Tetrahedron letters

A convenient method for phosphorylation involving a facile oxidation of H-phosphonate monoesters via bis (trimethylsilyl) phosphites

T Wada, A Mochizuki, Y Sato, M Sekine

文献索引：Wada, Takeshi; Mochizuki, Akira; Sato, Yuichi; Sekine, Mitsuo Tetrahedron Letters, 1998 , vol. 39, # 39 p. 7123 - 7126

全文：HTML全文

被引用次数: 49

摘要

A new convenient route to phosphate monoesters from alcohols has been developed. H- Phosphonate monoesters, which are readily accessible by phosphonylation of the parent alcohols, were oxidized with t-BuOOH or N-sulfonyloxaziridines under anhydrous conditions via the corresponding bis (trimethylsilyl) phosphites. N, O-Bis (trimethylsilyl) benzamide (BSB) and (camphorsulfonyl) oxaziridine (CSO) were found to be highly effective for ...