Synlett

Rhodium-and iridium-catalyzed allylation of electron-rich arenes with allyl tosylate

N Tsukada, Y Yagura, T Sato, Y Inoue

文献索引：Tsukada, Naofumi; Yagura, Yasushige; Sato, Tetsuo; Inoue, Yoshio Synlett, 2003 , # 10 p. 1431 - 1434

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被引用次数: 20

摘要

Abstract The allylation of electron-rich arenes with allyl tosylate proceeded at 0 C in the presence of [Rh (nbd)(CH 3 CN) 2] PF 6. Various oxygenated arenes were allylated with high para-selectivity in almost all cases. Especially in the reaction of anisoles, the tendency was remarkable.