Palladium-Catalyzed Saegusa–Ito Oxidation: Synthesis of α, β-Unsaturated Carbonyl Compounds from Trimethylsilyl Enol Ethers

…, PL Nguyen, N Lévaray, H Lebel

文献索引：Lu, Yingdong; Nguyen, Pierre Long; Levaray, Nicolas; Lebel, Heleine Journal of Organic Chemistry, 2013 , vol. 78, # 2 p. 776 - 779

全文：HTML全文

被引用次数: 15

摘要

Palladium-catalyzed Saegusa–Ito oxidation of trimethylsilyl enol ethers is possible using Oxone as a stoichiometric oxidant and sodium hydrogen phosphate as a buffer. Cyclic and acyclic enones as well as α, β-unsaturated aldehydes are obtained in good to excellent yields.