63470-53-1

• 常用中文名：三氟乙酰丙酮二甲基金(III)
• 常用英文名：DIMETHYL(TRIFLUOROACETYLACETONATE)GOLD (III)
• CAS号：63470-53-1
• 分子式：C₇H₁₀AuF₃O₂
• 分子量：380.11500
• 发布时间：2018-12-19 13:43:26
• 更新时间：2024-01-02 16:47:25

• 用作化学试剂

名称

• 中文名: 二甲基(三氟乙酰丙酮)金(III)
• 英文名: carbanide,gold(3+),(Z)-1,1,1-trifluoro-4-oxopent-2-en-2-olate
• 中文别名: 二甲基(三氟乙酰基丙铜)金(III)
• 英文别名: Gold,dimethyl(1,1,1-trifluoro-2,4-pentanedionato-kappaO,kappaO')-,(SP-4-3); (Z)-1,1,1-trifluoro-4-oxopent-2-en-2-olate; gold(3+)

物化性质

• 沸点: 195.6ºC at 760 mmHg
• 分子式: C₇H₁₀AuF₃O₂
• 分子量: 380.11500
• 闪点: 72.1ºC
• 精确质量: 380.03000
• PSA: 26.30000
• LogP: 2.66760
• 储存条件:

  密闭于阴凉干燥环境中

• 稳定性:

  遵照规定使用和储存则不会分解。

• 分子结构:

  1、摩尔折射率：无可用

  2、 摩尔体积（cm³/mol）：无可用

  3、 等张比容（90.2K）：无可用

  4、 表面张力（dyne/cm）：无可用

  5、 极化率：无可用

• 计算化学:

  1.疏水参数计算参考值（XlogP）:无

  2.氢键供体数量:0

  3.氢键受体数量:7

  4.可旋转化学键数量:1

  5.互变异构体数量:2

  6.拓扑分子极性表面积40.1

  7.重原子数量:13

  8.表面电荷:0

  9.复杂度:168

  10.同位素原子数量:0

  11.确定原子立构中心数量:0

  12.不确定原子立构中心数量:0

  13.确定化学键立构中心数量:1

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:4

• 更多:

  1. 性状：无可用

  2. 密度（g/mL,25/4℃）：无可用

  3. 相对蒸汽密度（g/mL,空气=1）：无可用

  4. 熔点（ºC）：无可用

  5. 沸点（ºC,常压）：无可用

  6. 沸点（ºC,5.2kPa）：无可用

  7. 折射率：无可用

  8. 闪点（ºC）：无可用

  9. 比旋光度（º）：无可用

  10. 自燃点或引燃温度（ºC）：无可用

  11. 蒸气压（kPa,25ºC）：无可用

  12. 饱和蒸气压（kPa,60ºC）：无可用

  13. 燃烧热（KJ/mol）：无可用

  14. 临界温度（ºC）：无可用

  15. 临界压力（KPa）：无可用

  16. 油水（辛醇/水）分配系数的对数值：无可用

  17. 爆炸上限（%,V/V）：无可用

  18. 爆炸下限（%,V/V）：无可用

  19. 溶解性：无可用

MSDS

Section 1: Product Identification Chemical Name:Dimethyl(trifluoroacetylacetonate)gold (III), 98% (99.9%-Au) **MUST SHIP OVERNIGHT/DRY ICE** CAS Registry Number:63470-53-1 Formula:(CH3)2Au(CF3COCHCOCH3) EINECS Number:None Chemical Family:metal fluorobeta-diketonate complexes Synonym:Dimethylgold (III) trifluoroacetylacetonate; Dimethylgold (III) 1,1,1-trifluoro-2,5-pentanedionate Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title Compound63470-53-1100%2.5mg/m3 (as F)2.5mg/m3 (as F) Section 3: Hazards Identification Toxic by inhalation. Irritating to skin, eyes, and respiratory tract. Exposure to gold compounds may damage Emergency Overview: kidney function and reduce blood cell count. This compound may cause fluoride poisoning. Primary Routes of Exposure:Ingestion, inhalation, skin, eyes Eye Contact:Causes slight to mild irritation of the eyes. Skin Contact:Causes slight to mild irritation of the skin. Toxic by inhalation. Irritating to the nose, mucous membranes and respiratory tract. Inhalation may cause Inhalation: fluoride poisoning. Ingestion may lead to dermatitis, dizziness, metallic taste, abdominal cramps, vomiting, bloody diarrhea, Ingestion: weakness, and convulsions. Toxic by inhalation. Gold compounds cause irritation to the eyes and respiratory tract, impairment of kidney Acute Health Affects: and bone marrow function, abdominal cramps, vomiting, bloody diarrhea, weakness, and convulsions. Prolonged exposure to gold compounds may lead to reduced red and white blood cell generation. Chronic Chronic Health Affects: fluoride poisoning can cause severe bone changes, loss of weight, and dental defects. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:not applicable Autoignition Temperature:none Explosion Limits:none Extinguishing Medium:none required If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure Special Fire Fighting Procedures: self- contained breathing apparatus and full protective clothing. Hazardous Combustion andCombustible material. If involved in a fire this material may emit toxic and corrosive fumes. Decomposion Products: Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures To avoid raising dust, small spills may be mixed with diatomaceous earth, sand, vermiculite, or other suitable Spill and Leak Procedures: inert material and swept up. SECTION 7: Handling and Storage Handling and Storage:Store cold (freezer), under an inert atmosphere, in a tightly sealed container. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear protective clothing and gloves. Ventilation:Material may form a fine dust. Handle the material in an efficient fume hood. If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Respirator: Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:Material may form a fine dust. Handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:white to off-white xtl. Molecular Weight:380.12 Melting Point:no data Boiling Point:no data Vapor Pressure:not applicable Specific Gravity:no data Odor:none Solubility in Water:insoluble SECTION 10: Stability and Reactivity Stability:air sensitive, heat sensitive, light sensitive Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:contact with air, heat, and light. Incompatibility:oxidizing agents and active metals Decomposition Products:carbon monoxide, carbon dioxide, hydrogen fluoride, and gold. SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files. Carcinogenic Effects:No data Mutagenic Effects:No data Tetratogenic Effects:No data SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Toxic solids, organic, N.O.S. Hazard Class (CFR):6.1 Additional Hazard Class (CFR):NA Packaging Group (CFR):II UN ID Number (CFR):UN# 2811 Shipping Name (IATA):Toxic solid, Organic, N.O.S. Hazard Class (IATA):6.1 Additional Hazard Class (IATA):NA Packaging Group (IATA):II UN ID Number (IATA):UN# 2811 SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory. SARA (Title 313):Title compound not listed. Second Ingredient:None SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

毒理学数据: 试验方法：吸入 摄入剂量： 81 mg/m3/4H 测试对象：啮齿动物-鼠 毒性类型：急性 毒性作用： 1.感官（眼）机构异常 -流泪 2.嗜睡（普通抑郁活动） 3.肺，胸部或呼吸-呼吸刺激 生态学数据: 该物质对环境可能有危害，对水体应给予特别注意。

安全

• 风险声明 (欧洲): R23/24/25
• 安全声明 (欧洲): 26-36/37/39-45
• 危险品运输编码: UN 2811
• 危险类别: 6.1(a)