67-72-1

67-72-1结构式

常用中文名：六氯乙烷
常用英文名：Hexachloroethane
CAS号：67-72-1
分子式：C₂Cl₆
分子量：236.739
相关类别：有机原料烃类化合物及其衍生物烃类卤化物
发布时间：2018-09-04 00:08:09
更新时间：2024-01-02 12:44:39
【用途一】
用作润滑油添加剂，亦可用于制造杀虫剂、驱虫剂、烟幕等
【用途二】
该品用作溶剂和用于生产氟里昂-113、农药、医药、兽药、发烟剂、除泡剂、铝制品的脱气剂、脱氧剂（铝、镁、铜及其合金）、切消油添加剂以及聚氯乙烯助增塑剂、有机合成中间体。六氯乙烷与锌粉、氯化铵、过氯酸铵等按比例混合可用作烟雾生成剂，六氯乙烷还用作樟脑代用品和橡胶硫化促进剂等。六氯乙烷本身也是一种兽用驱虫药。主要用于反刍兽肝蛭病及胃蛭病，其他睾吸虫病和线虫病等。
【用途三】
溶剂，防腐剂。该品用作溶剂和用于生产氟里昂-113、农药、医药、兽药、发烟剂、除泡剂、铝制品的脱气剂、脱氧剂（铝、镁、铜及其合金）、切消油添加剂以及聚氯乙烯助增塑剂、有机合成中间体。六氯乙烷与锌粉、氯化铵、过氯酸铵等按比例混合可用作烟雾生成剂，六氯乙烷还用作樟脑代用品和橡胶硫化促进剂等。六氯乙烷本身也是一种兽用驱虫药。主要用于反刍兽肝蛭病及胃蛭病，其他睾吸虫病和线虫病等。

中文名	六氯乙烷
英文名	hexachloroethane
中文别名	全氯乙烷六氯化二碳六氯化碳
英文别名	MFCD00000799 Hexachloroethane EINECS 200-666-4 Ethane, 1,1,1,2,2,2-hexachloro-

密度	1.8±0.1 g/cm3
沸点	186.8±0.0 °C at 760 mmHg
熔点	184 °C
分子式	C₂Cl₆
分子量	236.739
闪点	61.3±15.8 °C
精确质量	233.813110
LogP	4.47
外观性状	白色结晶粉末
蒸汽密度	8.16 (vs air)
蒸汽压	0.9±0.3 mmHg at 25°C
折射率	1.533
储存条件	储存注意事项储存于阴凉、通风的库房。远离火种、热源。包装密封。应与氧化剂、碱类、食用化学品分开存放，切忌混储。储区应备有合适的材料收容泄漏物。
稳定性	1.六氯乙烷能升华，在空气中逐渐挥发。化学性质稳定，常温下与水接触不发生分解。在酸或碱的水溶液中也不反应。与氯化锌反应生成四氯化碳。用锌和硫酸还原则生成四氯乙烯。高温热解生成四氯化碳、四氯乙烯和氯气。 2.稳定性稳定 3.禁配物强氧化剂、强碱、金属等 4.避免接触的条件光照、受热 5.聚合危害不聚合 6.分解产物氯化氢、光气
水溶解性	0.05 g/L (22 ºC)
分子结构	1、摩尔折射率：40.34 2、摩尔体积（cm³/mol）：129.9 3、等张比容（90.2K）：332.5 4、表面张力（dyne/cm）：42.8 5、极化率（10^-24cm³）：15.99
计算化学	1.疏水参数计算参考值（XlogP）:无 2.氢键供体数量:0 3.氢键受体数量:0 4.可旋转化学键数量:0 5.互变异构体数量:无 6.拓扑分子极性表面积0 7.重原子数量:8 8.表面电荷:0 9.复杂度:61.5 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:1
更多	1.性状：无色结晶，有樟脑样气味。 2.熔点（升华，℃）：186 3.沸点（℃）：186（103.34kPa，升华） 4.相对密度（水=1）：2.09 5.相对蒸气密度（空气=1）：8.16 6.饱和蒸气压（kPa）：0.13（32.7℃） 7.临界压力（MPa）：3.34 8.辛醇/水分配系数：3.82~4.19 9.溶解性：不溶于水，溶于乙醇、乙醚、苯、氯仿、油类等多数有机溶剂。 10.气相标准声称热(焓)( kJ·mol^-1) ：-138.9 11.气相标准熵(J·mol^-1·K^-1) ：398.85 12.气相标准生成自由能( kJ·mol^-1)：-54.9 13.气相标准热熔(J·mol^-1·K^-1)：136.73 14.液相标准声称热(焓)( kJ·mol^-1)：-187.6 15.液相标准熵(J·mol^-1·K^-1) ：245.6 16.液相标准生成自由能( kJ·mol^-1)：-83.47 17.液相标准热熔(J·mol^-1·K^-1)：196.2 18.蒸发热（KJ/kg,b.p.）：194.2 19.燃烧热（KJ/mol,20ºC,固体）：461 20.生成热（KJ/mol,20ºC,结晶）：226 21.生成热（KJ/mol,20ºC,气体）：154.9 22.比热容（KJ/(kg·K),25ºC,定压）：0.729

