13992-25-1

• 常用中文名：2,3,4,6-四-O-乙酰基-β-D-叠氮化吡喃葡萄糖
• 常用英文名：1-Azido-2,3,4,6-tetra-O-acetyl-beta-D-glucose
• CAS号：13992-25-1
• 分子式：C₁₄H₁₉N₃O₉
• 分子量：373.31500
• 相关类别： 生物化工 糖类化合物 单糖
• 发布时间：2018-12-16 19:21:15
• 更新时间：2024-01-30 14:35:51
• 2,3,4,6-四-O-乙酰基-β-D-吡喃半乳糖叠氮化物是一种生物化学试剂,可作为生物材料或有机化合物用于生命科学相关研究。

名称

• 中文名: 1-叠氮-1-脱氧-β-D-吡喃葡萄糖苷四乙酸酯
• 英文名: 1-AZIDO-2,3,4,6-TETRA-O-ACETYL-β-D-GLUCOSE
• 中文别名: 1-叠氮-1-脱氧-β-D-吡喃葡萄糖苷四乙酸
• 英文别名: 2,3,4,6-Tetra-O-acetyl-b-D-glucopyranosylazide; 2,3,4,6-TETRA-O-ACETYL-SS-D-GLUCOPYRANOSYL AZIDE; MFCD00216966; 2,3,4,6-Tetra-O-acetyl-D-glucopyranosyl azide; 1-AZIDO-2,3,4,6-TETRA-O-ACETYL-B-D-GLUCOSE; acetic acid 3,4,5-triacetoxy-6-azido-tetrahydro-pyran-2-ylmethyl ester; 1-Azido-2,3,4,6-tetra-O-acetyl-D-glucose; 1-AZIDO-2,3,4,6-TETRA-O-ACETYL-SS-D-GLUCOSE

物化性质

• 熔点: 127-131 °C(lit.)
• 分子式: C₁₄H₁₉N₃O₉
• 分子量: 373.31500
• 精确质量: 373.11200
• PSA: 164.18000
• 外观性状: 米色固体
• 储存条件: 2-8℃
• 分子结构:

  1、摩尔折射率：无可用的

  2、摩尔体积（cm³/mol）：无可用的

  3、等张比容（90.2K）：无可用的

  4、表面张力（dyne/cm）：无可用的

  5、介电常数：无可用的

  6、极化率（10^-24cm³）：无可用的

  7、单一同位素质量：373.112129 Da

  8、标称质量：373 Da

  9、平均质量：373.3154 Da

• 更多:

  1．性状：不可用

  2．密度（g/mL,25/4℃）：不可用

  3．相对蒸汽密度（g/mL,空气=1）：不可用

  4．熔点（ºC）：127-131

  5．沸点（ºC,常压）：不可用

  6．沸点（ºC,5.2kPa）：不可用

  7．折射率：不可用

  8．闪点（ºC）：不可用

  9．比旋光度（º）：不可用

  10．自燃点或引燃温度（ºC）：不可用

  11．蒸气压（kPa,25ºC）：不可用

  12．饱和蒸气压（kPa,60ºC）：不可用

  13．燃烧热（KJ/mol）：不可用

  14．临界温度（ºC）：不可用

  15．临界压力（KPa）：不可用

  16．油水（辛醇/水）分配系数的对数值：不可用

  17．爆炸上限（%,V/V）：不可用

  18．爆炸下限（%,V/V）：不可用

  19．溶解性：不可用

生物活性

• 描述: 2,3,4,6-四-O-乙酰基-β-D-吡喃半乳糖叠氮化物是一种生物化学试剂,可作为生物材料或有机化合物用于生命科学相关研究。
• 相关类别:
  研究领域 >> 其他

MSDS

Name: 2 3 4 6-Tetra-o-acetyl-betha-d-glucopyranosyl azide 98% Material Safety Data Sheet Synonym: CAS: 13992-25-1 Section 1 - Chemical Product MSDS Name:2 3 4 6-Tetra-o-acetyl-betha-d-glucopyranosyl azide 98% Material Safety Data Sheet Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 13992-25-1 2,3,4,6-TETRA-O-ACETYL-BETHA-D-GLUCOPY 98% unlisted Hazard Symbols: None Listed. Risk Phrases: None Listed. Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW The toxicological properties of this material have not been fully investigated.Light sensitive. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. Ingestion: The toxicological properties of this substance have not been fully investigated. Inhalation: May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Chronic: No information found. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Ingestion: If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Section 7 - HANDLING and STORAGE Handling: Wash thoroughly after handling. Use with adequate ventilation. Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Store in a cool, dry place. Store in a tightly closed container. Keep under a nitrogen blanket. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 13992-25-1: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: beige Odor: None reported. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 129 - 130 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C14H19N3O9 Molecular Weight: 373.32 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Oxidizing materials. Hazardous Decomposition Products: Carbon monoxide, oxides of nitrogen, carbon dioxide. Hazardous Polymerization: Has not been reported. Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 13992-25-1 unlisted. LD50/LC50: Not available. Carcinogenicity: 2,3,4,6-TETRA-O-ACETYL-BETHA-D-GLUCOPYRANOSYL AZIDE - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Not regulated as a hazardous material. IMO Not regulated as a hazardous material. RID/ADR Not regulated as a hazardous material. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: Not available. Risk Phrases: Safety Phrases: S 24/25 Avoid contact with skin and eyes. WGK (Water Danger/Protection) CAS# 13992-25-1: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 13992-25-1 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 13992-25-1 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

毒理学数据: 急性毒性：不可用。 生态学数据: 1、其它有害作用：该物质对环境可能有危害，对水体应给予特别注意。

安全

• 个人防护装备: Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter
• 危害码 (欧洲): Xi: Irritant;
• 风险声明 (欧洲): R2
• 安全声明 (欧洲): S22-S24/25
• 危险品运输编码: 1325
• WGK德国: 3

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