| 中文名 | 2,4-已二烯 |
|---|---|
| 英文名 | 2,4-hexadiene |
| 密度 | 0.72 g/mL at 25ºC(lit.) |
|---|---|
| 沸点 | 82ºC(lit.) |
| 分子式 | C6H10 |
| 分子量 | 82.14360 |
| 闪点 | 7 °F |
| 精确质量 | 82.07830 |
| LogP | 2.13860 |
| 折射率 | n20/D 1.445(lit.) |
Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 11 36/37 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Highly flammable. Irritating to eyes and respiratory system. Potential Health Effects The toxicological properties of this material have not been investigated. Use appropriate procedures to prevent opportunities for direct contact with the skin or eyes and to prevent inhalation. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Remove contaminated clothing and shoes. Ingestion: If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Flammable liquid and vapor. Extinguishing Media: In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Use agent most appropriate to extinguish fire. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up, then place into a suitable container for disposal. Section 7 - HANDLING and STORAGE Handling: Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep away from heat, sparks and flame. Storage: Keep away from heat, sparks, and flame. Flammables-area. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits. Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels. Exposure Limits CAS# 5194-50-3: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves and clothing to prevent skin exposure. Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin. Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use. Wear a NIOSH/MSHA or European Standard EN 149 approved full-facepiece airline respirator in the positive pressure mode with emergency escape provisions. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Not available. Color: Clearlight yellow liquid Odor: None reported. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 80.0 - 82.0 deg C @ 760.00mm Hg Freezing/Melting Point: 0 deg C Autoignition Temperature: Not available. Flash Point: -7 deg C ( 19.40 deg F) Explosion Limits, lower: .06 vol % Explosion Limits, upper: .02 vol % Decomposition Temperature: Solubility in water: Specific Gravity/Density: .7200g/cm3 Molecular Formula: CH3CH=CHCH=CHCH3 Molecular Weight: 82.13 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials, strong oxidants. Incompatibilities with Other Materials: Oxidizing agents. Hazardous Decomposition Products: Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, hydrogen bromide. Hazardous Polymerization: Has not been reported. Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 5194-50-3 unlisted. LD50/LC50: Not available. Carcinogenicity: cis-2, trans-4-Hexadiene - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: HEXADIENE Hazard Class: 3 UN Number: 2458 Packing Group: II IMO Shipping Name: HEXADIENE Hazard Class: 3 UN Number: 2458 Packing Group: II RID/ADR Shipping Name: HEXADIENES Hazard Class: 3 UN Number: 2458 Packing group: II Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XI F Risk Phrases: R 11 Highly flammable. R 36/37 Irritating to eyes and respiratory system. Safety Phrases: S 16 Keep away from sources of ignition - No smoking. WGK (Water Danger/Protection) CAS# 5194-50-3: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 5194-50-3 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 5194-50-3 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
| 危害码 (欧洲) | F: Flammable;Xi: Irritant; |
|---|---|
| 风险声明 (欧洲) | R11 |
| 安全声明 (欧洲) | 16-26-36 |
| 危险品运输编码 | UN 2458 3 |
| 包装等级 | II |
| 危险类别 | 3.1 |
| 海关编码 | 2901299090 |
| 上游产品 0 | |
|---|---|
| 下游产品 10 | |
| 海关编码 | 2901299090 |
|---|---|
| 中文概述 | 2901299090 其他不饱和无环烃。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:2.0%。普通关税:30.0% |
| 申报要素 | 品名, 成分含量, 用途, 用作气体燃料的应报明包装容器容积, 散装货物应报明 |
| Summary | 2901299090 unsaturated acyclic hydrocarbons。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:2.0%。General tariff:30.0% |
