Synthesis

LiClO4-amine mediated direct aldol process

M Markert, R Mahrwald

文献索引：Markert, Morris; Mahrwald, Rainer Synthesis, 2004 , # 9 p. 1429 - 1433

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被引用次数: 12

摘要

Abstract Aldol processes of aldehydes with secondary alcohols were observed by using a LiClO 4-amine reagent under very mild conditions. Unusual regio-and stereoselectivities observed during this new transformation are discussed. Stereotriades as well as stereopentades with configurations previously unattainable by aldol methodologies were isolated.