4206-61-5

• 常用中文名：2,2’-[氧基双(2,1-亚乙基氧基亚甲基)]双环氧乙烷
• 常用英文名：diethylenglykol-diglycidylether
• CAS号：4206-61-5
• 分子式：C₁₀H₁₈O₅
• 分子量：218.24700
• 相关类别： 化学试剂 有机试剂 环氧化物
• 发布时间：2018-12-01 01:55:15
• 更新时间：2024-01-05 09:35:55

名称

• 中文名: 2,2-[氧基双(2,1-亚乙基氧基亚甲基)]双环氧乙烷
• 英文名: 4,7,10-Trioxatridecane, 1,2_12,13-diepoxy
• 中文别名: 二乙二醇二缩水甘油醚; 聚乙二醇二缩水甘油醚; 2,2’-[氧基双(2,1-亚乙基氧基亚甲基)]双环氧乙烷
• 英文别名: diglycidyl diglycol; diethylene glycol glycidyl ether; Diethylene glycol bisglycidyl ether; DIETHYLENGLYKOL-DIGLYCIDYLETHER; diglycidyldiethyleneglycolether; 1,2:12,13-Diepoxy-4,7,10-trioxatridecane

物化性质

• 密度: 1.165g/cm3
• 沸点: 313ºC at 760mmHg
• 分子式: C₁₀H₁₈O₅
• 分子量: 218.24700
• 闪点: 127.3ºC
• 精确质量: 218.11500
• PSA: 52.75000
• 折射率: n20/D 1.467
• 储存条件: 2-8°C

MSDS

Section1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE Product identifiers Product name: Diethylene glycol diglycidyl ether CAS-No.: 4206-61-5 Relevant identified uses of the substance or mixture and uses advised against Identified uses: Laboratory chemicals, Manufacture of substances Section2. HAZARDS IDENTIFICATION Classification of the substance or mixture Not a hazardous substance or mixture according to Regulation (EC) No 1272/2008 Classification according to EU Directives 67/548/EEC or 1999/45/EC May form explosive peroxides. Label elements According to European Directive 67/548/EEC as amended. Hazard symbol(s)none R-phrase(s) R19May form explosive peroxides. S-phrase(s)none Other hazards - none Section3. COMPOSITION/INFORMATION ON INGREDIENTS Substances Synonyms: Diglycidyl diglycol Formula: C10H18O5 Molecular Weight: 218,25 g/mol Section4. FIRST AID MEASURES Description of first aid measures If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. In case of skin contact Wash off with soap and plenty of water. In case of eye contact Flush eyes with water as a precaution. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Most important symptoms and effects, both acute and delayed Indication of any immediate medical attention and special treatment needed no data available Section5. FIREFIGHTING MEASURES Extinguishing media Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Special hazards arising from the substance or mixture Carbon oxides Advice for firefighters Wear self contained breathing apparatus for fire fighting if necessary. Further information no data available Section6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Avoid breathing vapors, mist or gas. Environmental precautions Do not let product enter drains. Methods and materials for containment and cleaning up Keep in suitable, closed containers for disposal. Reference to other sections For disposal see section 13. Section7. HANDLING AND STORAGE Precautions for safe handling Normal measures for preventive fire protection. Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Store under inert gas. Moisture sensitive. Exposure to moisture. Specific end uses no data available Section8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Components with workplace control parameters Exposure controls Appropriate engineering controls General industrial hygiene practice. Personal protective equipment Eye/face protection Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Body Protection impervious clothing, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection Respiratory protection not required. For nuisance exposures use type OV/AG (US) or type ABEK (EU EN 14387) respirator cartridges. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Section9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties a) AppearanceForm: liquid Colour: colourless b) Odourno data available c) Odour Thresholdno data available d) pHno data available e) Melting point/freezingno data available point f) Initial boiling point and no data available boiling range g) Flash point125 °C - closed cup h) Evaporation rateno data available i) Flammability (solid, gas) no data available j) Upper/lowerno data available flammability or explosive limits k) Vapour pressureno data available l) Vapour densityno data available m) Relative density1,167 g/mL at 20 °C n) Water solubilityno data available o) Partition coefficient: n- no data available octanol/water p) Autoignitionno data available temperature q) Decompositionno data available temperature r) Viscosityno data available s) Explosive propertiesno data available t) Oxidizing propertiesno data available Other safety information no data available Section10. STABILITY AND REACTIVITY Reactivity no data available Chemical stability no data available Possibility of hazardous reactions no data available Conditions to avoid no data available Incompatible materials no data available Hazardous decomposition products Other decomposition products - no data available Section11. TOXICOLOGICAL INFORMATION Information on toxicological effects Acute toxicity no data available Skin corrosion/irritation no data available Serious eye damage/eye irritation no data available Respiratory or skin sensitization no data available Germ cell mutagenicity Genotoxicity in vivo - rat - Intraperitoneal Cytogenetic analysis Genotoxicity in vivo - rat - Intraperitoneal Other mutation test systems Carcinogenicity IARC:No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Reproductive toxicity no data available Specific target organ toxicity - single exposure no data available Specific target organ toxicity - repeated exposure no data available Aspiration hazard no data available Potential health effects InhalationMay be harmful if inhaled. May cause respiratory tract irritation. IngestionMay be harmful if swallowed. SkinMay be harmful if absorbed through skin. May cause skin irritation. Eyes May cause eye irritation. Additional Information RTECS: KN2330000 Section12. ECOLOGICAL INFORMATION Toxicity no data available Persistence and degradability no data available Bioaccumulative potential no data available Mobility in soil no data available Results of PBT and vPvB assessment no data available Other adverse effects no data available Section13. DISPOSAL CONSIDERATIONS Waste treatment methods Product Offer surplus and non-recyclable solutions to a licensed disposal company. Contaminated packaging Dispose of as unused product. Section14. TRANSPORT INFORMATION UN number ADR/RID: -IMDG: -IATA: - UN proper shipping name ADR/RID: Not dangerous goods IMDG: Not dangerous goods IATA:Not dangerous goods Transport hazard class(es) ADR/RID: -IMDG: -IATA: - Packaging group ADR/RID: -IMDG: -IATA: - Environmental hazards ADR/RID: noIMDG Marine pollutant: noIATA: no Special precautions for user no data available SECTION 15 - REGULATORY INFORMATION N/A SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