国标编号:	61558
ＣＡＳ:	67-72-1
中文名称:	六氯乙烷
英文名称:	hexachloroethane；carbon hexachloride
别名:	六氯化碳
分子式:	C₂Cl₆；CCl₃CCl₃
分子量:	236.76
熔点:	186℃/升华沸点：186
密度:	相对密度(水=1)2.09
蒸汽压:	32.7℃
溶解性:	不溶于水，溶于醇、苯、氯仿、油类等多数有机溶剂
稳定性:	稳定
外观与性状:	无色结晶，有樟脑样气味
危险标记:	14(有毒品)
用途:	用于有机合成、医药等。也用作溶剂

2、对环境的影响

该物质对环境可能有危害，在地下水中有蓄积作用。在对人类重要食物链中，特别是在水生生物中发生生物蓄积。

一、健康危害

侵入途径：吸入、食入、经皮吸收。健康危害：本品对中枢神经系统有麻醉作用，对肝、肾有损害；对皮肤粘膜有轻度刺激作用。误服出现眩晕、呕吐、肝区痛、血中胆红素增高、心率减慢、肾炎及无尿。动物实验见软弱无力、嗜睡、步态不稳、后肢轻瘫；亦可见痉挛、心率加快、昏睡、腹泻、食欲减退等。

二、毒理学资料及环境行为

毒性：属低毒类。急性毒性：LD504460mg/kg(大鼠经口)；大鼠吸入57mg/L×8小时，致死。亚急性和慢性毒性：大鼠经口1.5mg/kg/日×110日，肾功能异常；大鼠经口80mg/kg/日×110日，肝、肾细胞坏死，功能异常。致突变性：Ames试验沙门氏菌株(五个菌种)+S9阴性。致癌性：大鼠经口致肝瘤。

危险特性：高热时能分解出剧毒的光气。燃烧(分解)产物：氯化氢、光气。

3、现场应急监测方法

4、实验室监测方法

气相色谱法《城市和工业废水中有机化合物分析》王克欧等编气相色谱法《固体废弃物试验分析评价手册》中国环境监测总站等译色谱-质谱法《水和废水标准检验法》19版译文，江苏省环境监测中心

5、环境标准

前西德(1982)	职业环境空气中最高容许浓度	10mg/m³
前苏联(1982)	地面水中最高容许浓度	0.01mg/L
前苏联(1975)	污水排放标准	2mg/L

6、应急处理处置方法一、泄漏应急处理

隔离泄漏污染区，限制出入。建议应急处理人员戴自给式呼吸器，穿一般作业工作服。小量泄漏：用洁净的铲子收集于干燥、洁净、有盖的容器中。大量泄漏：收集、回收或运至废物处理场所处置。废弃物处置方法：用焚烧法。废料同其它燃料混合后焚烧，燃烧要充分，防止生成光气。焚烧炉排气中的卤化氢通过酸洗涤器除去。

二、防护措施

呼吸系统防护：可能接触其粉尘时，应该佩戴自吸过滤式防尘口罩。紧急事态抢救或撤离时，建议佩戴自给式呼吸器。眼睛防护：一般不需要特殊防护，高浓度接触时可戴安全防护眼镜。身体防护：穿透气型防毒服。手防护：戴防化学品手套。其它：工作现场禁止吸烟、进食和饮水。工作毕，沐浴更衣。单独存放被毒物污染的衣服，洗后备用。注意个人清洁卫生。

三、急救措施

皮肤接触：脱去被污染的衣着，用肥皂水和清水彻底冲洗皮肤。眼睛接触：提起眼睑，用流动清水或生理盐水冲洗。就医吸入：迅速脱离现场至空气新鲜处。保持呼吸道通畅。如呼吸困难，给输氧。如呼吸停止，立即进行人工呼吸。就医。食入：饮足量温水，催吐，洗胃。就医。

灭火方法：消防人员须佩戴防毒面具、穿全身消防服。喷水保持火场容器冷却，直至灭火结束。灭火剂：雾状水、泡沫、二氧化碳、砂土。

毒理学数据:

