| 中文名 | 间氨基苯乙醚 |
|---|---|
| 英文名 | 3-Ethoxyaniline |
| 中文别名 |
间乙氧基苯胺
3-乙氧基苯胺 3-氨基苯乙醚 |
| 英文别名 |
3-ethoxyphenylamine
m-ethoxyphenylamine 3-Ethoxybenzenamine m-Phenetidine Benzenamine,3-ethoxy EINECS 210-680-2 Benzenamine, 3-ethoxy- 3-ethoxy aniline 3-Ethoxyaniline m-Ethoxyaniline MFCD00007785 |
| 密度 | 1.0±0.1 g/cm3 |
|---|---|
| 沸点 | 251.1±13.0 °C at 760 mmHg |
| 分子式 | C8H11NO |
| 分子量 | 137.179 |
| 闪点 | 114.8±13.1 °C |
| 精确质量 | 137.084061 |
| PSA | 35.25000 |
| LogP | 1.37 |
| 外观性状 | 淡黄色至暗红色液体 |
| 蒸汽压 | 0.0±0.5 mmHg at 25°C |
| 折射率 | 1.545 |
| 储存条件 | 存放在密封容器内，放在阴凉，干燥处。 |
| 稳定性 | 避光 |
| 水溶解性 | 0.1-0.5 g/100 mL at 20 ºC |
| 分子结构 | 1、 摩尔折射率：41.80 2、 摩尔体积（cm3/mol）：132.2 3、 等张比容（90.2K）：329.5 4、 表面张力（dyne/cm）：38.5 5、 极化率（10-24cm3）：16.57 |
| 计算化学 | 1.疏水参数计算参考值（XlogP）:无 2.氢键供体数量:1 3.氢键受体数量:2 4.可旋转化学键数量:2 5.互变异构体数量:无 6.拓扑分子极性表面积35.2 7.重原子数量:10 8.表面电荷:0 9.复杂度:95.3 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:1 |
| 更多 | 1. 性状：棕色透明液体。 2. 密度（g/mL,25/4℃）：1.030 3. 相对蒸汽密度（g/mL,空气=1）：未确定 4. 熔点（ºC）：未确定 5. 沸点（ºC,常压）：248 6. 沸点（ºC,5.2kPa）：未确定 7. 折射率： 1.5655 8. 闪点（ºC）：＞112 9. 比旋光度（º）：未确定 10. 自燃点或引燃温度（ºC）：未确定 11. 蒸气压（kPa,25ºC）：未确定 12. 饱和蒸气压（kPa,60ºC）：未确定 13. 燃烧热（KJ/mol）：未确定 14. 临界温度（ºC）：未确定 15. 临界压力（KPa）：未确定 16. 油水（辛醇/水）分配系数的对数值：未确定 17. 爆炸上限（%,V/V）：未确定 18. 爆炸下限（%,V/V）：未确定 19. 溶解性：未确定。 |
Synonym:3-Ethoxybenzenamine; 3-Ethoxyaniline; Aniline, 3-ethoxy-; Benzenamine, 3-ethoxy-; m-Ethoxyanilin Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 23/24/25 33 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Toxic by inhalation, in contact with skin and if swallowed. Danger of cumulative effects.Cancer suspect agent.Light sensitive.Air sensitive. Potential Health Effects Eye: May cause eye irritation. May cause chemical conjunctivitis. Skin: May cause skin irritation. Ingestion: May be harmful if swallowed. May form methemoglobin which in sufficient concentration causes cyanosis (bluish discoloration of skin due to deficient oxygenation of the blood). Inhalation: May be harmful if inhaled. Inhalation of aniline causes anoxia due to the formation of methemoglobin. Chronic: Effects may be delayed. Section 4 - FIRST AID MEASURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing Media: In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill using an absorbent, non-combustible material such as earth, sand, or vermiculite. Do not use combustible materials such as sawdust. Provide ventilation. Place under an inert atmosphere. Section 7 - HANDLING and STORAGE Handling: Wash thoroughly after handling. Use with adequate ventilation. Do not get in eyes, on skin, or on clothing. Do not ingest or inhale. Store protected from light. Handle under an inert atmosphere. Store protected from air. Do not breathe vapor. Storage: Keep containers tightly closed. Do not expose to air. Store protected from light. Store under an inert atmosphere. Store in a cool, dry area away from incompatible substances. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits. Exposure Limits CAS# 621-33-0: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves and clothing to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Clear liquid Color: clear brown Odor: None reported. