邻苯二甲腈
邻苯二甲腈用途
广泛用于合成酞磺胺药物、酞菁颜料和染料、高热阻聚酰胺纤维、二甲苯基、二异氰酸酯塑料及脱硫催化剂等
【用途二】
广泛用于合成酞磺胺药物、酞菁颜料和染料、高热阻聚酰胺纤维、二甲苯基和二异氰酸酯塑料及脱硫催化剂等
【用途三】
用于染料、颜料及其他有机合成。
【用途四】
染料中间体。有机合成。
邻苯二甲腈名称
[ CAS 号 ]:
91-15-6
[ 中文名 ]:
1,2-二氰基苯
[ 英文名 ]:
Phthalonitrile
[中文别名 ]:
[英文别名 ]:
- o-Dicyanobenzene
- EINECS 202-044-8
- Phthalodinitril
- 1,2-DICYANOBENZENE
- o-pdn[qr]
- Phthalonitrile
- dicyanobenzene
- PHTHALICNITRILE
- o-PDN
- o-phthalonitrile
邻苯二甲腈物理化学性质
[ 密度 ]:
1.2±0.1 g/cm3
[ 沸点 ]:
304.6±25.0 °C at 760 mmHg
[ 熔点 ]:
137-139 °C(lit.)
[ 分子式 ]:
C8H4N2
[ 分子量 ]:
128.131
[ 闪点 ]:
153.3±17.1 °C
[ 精确质量 ]:
128.037445
[ PSA ]:
47.58000
[ LogP ]:
1.07
[ 外观性状 ]:
灰白色至黄褐色的粉末
[ 蒸汽压 ]:
0.0±0.6 mmHg at 25°C
[ 折射率 ]:
1.566
[ 储存条件 ]:
室温
[ 稳定性 ]:
Stable. Incompatible with strong bases, strong acids, strong oxidizing agents, strong reducing agents.
[ 水溶解性 ]:
0.56 g/L (25 ºC)
邻苯二甲腈MSDS
邻苯二甲腈毒性和生态
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- TI8575000
- CHEMICAL NAME :
- Phthalonitrile
- CAS REGISTRY NUMBER :
- 91-15-6
- LAST UPDATED :
- 199710
- DATA ITEMS CITED :
- 15
- MOLECULAR FORMULA :
- C8-H4-N2
- MOLECULAR WEIGHT :
- 128.14
- WISWESSER LINE NOTATION :
- NCR BCN
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 125 mg/kg
- TOXIC EFFECTS :
- Behavioral - convulsions or effect on seizure threshold
- REFERENCE :
- ZAARAM Zentralblatt fuer Arbeitsmedizin und Arbeitsschutz. (Darmstadt, Fed. Rep. Ger.) V.1-25, 1951-75. Volume(issue)/page/year: 19,225,1969
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 62 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- KJMDA6 Kobe Journal of the Medical Sciences. (Kobe Univ. School of Medicine, Kusunoki-cho, Chuo-ku, Kobe 650, Japan) V.1- 1951- Volume(issue)/page/year: 11,63,1965
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 65 mg/kg
- TOXIC EFFECTS :
- Behavioral - convulsions or effect on seizure threshold
- REFERENCE :
- INHEAO Industrial Health. (National Institute of Industrial Health, 6-21-1 Nagao, Tama-ku, Kawasaki, 213 Japan) V.1- 1963- Volume(issue)/page/year: 4,11,1966
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 25 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: AD277-689
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Subcutaneous
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 46 mg/kg
- TOXIC EFFECTS :
- Behavioral - convulsions or effect on seizure threshold
- REFERENCE :
- INHEAO Industrial Health. (National Institute of Industrial Health, 6-21-1 Nagao, Tama-ku, Kawasaki, 213 Japan) V.1- 1963- Volume(issue)/page/year: 4,11,1966
- TYPE OF TEST :
- LDLo - Lowest published lethal dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Mammal - cat
- DOSE/DURATION :
- 20 mg/kg
- TOXIC EFFECTS :
- Behavioral - convulsions or effect on seizure threshold
- REFERENCE :
- ZAARAM Zentralblatt fuer Arbeitsmedizin und Arbeitsschutz. (Darmstadt, Fed. Rep. Ger.) V.1-25, 1951-75. Volume(issue)/page/year: 19,225,1969
- TYPE OF TEST :
- LDLo - Lowest published lethal dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rabbit
- DOSE/DURATION :
- 25 mg/kg
- TOXIC EFFECTS :
- Behavioral - convulsions or effect on seizure threshold
- REFERENCE :
- ZAARAM Zentralblatt fuer Arbeitsmedizin und Arbeitsschutz. (Darmstadt, Fed. Rep. Ger.) V.1-25, 1951-75. Volume(issue)/page/year: 19,225,1969 ** TUMORIGENIC DATA **
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 7425 mg/kg/66W-I
- TOXIC EFFECTS :
- Tumorigenic - equivocal tumorigenic agent by RTECS criteria Liver - tumors Blood - leukemia
- REFERENCE :
- VOONAW Voprosy Onkologii. Problems of Oncology. For English translation, see PONCAU. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-10, 1928-37; V.1- 1955- Volume(issue)/page/year: 18(1),81,1972
