苦氨酸
苦氨酸用途
用于制造偶氮染料、分析试剂、指示剂等。
苦氨酸名称
[ CAS 号 ]:
96-91-3
[ 中文名 ]:
2-氨基-4,6-二硝基苯酚
[ 英文名 ]:
Picramic acid
[中文别名 ]:
[英文别名 ]:
- MFCD00070534
- EINECS 202-544-6
- 4,6-dinitro-2-aminophenol
- Zoba 4R
- 2-amino-4,6-DNP
- 1-amino-2-hydroxy-3,5-dinitrobenzene
- 2-amino-4,6-dinitro-1-hydroxybenzene
- 1-hydroxy-2-amino-4,6-dinitrobenzene
- Furro 4R
- Fourrine 4R
苦氨酸物理化学性质
[ 密度 ]:
1.749 g/cm 3
[ 沸点 ]:
386.3ºC at 760 mmHg
[ 熔点 ]:
169°C
[ 分子式 ]:
C6H5N3O5
[ 分子量 ]:
199.12100
[ 闪点 ]:
187.5ºC
[ 精确质量 ]:
199.02300
[ PSA ]:
137.89000
[ LogP ]:
2.41840
[ 外观性状 ]:
棕色糊
[ 折射率 ]:
1.73
[ 储存条件 ]:
库房通风低温干燥,与氧化剂、酸类分开存放
[ 稳定性 ]:
Stable. Combustible - burns rapidly: dangerous fire risk. Do not subject to shock, friction or heat. Incompatible with strong oxidizing agents.
[ 水溶解性 ]:
<0.1 g/100 mL at 20.5 ºC
苦氨酸MSDS
苦氨酸毒性和生态
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- SJ5800000
- CHEMICAL NAME :
- Phenol, 2-amino-4,6-dinitro-
- CAS REGISTRY NUMBER :
- 96-91-3
- BEILSTEIN REFERENCE NO. :
- 0989416
- LAST UPDATED :
- 199612
- DATA ITEMS CITED :
- 5
- MOLECULAR FORMULA :
- C6-H5-N3-O5
- MOLECULAR WEIGHT :
- 199.14
- WISWESSER LINE NOTATION :
- WNR CZ DQ ENW
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LDLo - Lowest published lethal dose
- ROUTE OF EXPOSURE :
- Subcutaneous
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 2100 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LDLo - Lowest published lethal dose
- ROUTE OF EXPOSURE :
- Intravenous
- SPECIES OBSERVED :
- Mammal - dog
- DOSE/DURATION :
- 150 mg/kg
- TOXIC EFFECTS :
- Behavioral - convulsions or effect on seizure threshold Cardiac - other changes Gastrointestinal - hypermotility, diarrhea
- TYPE OF TEST :
- LDLo - Lowest published lethal dose
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Bird - pigeon
- DOSE/DURATION :
- 140 mg/kg
- TOXIC EFFECTS :
- Behavioral - altered sleep time (including change in righting reflex) Behavioral - rigidity (including catalepsy) Lungs, Thorax, or Respiration - dyspnea
- TYPE OF TEST :
- LDLo - Lowest published lethal dose
- ROUTE OF EXPOSURE :
- Intramuscular
- SPECIES OBSERVED :
- Bird - pigeon
- DOSE/DURATION :
- 100 mg/kg
- TOXIC EFFECTS :
- Nutritional and Gross Metabolic - body temperature increase
MUTATION DATA
- TYPE OF TEST :
- Mutation in microorganisms
- TEST SYSTEM :
- Bacteria - Salmonella typhimurium
- DOSE/DURATION :
- 5 umol/plate
- REFERENCE :
- NEZAAQ Nippon Eiseigaku Zasshi. Japanese Journal of Hygiene. (Nippon Eisei Gakkai, c/o Kyoto Daigaku Igakubu, Konoe-cho, Yoshida, Sakyo-ku, Kyoto 606, Japan) V.1- 1946- Volume(issue)/page/year: 38,533,1983
苦氨酸安全信息
[ 危害码 (欧洲) ]:
E,Xn
[ 风险声明 (欧洲) ]:
R1
[ 安全声明 (欧洲) ]:
S35-S61
[ 危险品运输编码 ]:
3317
[ RTECS号 ]:
SJ5800000
[ 包装等级 ]:
II
[ 危险类别 ]:
4.1
[ 海关编码 ]:
2922299090
苦氨酸合成路线
苦氨酸上下游产品
苦氨酸上游产品
苦氨酸下游产品
苦氨酸制备
由2，4，6-三硝基苯酚用硫氢化钠部分还原或在硫酸钒的酒精硫酸溶液中进行电解还原制得。
苦氨酸海关
[ 海关编码 ]: 2922299090
[ 中文概述 ]:
2922299090. 其他氨基(萘酚、酚)及醚、酯〔包括它们的盐, 但含有一种以上含氧基的除外〕. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%
[ 申报要素 ]: 品名, 成分含量, 用途, 乙醇胺及其盐应报明色度, 乙醇胺及其盐应报明包装
[ Summary ]:
2922299090. other amino-naphthols and other amino-phenols, other than those containing more than one kind of oxygen function, their ethers and esters; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%
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