Tetrahedron letters

Aminolysis of allyl esters with bislithium aryl amides

CA Faler, MM Joullié

文献索引：Faler, Catherine A.; Joullie, Madeleine M. Tetrahedron Letters, 2006 , vol. 47, # 40 p. 7229 - 7231

被引用次数: 17

摘要

The aminolysis of allyl esters with bislithium amides is reported. Tertiary aryl amides were synthesized in a one-pot reaction with bislithium amides and a suitable electrophile in good yields. The scope of this reaction was demonstrated with a variety of anilines and aminopyridines and applied to the synthesis of triphenylmethylacetamides.

~96%

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~71%

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~85%

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~64%

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~60%

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~84%

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~68%

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~58%

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~95%

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~68%

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~21%

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~57%

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Reactions of Triphenylmethylmagnesium Bromide. II

[Bachmann; Cockerill Journal of the American Chemical Society, 1933 , vol. 55, p. 2932]

Thermal decomposition of methyl and phenyl triphenylmethylaz...

[Zabel,D.E.; Trahanovsky,W.S. Journal of Organic Chemistry, 1972 , vol. 37, # 15 p. 2413 - 2418]

Reactions of Triphenylmethylmagnesium Bromide. II

[Bachmann; Cockerill Journal of the American Chemical Society, 1933 , vol. 55, p. 2932]

Thermal decomposition of methyl and phenyl triphenylmethylaz...

[Zabel,D.E.; Trahanovsky,W.S. Journal of Organic Chemistry, 1972 , vol. 37, # 15 p. 2413 - 2418]