28240-66-6

• 常用中文名：1,3-双(苯基膦酰)丙烷
• 常用英文名：1,3-bis-(Phenylphosphino)propane
• CAS号：28240-66-6
• 分子式：C₁₅H₁₈P₂
• 分子量：260.25100
• 发布时间：2018-04-12 08:00:00
• 更新时间：2024-01-14 12:05:02

名称

• 中文名: 1,3-双(苯基膦酰)丙烷
• 英文名: phenyl(3-phenylphosphanylpropyl)phosphane
• 中文别名: 1,3-双(苯基膦)丙烷
• 英文别名: MFCD00014079

物化性质

• 沸点: 160-165ºC 1mm
• 分子式: C₁₅H₁₈P₂
• 分子量: 260.25100
• 精确质量: 260.08800
• PSA: 27.18000
• LogP: 3.38450
• 蒸汽压: 0mmHg at 25°C
• 储存条件:

  保持贮藏器密封、储存在阴凉、干燥的地方，确保工作间有良好的通风或排气装置

• 稳定性:

  如果遵照规格使用和储存则不会分解，未有已知危险反应

  避免氧化物

• 计算化学:

  1.疏水参数计算参考值（XlogP）:3.1

  2.氢键供体数量:0

  3.氢键受体数量:0

  4.可旋转化学键数量:6

  5.互变异构体数量:无

  6.拓扑分子极性表面积0

  7.重原子数量:17

  8.表面电荷:0

  9.复杂度:161

  10.同位素原子数量:0

  11.确定原子立构中心数量:0

  12.不确定原子立构中心数量:0

  13.确定化学键立构中心数量:0

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:1

• 更多:

  1. 性状：无色液体

  2. 密度（g/mL,25℃）：未确定

  3. 相对蒸汽密度（g/mL,空气=1）：未确定

  4. 熔点（ºC）：未确定

  5. 沸点（ºC,常压）：未确定

  6. 沸点（ºC,0.13KPa）：160-165

  7. 折射率：未确定

  8. 闪点（ºC）：160-165

  9. 比旋光度（º）：未确定

  10. 自燃点或引燃温度（ºC）：未确定

  11. 蒸气压（Pa,25ºC）：未确定

  12. 饱和蒸气压（KPa,20ºC）：未确定

  13. 燃烧热（KJ/mol）：未确定

  14. 临界温度（ºC）：未确定

  15. 临界压力（KPa）：未确定

  16. 油水（辛醇/水）分配系数的对数值：未确定

  17. 爆炸上限（%,V/V）：未确定

  18. 爆炸下限（%,V/V）：未确定

  19. 溶解性：难溶于水

MSDS

Section 1: Product Identification Chemical Name:1,3-Bis(phenylphosphino)propane, 90-95% CAS Registry Number:28240-66-6 Formula:C6H5P(H)CH2CH2CH2(H)PC6H5 EINECS Number:none Chemical Family:organophosphine ligand Synonym:None Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title Compound28240-66-6100%no datano data Section 3: Hazards Identification Emergency Overview:Irritating to skin, eyes and respiratory tract. May be harmful if swallowed. Primary Routes of Exposure:Ingestion, inhalation Eye Contact:Causes slight to mild irritation of the eyes. Skin Contact:Causes slight to mild irritation of the skin. Inhalation:Irritating to the nose, mucous membranes and respiratory tract. Ingestion:No information on the physiological effects of ingestion. Acute Health Affects:Irritating to skin, eyes and respiratory tract. Chronic Health Affects:No information on the effects of long-term exposure. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:no data Autoignition Temperature:no data Explosion Limits:no data Extinguishing Medium:carbon dioxide, dry powder or foam If this material is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure Special Fire Fighting Procedures: self-contained breathing apparatus and full protective clothing. Hazardous Combustion andIf involved in a fire this material may emit toxic organic fumes. Decomposion Products: Unusual Fire or Explosion Hazards: Flammable liquid. No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures Remove sources of ignition. Small spills can be mixed with vermiculite, sodium carbonate or other suitable non Spill and Leak Procedures: combustible adsorbent and swept up. SECTION 7: Handling and Storage Store in a tightly sealed container. Keep away from heat and direct sunlight. Prolonged exposure to air may Handling and Storage: result in the degradation of the product. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear protective clothing and gloves. Ventilation:If possible, handle the material in an efficient fume hood. If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Respirator: Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:If possible, handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:colorless liq. Molecular Weight:260.26 Melting Point:no data Boiling Point:160-165°C/1 mm Vapor Pressure:no data Specific Gravity:no data Odor:mild odor Solubility in Water:insoluble SECTION 10: Stability and Reactivity Stability:air sensitive liquid Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:prolonged contact with air Incompatibility:oxidizing agents and halogens Decomposition Products:carbon dioxide, carbon monoxide, phosphorus oxide, and organic fumes SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files. Carcinogenic Effects:No data available Mutagenic Effects:No data available Tetratogenic Effects:No data available SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Flammable liquids, N.O.S. Hazard Class (CFR):3 Additional Hazard Class (CFR):NA Packaging Group (CFR):II UN ID Number (CFR):UN# 1993 Shipping Name (IATA):Flammable liquid, N.O.S. Hazard Class (IATA):3 Additional Hazard Class (IATA):NA Packaging Group (IATA):II UN ID Number (IATA):UN# 1993 SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory. SARA (Title 313):Title compound not listed. Second Ingredient:none SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

生态学数据: 通常对水是不危害的，若无政府许可，勿将材料排入周围环境。

安全

• 危害码 (欧洲): Xi
• 风险声明 (欧洲): 11
• 安全声明 (欧洲): 9-16-33
• 危险品运输编码: UN 1993
• 海关编码: 2902909090

海关

海关编码	2902909090
中文概述	2902909090. 其他芳香烃. 增值税率:17.0%. 退税率:9.0%. 监管条件:无. 最惠国关税:2.0%. 普通关税:30.0%
申报要素	品名, 成分含量
Summary	2902909090 other aromatic hydrocarbons。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:2.0%。General tariff:30.0%