Tetrahedron

Reducing versus basic properties of 1, 2-diaryl-1, 2-disodioethanes

U Azzena, G Dettori, L Pisano, M Pittalis

文献索引：Azzena, Ugo; Dettori, Giovanna; Pisano, Luisa; Pittalis, Mario Tetrahedron, 2011 , vol. 67, # 19 p. 3470 - 3475

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被引用次数: 5

摘要

Abstract The outcome of the reaction between halogenated arylacetic acids and 1, 2-diaryl- 1, 2-disodioethanes strongly depends on the nature of both reaction partners, and it can be rationalized in terms of a competition between reducing and basic properties of the vic- diorganometals, as well as of the ease of the reductive cleavage of the different carbon– halide bonds. As an application of these findings, we developed a particularly mild ...