1.急性毒性LD50：4460mg/kg（大鼠经口）

2.刺激性暂无资料

3.致突变性姐妹染色单体交换：仓鼠卵巢330mg/L

4.致癌性 IARC致癌性评论：G2B，可疑人类致癌物。

生态学数据:

1.生态毒性

LC50：0.98mg/L（96h）（虹鳟鱼，动态）；1.53mg/L（96h）（黑头呆鱼，动态）；2.9mg/L（48h）（水蚤）

2.生物降解性

好氧生物降解（h）：672~4320

厌氧生物降解（h）：2688~17280

3.非生物降解性暂无资料

4.其他有害作用该物质对环境可能有危害，在地下水中有蓄积作用。在对人类重要食物链中，特别是在水生生物中发生生物蓄积。

CHEMICAL IDENTIFICATION

RTECS NUMBER :: KI4025000

CHEMICAL NAME :: Ethane, hexachloro-

CAS REGISTRY NUMBER :: 67-72-1

BEILSTEIN REFERENCE NO. :: 1740341

LAST UPDATED :: 199712

DATA ITEMS CITED :: 62

MOLECULAR FORMULA :: C2-Cl6

MOLECULAR WEIGHT :: 236.72

WISWESSER LINE NOTATION :: GXGGXGGG

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 4460 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LCLo - Lowest published lethal concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 5900 ppm/8H

TOXIC EFFECTS :: Behavioral - muscle weakness

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 2900 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 4500 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Intravenous

SPECIES OBSERVED :: Mammal - dog

DOSE/DURATION :: 325 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD - Lethal dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: >1 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 32 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Subcutaneous

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 4 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - guinea pig

DOSE/DURATION :: 4970 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 6944 mg/kg/16W-C

TOXIC EFFECTS :: Liver - changes in liver weight Kidney, Ureter, Bladder - changes in tubules (including acute renal failure, acute tubular necrosis) Kidney, Ureter, Bladder - changes in bladder weight

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 9 gm/kg/16D-I

TOXIC EFFECTS :: Related to Chronic Data - death

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 48750 mg/kg/13W-I

TOXIC EFFECTS :: Brain and Coverings - changes in brain weight Liver - changes in liver weight Kidney, Ureter, Bladder - changes in bladder weight

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 260 ppm/6H/6W-I

TOXIC EFFECTS :: Kidney, Ureter, Bladder - changes in bladder weight Endocrine - changes in spleen weight Related to Chronic Data - changes in testicular weight

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 12 gm/kg/12D-C

TOXIC EFFECTS :: Liver - other changes Kidney, Ureter, Bladder - other changes Nutritional and Gross Metabolic - weight loss or decreased weight gain

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - guinea pig

DOSE/DURATION :: 260 ppm/6H/6W-I

TOXIC EFFECTS :: Liver - changes in liver weight Related to Chronic Data - death

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 10300 mg/kg/2Y-C

TOXIC EFFECTS :: Tumorigenic - Carcinogenic by RTECS criteria Liver - tumors

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 230 gm/kg/78W-I

TOXIC EFFECTS :: Tumorigenic - Carcinogenic by RTECS criteria Liver - tumors

TYPE OF TEST :: TD - Toxic dose (other than lowest)

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 460 gm/kg/78W-I

TOXIC EFFECTS :: Tumorigenic - Carcinogenic by RTECS criteria Liver - tumors

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

DOSE :: 5500 mg/kg

SEX/DURATION :: female 6-16 day(s) after conception

TOXIC EFFECTS :: Reproductive - Fertility - litter size (e.g. # fetuses per litter; measured before birth) Reproductive - Fertility - other measures of fertility