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Subcutaneous
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 473 mg/kg/21W-I
- TOXIC EFFECTS :
- Tumorigenic - equivocal tumorigenic agent by RTECS criteria Liver - tumors Blood - leukemia
- REFERENCE :
- VOONAW Voprosy Onkologii. Problems of Oncology. For English translation, see PONCAU. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-10, 1928-37; V.1- 1955- Volume(issue)/page/year: 18(1),81,1972
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 21 gm/kg/65W-I
- TOXIC EFFECTS :
- Tumorigenic - equivocal tumorigenic agent by RTECS criteria Liver - tumors Blood - leukemia
- REFERENCE :
- VOONAW Voprosy Onkologii. Problems of Oncology. For English translation, see PONCAU. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-10, 1928-37; V.1- 1955- Volume(issue)/page/year: 18(1),81,1972
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 813 mg/kg/46W-I
- TOXIC EFFECTS :
- Tumorigenic - equivocal tumorigenic agent by RTECS criteria Blood - leukemia Reproductive - Tumorigenic effects - ovarian tumors
- REFERENCE :
- VOONAW Voprosy Onkologii. Problems of Oncology. For English translation, see PONCAU. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-10, 1928-37; V.1- 1955- Volume(issue)/page/year: 18(1),81,1972
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Subcutaneous
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 7 gm/kg/63W-I
- TOXIC EFFECTS :
- Tumorigenic - equivocal tumorigenic agent by RTECS criteria Blood - leukemia Tumorigenic - tumors at site of application
- REFERENCE :
- VOONAW Voprosy Onkologii. Problems of Oncology. For English translation, see PONCAU. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-10, 1928-37; V.1- 1955- Volume(issue)/page/year: 18(1),81,1972
邻苯二甲腈安全信息
[ 符号 ]:
GHS06
[ 信号词 ]:
Danger
[ 危害声明 ]:
H300
[ 警示性声明 ]:
P264-P301 + P310
[ 个人防护装备 ]:
Eyeshields;Faceshields;Gloves;type P2 (EN 143) respirator cartridges
[ 危害码 (欧洲) ]:
T:Toxic;
[ 风险声明 (欧洲) ]:
R23/24/25
[ 安全声明 (欧洲) ]:
S36/37/39-S45-S28A
[ 危险品运输编码 ]:
UN 3439 6.1/PG 2
[ WGK德国 ]:
1
[ RTECS号 ]:
TI8575000
[ 包装等级 ]:
II
[ 危险类别 ]:
6.1
[ 海关编码 ]:
2926909090
邻苯二甲腈合成路线
邻苯二甲腈上下游产品
邻苯二甲腈上游产品
邻苯二甲腈下游产品
邻苯二甲腈制备
邻苯二甲酰亚胺与氨反应得到酞酸酰胺后，再经脱水即制得邻苯二甲腈。另外，将苯酐氨化后再与三氯氧磷反应，或将萘五氨进行氨氧化反应，或由邻二甲苯与氨进行氨氧化反应都可制得该品。
邻苯二甲腈海关
[ 海关编码 ]: 2926909090
[ 中文概述 ]:
2926909090 其他腈基化合物. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:6.5% 普通关税:30.0%
[ 申报要素 ]: 品名, 成分含量, 用途
[ Summary ]:
HS:2926909090 other nitrile-function compounds VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%
邻苯二甲腈文献
Analyst 114(9) , 1009-12, (1989)
A method for the determination of emissions in workroom air as a result of the thermal degradation of polyester coating powders is described. The method is based on the determination of certain marker...
First example of a hexadentate bicyclic phthalocyanine analogue containing a divalent metal center.Dalton Trans. 42(47) , 16486-9, (2013)
A reaction of 1,2-dicyanobenzene and lithium methoxide at 70 °C in methanol yielded the half-phthalocyanine intermediate, which coordinates to a cadmium(II) ion in the subsequent reaction step to give...
An estimation of the sublimation rate of o-phthalodinitrile and acrylamide during filter sampling.Ind. Health 23(2) , 167-70, (1985)
相关化工产品/化学物质：
推荐生产厂家/供应商：
公司名：上海化源世纪贸易有限公司
区域：上海市普陀区
价格：
联系人：徐经理
产品详情：1,2-二氰基苯
公司名：上海吉至生化科技有限公司
区域：上海市奉贤区
价格：
￥318.0/500g
￥108.0/100g
联系人：刘佳
产品详情：邻苯二甲腈
公司名：上海阿拉丁生化科技股份有限公司
区域：上海市浦东新区
价格：
￥121.9/100g
￥40.9/25g
￥446.9/500g
￥1871.9/3kg
联系人：阿拉丁
产品详情：邻苯二甲腈
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相关化合物
【邻苯二甲腈】化源网提供邻苯二甲腈CAS号91-15-6，邻苯二甲腈MSDS及其说明、性质、英文名、生产厂家、作用/用途、分子量、密度、沸点、熔点、结构式等。CAS号查询邻苯二甲腈上化源网，专业又轻松。>>电脑版：邻苯二甲腈
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