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306935-15-9

306935-15-9结构式
306935-15-9结构式

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中文名 3-甲氧基羰基-1,2,2-三甲基环戊烷-1-羧酸
英文名 3-methoxycarbonyl-1,2,2-trimethylcyclopentane-1-carboxylic acid
英文别名 1,2,2-Trimethyl-cyclopentan-1,3-dicarbonsaeure-3-methylester
3-(methoxycarbonyl)-1,2,2-trimethylcyclopentane-1-carboxylic acid
1,2,2-trimethyl-cyclopentane-1,3-dicarboxylic acid-3-methyl ester
1,2,2-trimethyl-cyclopentane-1r,3c-dicarboxylic acid 3-methyl ester
3-(methoxycarbonyl)-1,2,2-trimethylcyclopentanecarboxylic acid
F1901-0012
密度 1.096g/cm3
沸点 295.4ºC at 760mmHg
熔点 62-64ºC
分子式 C11H18O4
分子量 214.25800
闪点 106.3ºC
精确质量 214.12100
PSA 63.60000
LogP 1.68650
折射率 1.465
Name: 3-(Methoxycarbonyl)-1 2 2-trimethylcyclopentane-1-carboxylic acid Material Safety Data Sheet
Synonym:
CAS: 306935-15-9
Section 1 - Chemical Product MSDS Name:3-(Methoxycarbonyl)-1 2 2-trimethylcyclopentane-1-carboxylic acid Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
306935-15-9 3-(Methoxycarbonyl)-1,2,2-trimethylcyc 97% unlisted
Hazard Symbols: XI
Risk Phrases: 36/37/38

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if swallowed.
Inhalation:
Causes respiratory tract irritation. May be harmful if inhaled.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 306935-15-9: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 62 - 64 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C11H18O4
Molecular Weight: 214

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, acrid smoke and fumes.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 306935-15-9 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
3-(Methoxycarbonyl)-1,2,2-trimethylcyclopentane-1-carboxylic acid - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
No information available.
IMO
No information available.
RID/ADR
No information available.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 306935-15-9: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 306935-15-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 306935-15-9 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A
危害码 (欧洲) Xi: Irritant;
风险声明 (欧洲) R36/37/38
安全声明 (欧洲) S26-S37/39
海关编码 2918990090

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306935-15-9结构式

306935-15-9

文献:Noyes; Littleton Journal of the American Chemical Society, 1913 , vol. 35, p. 80 Full Text Show Details Noyes; Knight Journal of the American Chemical Society, 1910 , vol. 32, p. 1672 Full Text Show Details Noyes; Skinner Journal of the American Chemical Society, 1917 , vol. 39, p. 2692,2700

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306935-15-9结构式

306935-15-9

文献:Oecal, Nueket; Yano, Lovelle M.; Erden, Ihsan Tetrahedron Letters, 2003 , vol. 44, # 36 p. 6947 - 6949

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306935-15-9结构式

306935-15-9

文献:Wegscheider Monatshefte fuer Chemie, 1899 , vol. 20, p. 693

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306935-15-9结构式

306935-15-9

文献:Bruehl; Braunschweig Chemische Berichte, 1893 , vol. 26, p. 285
海关编码 2918990090
中文概述 2918990090. 其他含其他附加含氧基羧酸(包括酸酐、酰卤化物、过氧化物和过氧酸及该税号的衍生物). 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%
申报要素 品名, 成分含量, 用途
Summary 2918990090. other carboxylic acids with additional oxygen function and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%