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 248 deg C @ 760.00mmHg Freezing/Melting Point: Not available. Autoignition Temperature: Not applicable. Flash Point: > 112 deg C (> 233.60 deg F) Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Not available. Solubility in water: Not available. Specific Gravity/Density: 1.0320g/cm3 Molecular Formula: C8H11NO Molecular Weight: 137.18 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials, light, exposure to air, excess heat. Incompatibilities with Other Materials: Air, acid anhydrides, acid chlorides, acids, chloroformates, direct light, strong oxidizing agents. Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, carbon dioxide. Hazardous Polymerization: Has not been reported. Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 621-33-0: SI5400000 LD50/LC50: Not available. Carcinogenicity: m-Phenetidine - Not listed by ACGIH, IARC, or NTP. Other: See actual entry in RTECS for complete information. Section 12 - ECOLOGICAL INFORMATION Other No information available. Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: PHENETIDINES Hazard Class: 6.1 UN Number: 2311 Packing Group: III IMO Shipping Name: PHENETIDINES Hazard Class: 6.1 UN Number: 2311 Packing Group: III RID/ADR Shipping Name: PHENETIDINES Hazard Class: 6.1 UN Number: 2311 Packing group: III Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: T Risk Phrases: R 23/24/25 Toxic by inhalation, in contact with skin and if swallowed. R 33 Danger of cumulative effects. Safety Phrases: S 28A After contact with skin, wash immediately with plenty of water. S 36/37 Wear suitable protective clothing and gloves. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). WGK (Water Danger/Protection) CAS# 621-33-0: No information available. Canada CAS# 621-33-0 is listed on Canada's NDSL List. CAS# 621-33-0 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 621-33-0 is listed on the TSCA inventory. SECTION 16 - ADDITIONAL INFORMATION N/A |
|
生态学数据: 不要注入水渠。
CHEMICAL IDENTIFICATION
HEALTH HAZARD DATAACUTE TOXICITY DATAMUTATION DATA
|
| 符号 |
GHS06, GHS08 |
|---|---|
| 信号词 | Danger |
| 危害声明 | H301 + H311 + H331-H373 |
| 警示性声明 | P261-P280-P301 + P310-P311 |
| 个人防护装备 | Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter |
| 危害码 (欧洲) | T:Toxic; |
| 风险声明 (欧洲) | R23/24/25;R33 |
| 安全声明 (欧洲) | S28-S36/37/39-S45-S36/37-S28A |
| 危险品运输编码 | UN 2311 6.1/PG 3 |
| WGK德国 | 3 |
| RTECS号 | SI5400000 |
| 包装等级 | III |
| 危险类别 | 6.1(b) |
| 海关编码 | 29222200 |
|
~%
621-33-0 |
| 文献：Journal fuer Praktische Chemie (Leipzig), , vol. <2>96, p. 25 |
|
~95%
621-33-0 |
| 文献：Prasad; Gowda, Shankare; Gowda, D. Channe Synthetic Communications, 2004 , vol. 34, # 1 p. 1 - 10 |
|
~%
621-33-0 |
| 文献：Collection of Czechoslovak Chemical Communications, , vol. 54, # 7 p. 1846 - 1853 |
|
~%
621-33-0 |
| 文献：Bulletin de la Societe Chimique de France, , vol. <4>17, p. 407 |
|
~%
621-33-0 |
| 文献：Bulletin de la Societe Chimique de France, , vol. <4>17, p. 407 |
|
~%
621-33-0 |
| 文献：Journal of the American Chemical Society, , vol. 61, p. 384,385 |
|
~%
621-33-0 |
| 文献：Journal of the Chemical Society, , p. 2955 |
|
~%
621-33-0 |
| 文献：Journal fuer Praktische Chemie (Leipzig), , vol. <2> 32, p. 71 |
|
~%
621-33-0 |
| 文献：Journal fuer Praktische Chemie (Leipzig), , vol. <2>96, p. 25 |
| 上游产品 8 | |
|---|---|
| 下游产品 10 | |
| 海关编码 | 2922299090 |
|---|---|
| 中文概述 | 2922299090. 其他氨基(萘酚、酚)及醚、酯〔包括它们的盐, 但含有一种以上含氧基的除外〕. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0% |
| 申报要素 | 品名, 成分含量, 用途, 乙醇胺及其盐应报明色度, 乙醇胺及其盐应报明包装 |
| Summary | 2922299090. other amino-naphthols and other amino-phenols, other than those containing more than one kind of oxygen function, their ethers and esters; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0% |
