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878-61-5

878-61-5结构式
878-61-5结构式

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中文名 马杜拉霉素
英文名 1-bromo-3-ethyladamantane
中文别名 1-溴-3-乙基金刚烷
英文别名 1-Brom-3-aethyl-adamantan
3-Brom-1-ethyl-adamantan
1-ethyl-3-bromoadamantane
3-Brom-1-aethyl-adamantan
1-bromo-3-ethyl-adamantane
密度 1.344g/cm3
沸点 124ºC
熔点 23ºC
分子式 C12H19Br
分子量 243.18300
闪点 115.6ºC
精确质量 242.06700
LogP 4.13030
折射率 1.567
Name: 1-Bromo-3-ethyladamantane 95+% Material Safety Data Sheet
Synonym:
CAS: 878-61-5
Section 1 - Chemical Product MSDS Name:1-Bromo-3-ethyladamantane 95+% Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
878-61-5 1-Bromo-3-ethyladamantane 95+% unlisted
Hazard Symbols: XI
Risk Phrases: 36/37/38

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if swallowed.
Inhalation:
Causes respiratory tract irritation. May be harmful if inhaled.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Keep refrigerated. (Store below 4C/39F.) Store in a tightly closed container. Store in a dry area.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 878-61-5: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 124 - 125 deg C @7mmHg
Freezing/Melting Point: 23 - 24 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C12H19Br
Molecular Weight: 243

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, hydrogen bromide, acrid smoke and fumes, bromine.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 878-61-5 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
1-Bromo-3-ethyladamantane - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
No information available.
IMO
No information available.
RID/ADR
No information available.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 878-61-5: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 878-61-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 878-61-5 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A
危害码 (欧洲) Xi: Irritant;
海关编码 2903890090

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878-61-5结构式

878-61-5

文献:Inomata, Sotaro; Harada, Yusuke; Nakamura, Yuya; Uehara, Yosuke; Ishizone, Takashi Journal of Polymer Science, Part A: Polymer Chemistry, 2013 , vol. 51, # 19 p. 4111 - 4124

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878-61-5结构式

878-61-5

文献:Journal of Medicinal Chemistry, , vol. 25, # 1 p. 51 - 56

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878-61-5结构式

878-61-5

文献:Journal of Medicinal Chemistry, , vol. 25, # 1 p. 51 - 56

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878-61-5结构式

878-61-5

文献:Journal of Organic Chemistry USSR (English Translation), , vol. 5, p. 2123 - 2125 Zhurnal Organicheskoi Khimii, , vol. 5, # 12 p. 2187 - 2189

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878-61-5结构式

878-61-5

文献:Journal of Organic Chemistry USSR (English Translation), , vol. 5, p. 2123 - 2125 Zhurnal Organicheskoi Khimii, , vol. 5, # 12 p. 2187 - 2189
海关编码 2903890090
中文概述 2903890090. 其他环烷烃、环烯烃或环萜烯烃的卤化衍生物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:5.5%. 普通关税:30.0%
申报要素 品名, 成分含量, 用途
Summary 2903890090. halogenated derivatives of cyclanic, cyclenic or cyclotherpenic hydrocarbons. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%