Oxidative nucleophilic addition of organovanadium reagents to aldehydes with formation of ketones

T Hirao, D Misu, T Agawa

文献索引：Hirao, Toshikazu; Misu, Daisuke; Agawa, Toshio Journal of the American Chemical Society, 1985 , vol. 107, # 24 p. 7179 - 7181

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被引用次数: 36

摘要

42 oUnless otherwise stated, the reaction was carried out using an aldehyde or ketone, an organolithium or magnesium compound, and vanadium trichloride in a ratio of 1: l: l. bToluene was added to the mixture which was kept at-78 OC for 2 h after the addition of an aldehyde. cn-BuMgBr/VC13= 3: l. dn-BuMgBr/VC13= 2: l.'n-Butylvanadium species/R'CHO= 2: l./Room temperature. g The corresponding ketone was not obtained.