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6-甲基喹啉

6-甲基喹啉用途

【用途一】
用于有机合成
【用途二】
可用于蜜香型、百花型、紫丁香型、铃兰型、依兰型、茉莉型、烟草型、橡苔型等香精配方，以增强加重气息。也常与橡苔或树苔制品、依兰、乙酸苯乙酯共用于有色皂用香精中。

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6-甲基喹啉名称

[ CAS 号 ]:
91-62-3

[ 中文名 ]:
6-甲基喹啉

[ 英文名 ]:
6-Methylquinoline

[中文别名 ]:

[英文别名 ]:

6-Methylquinoline
p-Toluquinoline
Tolliquinoline,p
MFCD00006804
EINECS 202-084-6
6-methyl quinoline
6-Methyl-chinolin
Quinoline,6-methyl
Quinoline, 6-methyl-

6-甲基喹啉物理化学性质

[ 密度 ]:
1.1±0.1 g/cm3

[ 沸点 ]:
258.6±0.0 °C at 760 mmHg

[ 熔点 ]:
-22°C

[ 分子式 ]:
C₁₀H₉N

[ 分子量 ]:
143.185

[ 闪点 ]:
104.4±11.3 °C

[ 精确质量 ]:
143.073502

[ PSA ]:
12.89000

[ LogP ]:
2.54

[ 外观性状 ]:
黄色液体

[ 蒸汽密度 ]:
>1 (vs air)

[ 蒸汽压 ]:
0.0±0.5 mmHg at 25°C

[ 折射率 ]:
1.625

[ 储存条件 ]:
库房通风低温干燥,与食品原料分开储运

6-甲基喹啉MSDS

6-甲基喹啉毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: VC0550000

CHEMICAL NAME :: Quinoline, 6-methyl-

CAS REGISTRY NUMBER :: 91-62-3

BEILSTEIN REFERENCE NO. :: 0110336

LAST UPDATED :: 199712

DATA ITEMS CITED :: 7

MOLECULAR FORMULA :: C10-H9-N

MOLECULAR WEIGHT :: 143.20

WISWESSER LINE NOTATION :: T66 BNJ H1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 800 mg/kg

TOXIC EFFECTS :: Behavioral - somnolence (general depressed activity) Behavioral - muscle contraction or spasticity Lungs, Thorax, or Respiration - respiratory stimulation

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 386 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 5 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

MUTATION DATA

TYPE OF TEST :: Mutation in microorganisms

TEST SYSTEM :: Bacteria - Salmonella typhimurium

DOSE/DURATION :: 25 ug/plate

REFERENCE :: APTOD9 Abstracts of Papers, Society of Toxicology. Annual Meetings. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) Volume(issue)/page/year: 19,A105,1980

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6-甲基喹啉安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H302-H315

[ 警示性声明 ]:
P301 + P312 + P330

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
Xn:Harmful;

[ 风险声明 (欧洲) ]:
R22;R36/37/38;R68

[ 安全声明 (欧洲) ]:
S26-S36-S45-S36/37/39

[ 危险品运输编码 ]:
2810.0

[ WGK德国 ]:
3

[ RTECS号 ]:
VC0550000

[ 危险类别 ]:
6.1

[ 海关编码 ]:
29334990

6-甲基喹啉合成路线

6-甲基喹啉上下游产品

6-甲基喹啉上游产品

6-甲基喹啉下游产品

6-甲基喹啉海关

[ 海关编码 ]: 2933499090

[ 中文概述 ]:
2933499090. 其他含喹琳或异喹啉环系的化合物〔但未进一步稠合的〕. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 乌洛托品请注明外观, 6－己内酰胺请注明外观, 签约日期

[ Summary ]:
2933499090. other compounds containing in the structure a quinoline or isoquinoline ring-system (whether or not hydrogenated), not further fused. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

6-甲基喹啉文献

Chloride-sensitive fluorescent indicators.

Anal. Biochem. 293(1) , 60-6, (2001)

Three fluorescent halide-sensitive quinolinium dyes have been produced by the reaction of the 6-methylquinoline heterocyclic nitrogen base with methyl bromide, methyl iodide, and 3-bromo-1-propanol. T...

Hydroxylation and biodegradation of 6-methylquinoline by pseudomonads in aqueous and nonaqueous immobilized-cell bioreactors.

Appl. Environ. Microbiol. 59(7) , 2139-44, (1993)

Selective culturing of pseudomonads that could degrade quinoline led to enrichment cultures and pure cultures with expanded substrate utilization and transformation capabilities for substituted quinol...

The hepatic metabolism of two methylquinolines.

Carcinogenesis 14(5) , 1041-7, (1993)

The hepatic microsomal metabolism of the carcinogenic 8-methylquinoline (8MQ) and its noncarcinogenic isomer, 6-methylquinoline (6MQ), were compared for preparations from control rats and rats pretrea...

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