Oxidative decyanation of secondary nitriles to ketones
RW Freerksen, SJ Selikson, RR Wroble…
文献索引：Freerksen, Robert W.; Selikson, Sandra J.; Wroble, Randall R.; Kyler, S. Keith; Watt, David S. Journal of Organic Chemistry, 1983 , vol. 48, # 22 p. 4087 - 4096
Procedures for the oxidative decyanation of secondary nitriles to ketones involve (1) iodination of N-(trialkylsily1) ketenimines derived from secondary nitriles and subsequent hydrolysis of the dodo nitriles with silver oxide,(2) addition of nitrosobenzene to N- (trialkylsilyl) ketenimines,(3) conversion of secondary nitriles to a-(phenylthio) nitriles and subsequent hydrolysis with N-bromosuccinimide in aqueous acetonitrile, and (4) ...
![2-(10,13-dimethyl-1,2,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydrospiro[cyclopenta[a]phenanthrene-3,2'-[1,3]dioxolan]-17-yl)propanenitrile结构式](https://image.chemsrc.com/caspic/007/58462-92-3.png)
