| 中文名 | 2,4-DIMETHYL-3-PENTYLAMINE |
|---|---|
| 英文名 | 2,4-dimethylpentan-3-amine |
| 英文别名 |
2,4-Dimethylpentan-3-amine
3-Amino-2,4-dimethylpentane 2,4-DIMETHYL-3-PENTYLAMINE 2,4-dimethyl-3-aminopentane 2,4-Dimethyl-3-pentanamine EINECS 223-809-2 2,4-dimethyl-pent-3-ylamine 1-Isopropyl-2-methylpropylamine 3-Pentanamine, 2,4-dimethyl- diisopropylmethylamine 3-Pentanamine,2,4-dimethyl |
| 密度 | 0.8±0.1 g/cm3 |
|---|---|
| 沸点 | 123.2±8.0 °C at 760 mmHg |
| 分子式 | C7H17N |
| 分子量 | 115.217 |
| 闪点 | 22.3±13.3 °C |
| 精确质量 | 115.136101 |
| PSA | 26.02000 |
| LogP | 1.97 |
| 蒸汽压 | 13.4±0.2 mmHg at 25°C |
| 折射率 | 1.423 |
Synonym:(Diisopropylmethyl)amine; 1-(1-Methylethyl)-2-Methylpropanamine Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 11 34 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Highly flammable. Causes burns.Air sensitive.Highly flammable.Corrosive. Potential Health Effects Eye: Causes eye burns. May cause chemical conjunctivitis and corneal damage. Skin: Causes skin burns. May cause skin rash (in milder cases), and cold and clammy skin with cyanosis or pale color. Ingestion: May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns. May cause perforation of the digestive tract. May cause systemic effects. Inhalation: Causes chemical burns to the respiratory tract. Aspiration may lead to pulmonary edema. Vapors may cause dizziness or suffocation. May cause systemic effects. Chronic: Effects may be delayed. Section 4 - FIRST AID MEASURES Eyes: Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed. Extensive irrigation with water is required (at least 30 minutes). Skin: Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes. Ingestion: Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors may form an explosive mixture with air. Vapors can travel to a source of ignition and flash back. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Water may be ineffective. Material is lighter than water and a fire may be spread by the use of water. Flammable liquid and vapor. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Will be easily ignited by heat, sparks or flame. Containers may explode if exposed to fire. Extinguishing Media: For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. Water may be ineffective. Water may spread fire. If water is the only media available, use in flooding amounts. For large fires, use water spray, fog or alcohol-resistant foam. Do NOT use straight streams of water. Cool containers with flooding quantities of water until well after fire is out. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Scoop up with a nonsparking tool, then place into a suitable container for disposal. Remove all sources of ignition. Provide ventilation. Place under an inert atmosphere. Section 7 - HANDLING and STORAGE Handling: Use only in a well-ventilated area. Ground and bond containers when transferring material. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Keep away from heat, sparks and flame. Handle under an inert atmosphere. Store protected from air. Discard contaminated shoes. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Storage: Keep away from heat, sparks, and flame. Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area. Do not expose to air. Store under an inert atmosphere. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local explosion-proof ventilation to keep airborne levels to acceptable levels. Exposure Limits CAS# 4083-57-2: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Color: clear, colorless Odor: None reported. pH: Not available. Vapor Pressure: Not available. Viscosity: 0.8 MPA 20.00 deg C Boiling Point: 132 deg C @ 760.00mm Hg Freezing/Melting Point: Not available. Autoignition Temperature: 390 deg C ( 734.00 deg F) Flash Point: 20 deg C ( 68.00 deg F) Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: +/- 12 G/L (20C) Specific Gravity/Density: .7760g/cm3 Molecular Formula: C7H17N Molecular Weight: 115.22 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials, ignition sources, exposure to air, excess heat, strong oxidants. Incompatibilities with Other Materials: Air, strong acids, strong bases, strong oxidizing agents. Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, nitrogen. Hazardous Polymerization: Has not been reported. Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 4083-57-2 unlisted. LD50/LC50: Not available. Carcinogenicity: 3-Amino-2,4-dimethylpentane - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: AMINES, FLAMMABLE, CORROSIVE, N.O.S.* Hazard Class: 3 (8) UN Number: 2733 Packing Group: II IMO Shipping Name: AMINES, FLAMMABLE, CORROSIVE, N.O.S. Hazard Class: 3.2 (8) UN Number: 2733 Packing Group: II RID/ADR Shipping Name: AMINES, FLAMMABLE, CORROSIVE, N.O.S. Hazard Class: 3 UN Number: 2733 Packing group: II Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: F C Risk Phrases: R 11 Highly flammable. R 34 Causes burns. Safety Phrases: S 16 Keep away from sources of ignition - No smoking. S 23 Do not inhale gas/fumes/vapour/spray. S 24/25 Avoid contact with skin and eyes. WGK (Water Danger/Protection) CAS# 4083-57-2: No information available. Canada CAS# 4083-57-2 is listed on Canada's NDSL List. CAS# 4083-57-2 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 4083-57-2 is listed on the TSCA inventory. SECTION 16 - ADDITIONAL INFORMATION N/A |
| 危险品运输编码 | UN 2924 |
|---|---|
| 包装等级 | II |
| 危险类别 | 3.1 |
| 海关编码 | 2921199090 |
|
~84%
4083-57-2 |
| 文献：Miriyala, Bruhaspathy; Bhattacharyya, Sukanta; Williamson, John S. Tetrahedron, 2004 , vol. 60, # 7 p. 1463 - 1471 |
|
~%
4083-57-2 |
| 文献：Walter Journal of the American Chemical Society, 1952 , vol. 74, p. 5185 |
|
~%
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| 文献：Ingersoll et al.; zit. bei Moore Org. Reactions, 1949 , vol. 5, p. 301,327 |
|
~%
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| 文献：Mailhe Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1920 , vol. 170, p. 1265 Bulletin de la Societe Chimique de France, 1920 , vol. <4>27, p. 544 |
|
~%
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| 文献：Mailhe Bulletin de la Societe Chimique de France, 1914 , vol. <4>15, p. 328 |
|
~%
4083-57-2 |
| 文献：Walter Journal of the American Chemical Society, 1952 , vol. 74, p. 5185 |
|
~%
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| 文献：Schwoegler; Adkins Journal of the American Chemical Society, 1939 , vol. 61, p. 3499,3500 |
|
~%
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| 文献：Mailhe Bulletin de la Societe Chimique de France, 1914 , vol. <4>15, p. 328 |
| 上游产品 8 | |
|---|---|
| 下游产品 7 | |
| 海关编码 | 2921199090 |
|---|---|
| 中文概述 | 2921199090 其他无环单胺及其衍生物及其盐。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:6.5%。普通关税:30.0% |
| 申报要素 | 品名, 成分含量, 用途 |
| Summary | 2921199090 other acyclic monoamines and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0% |
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