N-苯基马来酰亚胺

N-苯基马来酰亚胺用途

N-苯基马来酰亚胺（N-PMI）在天然橡胶和合成橡胶中可作为硫化交联剂，在ABS、PVC、PMMA树脂和感光材料中作为耐热改性剂，可提高树脂的耐热性，耐冲击性，热熔性和加工性等。N-PMI可用作树脂中间体，用来制造耐热聚合物，植物生长促进剂等农用化学品，N-PMI还有一定的抗菌活性。

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N-苯基马来酰亚胺名称

[ CAS 号 ]:
941-69-5

[ 中文名 ]:
N-苯基马来酰亚胺

[ 英文名 ]:
N-Phenylmaleimide

[中文别名 ]:

[英文别名 ]:

N-Phenylmaleimide
N-Phenylmaleimide(N-PMI)
Maleanil
EINECS 213-382-0
phenylmaleimide
1-phenylpyrrole-2,5-dione
MFCD00005502
1-Phenyl-1H-pyrrole-2,5-dione
1-phenyl-2,5-dihydro-1H-pyrrole-2,5-dione
1H-Pyrrole-2,5-dione, 1-phenyl-

N-苯基马来酰亚胺物理化学性质

[ 密度 ]:
1.3±0.1 g/cm3

[ 沸点 ]:
299.3±9.0 °C at 760 mmHg

[ 熔点 ]:
85-87 °C(lit.)

[ 分子式 ]:
C₁₀H₇NO₂

[ 分子量 ]:
173.168

[ 闪点 ]:
136.8±11.1 °C

[ 精确质量 ]:
173.047684

[ PSA ]:
37.38000

[ LogP ]:
1.09

[ 外观性状 ]:
黄色结晶粉末或针状

[ 蒸汽压 ]:
0.0±0.6 mmHg at 25°C

[ 折射率 ]:
1.630

[ 储存条件 ]:
室温

[ 水溶解性 ]:
水溶性：微溶；可溶于：苯,乙醇,甲醇

N-苯基马来酰亚胺MSDS

N-苯基马来酰亚胺毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: ON5950000

CHEMICAL NAME :: Maleimide, N-phenyl-

CAS REGISTRY NUMBER :: 941-69-5

BEILSTEIN REFERENCE NO. :: 0125098

LAST UPDATED :: 199710

DATA ITEMS CITED :: 8

MOLECULAR FORMULA :: C10-H7-N-O2

MOLECULAR WEIGHT :: 173.18

WISWESSER LINE NOTATION :: T5VNVJ BR

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

REFERENCE :: SCCUR* Shell Chemical Company. Unpublished Report. (2401 Crow Canyon Rd., San Romon, CA 94583) Volume(issue)/page/year: -,8,1961 ** ACUTE TOXICITY DATA **

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 188 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: SCCUR* Shell Chemical Company. Unpublished Report. (2401 Crow Canyon Rd., San Romon, CA 94583) Volume(issue)/page/year: -,8,1961

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 25 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: NCNSA6 National Academy of Sciences, National Research Council, Chemical-Biological Coordination Center, Review. (Washington, DC) Volume(issue)/page/year: 5,22,1953

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 78 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: SCCUR* Shell Chemical Company. Unpublished Report. (2401 Crow Canyon Rd., San Romon, CA 94583) Volume(issue)/page/year: -,8,1961

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 100 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: SCCUR* Shell Chemical Company. Unpublished Report. (2401 Crow Canyon Rd., San Romon, CA 94583) Volume(issue)/page/year: -,8,1961 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X9528 No. of Facilities: 10 (estimated) No. of Industries: 1 No. of Occupations: 2 No. of Employees: 30 (estimated) No. of Female Employees: 20 (estimated)

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N-苯基马来酰亚胺安全信息

[ 符号 ]:

GHS05, GHS06, GHS09

[ 信号词 ]:
Danger

[ 危害声明 ]:
H301-H315-H317-H318-H400

[ 警示性声明 ]:
P273-P280-P301 + P310-P305 + P351 + P338

[ 个人防护装备 ]:
Eyeshields;Faceshields;Gloves;type P2 (EN 143) respirator cartridges

[ 危害码 (欧洲) ]:
T:Toxic;

[ 风险声明 (欧洲) ]:
R25;R36/37/38

[ 安全声明 (欧洲) ]:
S45-S24/25

[ 危险品运输编码 ]:
UN 2811 6.1/PG 3

[ WGK德国 ]:
3

[ RTECS号 ]:
ON5950000

[ 包装等级 ]:
III

[ 危险类别 ]:
6.1

[ 海关编码 ]:
2925190090

N-苯基马来酰亚胺合成路线

N-苯基马来酰亚胺上下游产品

N-苯基马来酰亚胺上游产品

N-苯基马来酰亚胺下游产品

N-苯基马来酰亚胺制备

通过马来酸酐与苯胺反应制得。简单流程如下。

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N-苯基马来酰亚胺海关

[ 海关编码 ]: 2925190090

[ 中文概述 ]:
2925190090 其他酰亚胺及其衍生物盐. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:6.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2925190090 other imides and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

N-苯基马来酰亚胺文献

Michael addition/pericyclization/rearrangement--a multicomponent strategy for the synthesis of substituted resorcinols.

Org. Biomol. Chem. 10(31) , 6388-94, (2012)

The combination of methyl 3,7-dioxo-2-diazo-4-octenoate from the zinc triflate catalyzed Mukaiyama-Michael reaction of methyl 3-tert-butylsilyloxy-2-diazobutenoate and 4-methoxy-3-buten-2-one with Mic...

Chemical modification of milk xanthine oxidase with different modifiers.

Prep Biochem Biotechnol. 33(3) , 173-87, (2003)

Xanthine oxidase (XO), purified from buttermilk was subjected to modification with N-phenylmaleimide, p-toluene-sulfonyl chloride, and 2-mercaptobenzimidazole. Spectrophotometric monitoring of the enz...

Behavior of N-phenylmaleimide- and p-phenylenedimaleimide-reacted muscle crossbridge heads.

Biochim. Biophys. Acta 1367(1-3) , 127-33, (1998)

The finding of Barnett et al. (Biophys. J. 61 (1992) 358) that NPM-reacted crossbridge heads do not bind strongly to actin in rigor solution is not easily interpreted in terms of the solution studies ...

更多文献

N-苯基马来酰亚胺

N-苯基马来酰亚胺用途

N-苯基马来酰亚胺名称

N-苯基马来酰亚胺物理化学性质

N-苯基马来酰亚胺MSDS

详细MSDS(安全技术说明书)

N-苯基马来酰亚胺毒性和生态

CHEMICAL IDENTIFICATION

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

N-苯基马来酰亚胺安全信息

N-苯基马来酰亚胺合成路线

详细合成路线

N-苯基马来酰亚胺上下游产品

N-苯基马来酰亚胺上游产品

N-苯基马来酰亚胺下游产品

N-苯基马来酰亚胺制备

N-苯基马来酰亚胺海关

N-苯基马来酰亚胺文献

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