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四丁基溴化铵

四丁基溴化铵用途

【用途一】
用作有机合成中间体，相转移催化剂
【用途二】
离子对试剂，用于巴氨西林、舒他西林等的合成。
【用途三】
离子对色谱试剂，相转移催化剂。巴氨西林、舒他西林等的合成。

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四丁基溴化铵名称

[ CAS 号 ]:
1643-19-2

[ 中文名 ]:
四丁基溴化铵

[ 英文名 ]:
Tetrabutylammonium bromide

[中文别名 ]:

[英文别名 ]:

Tetrabutyl ammonium bromide
tetra-n-butyl-ammonium bromide
Tetrabutylammonium b
TBAB
IPC-TBA-BR
tetrabutylammomium bromide
N,N,N-tributylbutan-1-aminium bromide
Tetrabutyl
TETRABUTYL AMONIUM BROMIDE
aliquat 100

四丁基溴化铵物理化学性质

[ 密度 ]:
1.039 g/mL at 25 °C

[ 沸点 ]:
102 °C

[ 熔点 ]:
102-106 °C(lit.)

[ 分子式 ]:
C₁₆H₃₆BrN

[ 分子量 ]:
322.368

[ 精确质量 ]:
321.203094

[ LogP ]:
2.00760

[ 外观性状 ]:
白色至灰白色结晶粉末

[ 折射率 ]:
n20/D 1.422

[ 储存条件 ]:
Store at RT.

[ 稳定性 ]:
Stable. Incompatible with strong oxidizing agents. Protect from moisture.

[ 水溶解性 ]:
600 g/L (20 ºC)

四丁基溴化铵MSDS

详细MSDS(安全技术说明书)

四丁基溴化铵安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H315-H319-H335

[ 警示性声明 ]:
P261-P305 + P351 + P338

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xi: Irritant;Xn: Harmful;

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
S26-S36-S37/39

[ 危险品运输编码 ]:
3077.0

[ WGK德国 ]:
3

[ 海关编码 ]:
2923900090

四丁基溴化铵上下游产品

四丁基溴化铵上游产品

四丁基溴化铵下游产品

四丁基溴化铵海关

[ 海关编码 ]: 2923900090

[ 中文概述 ]:
2923900090 其他季铵盐及季铵碱。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:6.5%。普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2923900090 other quaternary ammonium salts and hydroxides。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

四丁基溴化铵文献

High-turnover hypoiodite catalysis for asymmetric synthesis of tocopherols.

Science 345(6194) , 291-4, (2014)

The diverse biological activities of tocopherols and their analogs have inspired considerable interest in the development of routes for their efficient asymmetric synthesis. Here, we report that chira...

Tandem cyclization of α-cyano α-alkynyl aryl ketones induced by tert-butyl hydroperoxide and tetrabutylammonium iodide.

Org. Lett. 14(23) , 6024-7, (2012)

The radical cascade protocol of the α-cyano α-TMS/aryl-capped alkynyl aryl ketones promoted by tert-butyl hydroperoxide under catalysis with tetrabutylammonium iodide in refluxing benzene has been dev...

Tetragonal Cu2Se nanoflakes: synthesis using selenated propylamine as Se source and activation of Suzuki and Sonogashira cross coupling reactions.

Dalton Trans. 44(2) , 725-32, (2014)

The metastable tetragonal Cu2Se phase as nanoflakes has been synthesized for the first time by treating CuCl2 taken in a mixture (1:1) of 1-octadecene and oleylamine with H2N-(CH2)3-SePh dissolved in ...

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