TYPE OF TEST :: Mutation test systems - not otherwise specified

MUTATION DATA

TYPE OF TEST :: Sister chromatid exchange

TEST SYSTEM :: Rodent - hamster Ovary

REFERENCE :: EMMUEG Environmental and Molecular Mutagenesis. (Alan R. Liss, Inc., 41 E. 11th St., New York, NY 10003) V.10- 1987- Volume(issue)/page/year: 10(Suppl 10),1,1987 *** REVIEWS *** ACGIH TLV-Animal carcinogen DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 ACGIH TLV-TWA 9.7 mg/m3 (1 ppm) (skin) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 IARC Cancer Review:Animal Limited Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 20,467,1979 IARC Cancer Review:Human No Adequate Data IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 20,467,1979 IARC Cancer Review:Group 3 IMSUDL IARC Monographs, Supplement. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) No.1- 1979- Volume(issue)/page/year: 7,56,1987 TOXICOLOGY REVIEW AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 40(3),A46,1979 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 1 ppm (10 mg/m3) (skin) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,124,1971 OSHA PEL (Gen Indu):8H TWA 1 ppm (10 mg/m3) (skin) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 1 ppm (10 mg/m3) (skin) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 1 ppm (10 mg/m3) (skin) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 1 ppm (10 mg/m3) (skin) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 10 ppm (100 mg/m3) JAN 1993 OEL-BELGIUM:TWA 1 ppm (9.7 mg/m3) JAN 1993 OEL-DENMARK:TWA 1 ppm (10 mg/m3);Skin JAN 1993 OEL-FINLAND:TWA 1 ppm (10 mg/m3);STEL 3 ppm (30 mg/m3);Skin JAN 1993 OEL-FRANCE:TWA 10 ppm (100 mg/m3) JAN 1993 OEL-GERMANY:TWA 1 ppm (10 mg/m3) JAN 1993 OEL-THE NETHERLANDS:TWA 1 ppm (10 mg/m3);Skin JAN 1993 OEL-THE PHILIPPINES:TWA 1 ppm (10 mg/m3);Skin JAN 1993 OEL-SWITZERLAND:TWA 1 ppm (10 mg/m3);Skin JAN 1993 OEL-UNITED KINGDOM:TWA 5 mg/m3 (resp. dust) JAN 1993 OEL-UNITED KINGDOM:TWA 5 ppm (50 mg/m3) (vapor) JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO HEXACHLOROETHANE-air:8H CA TWA 1 ppm REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992 NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 17385 No. of Facilities: 219 (estimated) No. of Industries: 5 No. of Occupations: 9 No. of Employees: 1488 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 17385 No. of Facilities: 170 (estimated) No. of Industries: 12 No. of Occupations: 23 No. of Employees: 8516 (estimated) No. of Female Employees: 576 (estimated)

符号	GHS07, GHS08, GHS09
信号词	Warning
危害声明	H315-H319-H335-H351-H410
警示性声明	P261-P273-P281-P305 + P351 + P338-P501
个人防护装备	Eyeshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges
危害码 (欧洲)	Xn:Harmful
风险声明 (欧洲)	R36/37/38;R40;R51/53
安全声明 (欧洲)	S36/37-S61-S45-S36/37/39-S26-S24-S16-S7
危险品运输编码	UN 9037
WGK德国	3
RTECS号	KI4025000
包装等级	III
危险类别	9
海关编码	2942000000

上游产品 10
127-18-4 56-23-5 79-34-5 10170-69-1
75-68-3 773-14-8 355-79-3 87-68-3
6430-25-7 624-74-8
下游产品 10
60736-71-2 150444-93-2 127-18-4 507-20-0
946061-13-8 56-23-5 1291-32-3 126859-53-8
75-44-5 110-81-6

1.由四氯乙烷经氯化而得。将脱水后的四氯乙烷投入搪玻离反应锅，在强光照射下通入氯气，反应温度逐渐上升，最后保持在90-100℃。当反应液由浑转清，通氯管出现结晶时，氯化即到达终点。停止通氯，提高温度至120℃，排出锅内余氯到达终点。停止通氯，提出高温度至120℃，排出锅内余氯。出料至盛有沸水的结晶锅内，用热水洗涤，再加1%碳酸钠和5%尿素溶液搅拌除氯。用水充分洗涤后后冷却结晶，离心过滤，最后将结晶浸泡于蒸馏水中再甩干，于40℃干燥、粉碎即得六氯乙烷。工业上也采用三氯乙烯与氯气进行光氯化。三氯乙烯与氯气发生光氯化反应生成五氯乙烷，再与液碱作用生成四氯乙烯。四氯乙烯与液氯（1：0.213）经光氯化反应制得粗制品，再经纯碱液中和、水洗、冷却结晶、离心过滤、干燥，粉碎而得成品。用此法生产六氯乙烷，每吨产品消耗三氯乙烯680kg，液氯700kg。另外，四氯化碳在氯化铝存在下与氯气反应，或乙烯在300-350℃，与氯反应都可制得该品。

海关编码	2942000000

67-72-1	93952-15-9
13465-77-5	1089719-72-1
18024-00-5	15873-56-0
76-01-7	1622-32-8
79-34-5	25323-89-1
1158522-08-7	940364-43-2
134104-43-1	131615-57-1
6906-52-1	930439-75-1
1018584-77-4	1375289-11-4
849349-65-1	127437-46-1