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| 中文名 | 2,2,6,6-四甲基-3,5-庚二酮基[[Rb(TMHD)] |
|---|---|
| 英文名 | 2,2,6,6-tetramethyl-3,5-heptanedionato rubidium |
| 英文别名 |
RB(TMHD)
RUBIDIUM 2,2,6,6-TETRAMETHYLHEPTANEDIONATE 2,2,5-TRIMETHYL-1,3-DIOXANE-5-CARBOXYLIC ACID METHYL ESTER-D3 2,2,6,6-Tetramethyl-3,5-heptanedionato rubidium [Rb(TMHD)] |
| 分子式 | C11H19O2Rb |
|---|---|
| 分子量 | 268.73500 |
| 精确质量 | 268.05000 |
| PSA | 40.13000 |
| LogP | 2.96210 |
| 计算化学 | 1、 疏水参数计算参考值（XlogP）：1.5 2、 氢键供体数量：0 3、 氢键受体数量：2 4、 可旋转化学键数量：1 5、 互变异构体数量：4 6、 拓扑分子极性表面积（TPSA）：37.4 7、 重原子数量：15 8、 表面电荷：0 9、 复杂度：292 10、同位素原子数量：0 11、确定原子立构中心数量：0 12、不确定原子立构中心数量：1 13、确定化学键立构中心数量：0 14、不确定化学键立构中心数量：0 15、共价键单元数量：1 |
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Section 1: Product Identification Chemical Name:2,2,6,6-Tetramethyl-3,5-heptanedionato rubidium Rb(TMHD) CAS Registry Number:166439-15-2 Formula:RbC11H19O2 EINECS Number:none Chemical Family:metal beta-diketonate complexes Synonym:Dipivaloylmethane, rubidium complex
Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title Compound166439-15-2100%no datano data Section 3: Hazards Identification Emergency Overview:No particular hazard associated with this material. May be irritating to skin, eyes and respiratory tract. Primary Routes of Exposure:Ingestion, inhalation Eye Contact:May cause slight to mild irritation of the eyes. Skin Contact:May cause slight to mild irritation of the skin. Inhalation:May be irritating to the nose, mucous membranes and respiratory tract. Ingestion:No specific information is available on the physiological effects of ingestion. Acute Health Affects:May be irritating to skin, eyes and respiratory tract. Chronic Health Affects:No information available on long-term chronic effects. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with soap and water. Remove contaminated clothes if necessary. Seek medical Skin Exposure: assistance if irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Ingestion:Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). SECTION 5: Fire Fighting Measures Flash Point:not applicable Autoignition Temperature:none Explosion Limits:none Extinguishing Medium:carbon dioxide, dry powder or foam If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained Special Fire Fighting Procedures: breathing apparatus and full protective clothing. Hazardous Combustion andIf involved in a fire this material may emit toxic organic fumes. Decomposion Products: Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures Spill and Leak Procedures:Small spills can be mixed with vermiculite or sodium carbonate and swept up. SECTION 7: Handling and Storage Handling and Storage:Store in a sealed container. Keep away from heat and moisture. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear appropriate chemical resistant gloves and protective clothing. Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood. If in form of fine dust and ventilation is not available a respirator should be worn. The use of respirators Respirator: requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:white to off-white pwdr. Molecular Weight:268.74 Melting Point:no data Boiling Point:no data Vapor Pressure:no data Specific Gravity:no data Odor:none Solubility in Water:soluble SECTION 10: Stability and Reactivity Stability:air and moisture stable solid Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:none Incompatibility:Oxidizing agents Decomposition Products:Carbon dioxide, carbon monoxide, organic vapors, and metal oxides and carbonates. SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files. Carcinogenic Effects:No data available Mutagenic Effects:No data available Tetratogenic Effects:No data available SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Non-hazardous Hazard Class (CFR):NA Additional Hazard Class (CFR):NA Packaging Group (CFR):NA UN ID Number (CFR):NA Shipping Name (IATA):Non-hazardous Hazard Class (IATA):NA Additional Hazard Class (IATA):NA Packaging Group (IATA):NA UN ID Number (IATA):NA SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory. SARA (Title 313):Title compound not listed. Second Ingredient:none SECTION 16 - ADDITIONAL INFORMATION N/A |
| 风险声明 (欧洲) | R36/37/38 |
|---|---|
| 安全声明 (欧洲) | S26;S36/S37/S39 |