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2-巯基萘

2-巯基萘用途

【用途一】
在橡胶工业中用作再生活化剂，适于低温使用，但活化效果不及芒香族二硫化物，而且使再生胶带有难闻的气味。一般用量为0.1-1.5%，该品也可用作防老剂、增塑剂和有机合成的中间体。2-萘硫酚有毒，能引起皮炎和溃疡。

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2-巯基萘名称

[ CAS 号 ]:
91-60-1

[ 中文名 ]:
2-萘硫醇

[ 英文名 ]:
2-Naphthalenethiol

[中文别名 ]:

[英文别名 ]:

2-Naphthalenethiol
β-Mercaptonaphthalene
MFCD00004868
Naphthalen-2-thiol
EINECS 202-082-5
Naphthalene-2-thiol
β-Naphthalenethiol

2-巯基萘物理化学性质

[ 密度 ]:
1.2±0.1 g/cm3

[ 沸点 ]:
286.0±0.0 °C at 760 mmHg

[ 熔点 ]:
79-81 °C(lit.)

[ 分子式 ]:
C₁₀H₈S

[ 分子量 ]:
160.236

[ 闪点 ]:
134.2±16.7 °C

[ 精确质量 ]:
160.034668

[ PSA ]:
38.80000

[ LogP ]:
3.75

[ 外观性状 ]:
近乎于白色至奶油色粉末

[ 蒸汽压 ]:
0.0±0.5 mmHg at 25°C

[ 折射率 ]:
1.694

[ 储存条件 ]:
存放于惰性气体之中;避免空气

[ 水溶解性 ]:
水溶性：微溶；可溶于：乙醚,乙醇

2-巯基萘MSDS

2-巯基萘毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: QK3930000

CHEMICAL NAME :: 2-Naphthalenethiol

CAS REGISTRY NUMBER :: 91-60-1

BEILSTEIN REFERENCE NO. :: 0636389

LAST UPDATED :: 199710

DATA ITEMS CITED :: 6

MOLECULAR FORMULA :: C10-H8-S

MOLECULAR WEIGHT :: 160.24

WISWESSER LINE NOTATION :: L66J CSH

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 385 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: DCTODJ Drug and Chemical Toxicology. (Marcel Dekker, 270 Madison Ave., New York, NY 10016) V.1- 1977/78- Volume(issue)/page/year: 3,249,1980

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 200 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: AD277-689 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - M0815 No. of Facilities: 23 (estimated) No. of Industries: 1 No. of Occupations: 5 No. of Employees: 455 (estimated)

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2-巯基萘安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H302

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Faceshields;Gloves

[ 危害码 (欧洲) ]:
Xn:Harmful;

[ 风险声明 (欧洲) ]:
R20/21/22

[ 安全声明 (欧洲) ]:
S36/37

[ 危险品运输编码 ]:
UN 3335 9

[ WGK德国 ]:
3

[ RTECS号 ]:
QK3930000

[ 海关编码 ]:
2930909090

2-巯基萘合成路线

2-巯基萘上下游产品

2-巯基萘上游产品

2-巯基萘下游产品

2-巯基萘制备

先将2-萘酚与二甲氨基硫代甲酰氯在碱存在反应制得O-2萘基二甲氨基硫代甲酸酯，经精制各加热至270-275℃，反应45min。冷却后加入氢氧化钾溶液和乙二醇的混合液中，加热回流1h。经盐酸化，氯仿提取，减仿提取，减压蒸馏，即得2-萘硫酚

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2-巯基萘海关

[ 海关编码 ]: 2930909090

[ 中文概述 ]:
2930909090. 其他有机硫化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

2-巯基萘文献

Direct identification of on-bead peptides using surface-enhanced Raman spectroscopic barcoding system for high-throughput bioanalysis.

Sci. Rep. 5 , 10144, (2015)

Recently, preparation and screening of compound libraries remain one of the most challenging tasks in drug discovery, biomarker detection, and biomolecular profiling processes. So far, several distinc...

Exploring the boundaries of a light-driven molecular motor design: new sterically overcrowded alkenes with preferred direction of rotation.

Org. Biomol. Chem. 2(10) , 1531-41, (2004)

Insight in the steric and electronic parameters governing isomerization processes in artificial molecular motors is essential in order to design more advanced motor systems. A subtle balance of steric...

Protein separation and identification using magnetic beads encoded with surface-enhanced Raman spectroscopy.

Anal. Biochem. 391(1) , 24-30, (2009)

This article presents a prototype of a surface-enhanced Raman spectroscopy (SERS)-encoded magnetic bead of 8mum diameter. The core part of the bead is composed of a magnetic nanoparticle (NP)-embedded...

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2-巯基萘

2-巯基萘用途

2-巯基萘名称

2-巯基萘物理化学性质

2-巯基萘MSDS

详细MSDS(安全技术说明书)

2-巯基萘毒性和生态

CHEMICAL IDENTIFICATION

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

2-巯基萘安全信息

2-巯基萘合成路线

详细合成路线

2-巯基萘上下游产品

2-巯基萘上游产品

2-巯基萘下游产品

2-巯基萘制备

2-巯基萘海关

2-巯基萘文献

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