Tetrahedron letters

One-step conversion of flavanones into isoflavones: a new facile biomimetic synthesis of isoflavones

T Kinoshita, K Ichinose, U Sankawa

文献索引：Kinoshita, Takeshi; Ichinose, Koji; Sankawa, Ushio Tetrahedron Letters, 1990 , vol. 31, # 50 p. 7355 - 7356

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被引用次数: 26

摘要

Abstract One-step chemical conversion of flavanones into isoflavones by use of thallium trinitrate (TIN) is reported, and the mechanism of a 2, 3-aryl migration in this reaction is discussed in relation to in vivo rearrangement process of flavanone precursors in the isoflavone biosynthesis.