Journal of fluorine chemistry

The Bamberger reaction in hydrogen fluoride: the use of mild reductive metals for the preparation of fluoroaromatic amines

M Tordeux, C Wakselman

文献索引：Tordeux, Marc; Wakselman, Claude Journal of Fluorine Chemistry, 1995 , vol. 74, # 2 p. 251 - 254

被引用次数: 12

摘要

The reduction of nitroaromatic compounds by various metals (tin, lead, bismuth) in liquid hydrogen fluoride under an inert atmosphere leads to fluoroaromatic amines, in accord with the Bamberger reaction. Generally, a co-solvent such as pentane or methylene chloride is used. Some non-fluorinated arylamines are also formed by a competitive direct reduction of the N-arylhydroxylamine intermediate. Of the mild reductive metals studied, bismuth was ...