CHEMICAL IDENTIFICATION RTECS NUMBER : KN2330000 CHEMICAL NAME : Ether, bis(2-(2,3-epoxypropoxy)ethyl) CAS REGISTRY NUMBER : 4206-61-5 LAST UPDATED : 199712 DATA ITEMS CITED : 4 MOLECULAR FORMULA : C10-H18-O5 MOLECULAR WEIGHT : 218.28 WISWESSER LINE NOTATION : T3OTJ B1O2O2O1- BT3OTJ HEALTH HAZARD DATA ACUTE TOXICITY DATA TYPE OF TEST : Mutation test systems - not otherwise specified MUTATION DATA TEST SYSTEM : Rodent - rat DOSE/DURATION : 100 mg/kg REFERENCE : BJPCAL British Journal of Pharmacology and Chemotherapy. (London, UK) V.1-33, 1946-68. For publisher information, see BJPCBM. Volume(issue)/page/year: 6,235,1951

安全

• 风险声明 (欧洲): 19
• WGK德国: 3
• RTECS号: KN2330000
• 海关编码: 2910900090

合成路线

106-89-8 111-46-6 ~67% 4206-61-5

文献：Xue-Ping Gu; Ikeda, Isao; Okahara, Mitsuo Synthesis, 1985 , # 6/7 p. 649 - 651

上下游产品

上游产品  2
106-89-8 111-46-6
下游产品  1
90655-79-1

海关

海关编码	2910900090
中文概述	2910900090. 三节环环氧化物，环氧醇（酚，醚），包括其卤化，磺化，硝化或亚硝化的衍生物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:5.5%. 普通关税:30.0%
申报要素	品名, 成分含量, 用途
Summary	2910900090. epoxides, epoxyalcohols, epoxyphenols and epoxyethers, with a three-membered ring, and their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%