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溴化苄

溴化苄用途

【用途一】
用于有机合成及作泡沫剂和酵母防腐剂
【用途二】
用于发泡剂的制造，也用作有机合成中间体
【用途三】
有机合成中间体、发泡剂的原料。

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溴化苄名称

[ CAS 号 ]:
100-39-0

[ 中文名 ]:
溴化苄

[ 英文名 ]:
Benzyl bromide

[中文别名 ]:

[英文别名 ]:

α-bromo toluene
Benzybromide
α-BROMOTOLUENE
Benzene, (bromomethyl)-
EINECS 202-847-3
benzylbromide
Bromo Thluene
A-BROMOTOLUENE
1-Bromotoluene
cyclite

溴化苄物理化学性质

[ 密度 ]:
1.4±0.1 g/cm3

[ 沸点 ]:
198.5±0.0 °C at 760 mmHg

[ 熔点 ]:
-3 °C

[ 分子式 ]:
C₇H₇Br

[ 分子量 ]:
171.035

[ 闪点 ]:
86.7±0.0 °C

[ 精确质量 ]:
169.973099

[ LogP ]:
2.92

[ 外观性状 ]:
透明至淡黄色液体

[ 蒸汽密度 ]:
5.8 (vs air)

[ 蒸汽压 ]:
0.5±0.3 mmHg at 25°C

[ 折射率 ]:
1.568

[ 储存条件 ]:
库房通风低温干燥,与氧化剂、食品添加剂分开存放

[ 稳定性 ]:
Stable. Combustible. Incompatible with strong oxidizing agents.

[ 水溶解性 ]:
混溶：乙醚；可溶于：苯

溴化苄MSDS

溴化苄毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: XS7965000

CHEMICAL NAME :: Toluene, alpha-bromo-

CAS REGISTRY NUMBER :: 100-39-0

LAST UPDATED :: 199707

DATA ITEMS CITED :: 4

MOLECULAR FORMULA :: C7-H7-Br

MOLECULAR WEIGHT :: 171.05

WISWESSER LINE NOTATION :: E1R

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

MUTATION DATA

TYPE OF TEST :: Sister chromatid exchange

TEST SYSTEM :: Rodent - hamster Ovary

DOSE/DURATION :: 30 umol/L

REFERENCE :: JJATDK JAT, Journal of Applied Toxicology. (John Wiley & Sons Ltd., Baffins Lane, Chichester, W. Sussex PO19 1UD, UK) V.1- 1981- Volume(issue)/page/year: 3,203,1983

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溴化苄安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H315-H319-H335

[ 警示性声明 ]:
P261-P305 + P351 + P338

[ 个人防护装备 ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
Xi:Irritant;

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
S39-S2

[ 危险品运输编码 ]:
UN 1737 6.1/PG 2

[ WGK德国 ]:
2

[ RTECS号 ]:
XS7965000

[ 包装等级 ]:
II

[ 危险类别 ]:
6.1

[ 海关编码 ]:
2827590000

溴化苄合成路线

溴化苄上下游产品

溴化苄上游产品

溴化苄下游产品

溴化苄制备

由甲苯溴化而得。将甲苯加热到50℃，加溴反应，反应温度为75-80℃，反应6h，在常压下分馏除去140℃以前的馏分，然后减压蒸馏，收集112-114℃（2.0kPa）馏分，得苄基溴。

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溴化苄海关

[ 海关编码 ]: 2903999090

[ 中文概述 ]:
2903999090 其他芳烃卤化衍生物. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:5.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

溴化苄文献

Structure-activity relationships of a novel pyranopyridine series of Gram-negative bacterial efflux pump inhibitors.

Bioorg. Med. Chem. 23(9) , 2024-34, (2015)

Recently we described a novel pyranopyridine inhibitor (MBX2319) of RND-type efflux pumps of the Enterobacteriaceae. MBX2319 (3,3-dimethyl-5-cyano-8-morpholino-6-(phenethylthio)-3,4-dihydro-1H-pyrano[...

Opposite regiospecific ring opening of 2-(cyanomethyl)aziridines by hydrogen bromide and benzyl bromide: experimental study and theoretical rationalization.

J. Org. Chem. 75(13) , 4530-41, (2010)

Ring opening of 1-arylmethyl-2-(cyanomethyl)aziridines with HBr afforded 3-(arylmethyl)amino-4-bromobutyronitriles via regiospecific ring opening at the unsubstituted aziridine carbon. Previous experi...

Synthesis and Catalytic Performance of Hierarchically Porous MIL-100(Fe)@polyHIPE Hybrid Membranes.

Macromol. Rapid Commun. 36 , 1605-11, (2015)

Metal-organic frameworks (MOFs) nanoparticles in combination with a nonionic surfactant (Pluronic L-121) are used to stabilize dicyclopentadiene (DCPD)-in-water high internal phase emulsions (HIPEs). ...

更多文献

溴化苄

溴化苄用途

溴化苄名称

溴化苄物理化学性质

溴化苄MSDS

详细MSDS(安全技术说明书)

溴化苄毒性和生态

CHEMICAL IDENTIFICATION

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

MUTATION DATA

溴化苄安全信息

溴化苄合成路线

详细合成路线

溴化苄上下游产品

溴化苄上游产品

溴化苄下游产品

溴化苄制备

溴化苄海关

溴化苄文献

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