H₂₁BF₄P

[ 分子量 ]:
247.04100

[ 精确质量 ]:
247.14100

[ PSA ]:
13.59000

[ LogP ]:
4.99510

[ 外观性状 ]:
Powder | white

[ 储存条件 ]:
室温

四氟硼酸二叔丁基甲基膦鎓盐MSDS

详细MSDS(安全技术说明书)

四氟硼酸二叔丁基甲基膦鎓盐安全信息

[ 符号 ]:

GHS05

[ 信号词 ]:
Danger

[ 危害声明 ]:
H314

[ 警示性声明 ]:
P280-P305 + P351 + P338-P310

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ 危害码 (欧洲) ]:
C

[ 风险声明 (欧洲) ]:
34

[ 安全声明 (欧洲) ]:
26-36/37/39-45

[ 危险品运输编码 ]:
UN 3261 8/PG 2

四氟硼酸二叔丁基甲基膦鎓盐文献

Catalytic intermolecular direct arylation of perfluorobenzenes.

J. Am. Chem. Soc. 128 , 8754, (2006)

Penta-, tetra-, tri-, and difluorobenzenes undergo direct arylation with a wide range of arylhalides in high yield. Inverse reactivity is observed compared to the common electrophilic aromatic substit...

Palladium-catalyzed direct arylation of nitro-substituted aromatics with aryl halides.

Org. Lett. 10 , 4533, (2008)

Direct arylation reactions of nitrobenzenes and aryl halides occur in good yield and high ortho regioselectivity. These reactions can be performed on gram scale with as few as 3 equiv of the nitro are...

Palladium-catalyzed direct heck arylation of dual pi-deficient/pi-excessive heteroaromatics. Synthesis of C-5 arylated imidazo[1,5-a]pyrazines.

Org. Lett. 10 , 2923, (2008)

A general and efficient synthesis of 5-aryl imidazo[1,5- a]pyrazines by palladium-catalyzed coupling of the corresponding 8-substituted derivatives with aryl halides is described. The scope of this ne...

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