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| 中文名 | 2-异丙烯基-2-氧唑啉 |
|---|---|
| 英文名 | 2-prop-1-en-2-yl-4,5-dihydro-1,3-oxazole |
| 中文别名 | 2-异丙烯基噁唑啉 |
| 英文别名 |
2-isopropenyl-2-oxazoline
isopropenyl oxazoline Oxazole,4,5-dihydro-2-(1-methylethenyl) 2-isopropenyl-4,5-dihydro-oxazole 2-isopropenyloxazoline 2-(1-methylethenyl)-4,5-dihydrooxazole 2-(Prop-1-en-2-yl)-4,5-dihydro-1,3-oxazole 2-Isopropenyl-4,5-dihydro-1,3-oxazole 2-(Propen-2-yl)-4,5-dihydro-1,3-oxazole Oxazole, 4,5-dihydro-2-(1-methylethenyl)- |
| 密度 | 1.0±0.1 g/cm3 |
|---|---|
| 沸点 | 116.7±9.0 °C at 760 mmHg |
| 熔点 | -47ºC(lit.) |
| 分子式 | C6H9NO |
| 分子量 | 111.142 |
| 闪点 | 25.3±11.2 °C |
| 精确质量 | 111.068413 |
| PSA | 21.59000 |
| LogP | 0.29 |
| 蒸汽压 | 21.4±0.2 mmHg at 25°C |
| 折射率 | 1.490 |
| 储存条件 | 2-8°C |
|
SECTION 1: Identification of the substance/mixture and of the company/undertaking Product identifiers Product name: 2-Isopropenyl-2-oxazoline REACH No.: A registration number is not available for this substance as the substance or its uses are exempted from registration, the annual tonnage does not require a registration or the registration is envisaged for a later registration deadline.
CAS-No.: 10471-78-0 Relevant identified uses of the substance or mixture and uses advised against Identified uses: Laboratory chemicals, Manufacture of substances SECTION 2: Hazards identification Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 Flammable liquids (Category 3), H226 Acute toxicity, Inhalation (Category 3), H331 Skin irritation (Category 2), H315 Eye irritation (Category 2), H319 Specific target organ toxicity - single exposure (Category 3), Respiratory system, H335 For the full text of the H-Statements mentioned in this Section, see Section 16. Classification according to EU Directives 67/548/EEC or 1999/45/EC R10 T ToxicR23 Xi IrritantR36/37/38 For the full text of the R-phrases mentioned in this Section, see Section 16. Label elements Labelling according Regulation (EC) No 1272/2008 Pictogram Signal wordDanger Hazard statement(s) H226Flammable liquid and vapour. H315Causes skin irritation. H319Causes serious eye irritation. H331Toxic if inhaled. H335May cause respiratory irritation. Precautionary statement(s) P261Avoid breathing vapours. P305 + P351 + P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P311Call a POISON CENTER or doctor/ physician. Supplemental Hazardnone Statements Contains: Phenothiazine. May produce an allergic reaction. Sensitising components: Phenothiazine May produce an allergic reaction. Other hazards - none SECTION 3: Composition/information on ingredients Substances Formula: C6H9NO Molecular Weight: 111,14 g/mol CAS-No.: 10471-78-0 Hazardous ingredients according to Regulation (EC) No 1272/2008 ComponentClassificationConcentration 2-Isopropenyl-2-oxazoline CAS-No.10471-78-0Flam. Liq. 3; Acute Tox. 3;50 - 100 % Skin Irrit. 2; Eye Irrit. 2; STOT SE 3; H226, H315, H319, H331, H335 Phenothiazine CAS-No.92-84-2Acute Tox. 4; Skin Sens. 1;0,1 - 1 % EC-No.202-196-5STOT RE 2; Aquatic Chronic 3; H302, H317, H373, H412 Hazardous ingredients according to Directive 1999/45/EC ComponentClassificationConcentration 2-Isopropenyl-2-oxazoline CAS-No.10471-78-0T, R23 - R10 - R36/37/3850 - 100 % Phenothiazine CAS-No.92-84-2Xn, R22 - R43 - R48/22 -0,1 - 1 % EC-No.202-196-5R52/53 For the full text of the H-Statements and R-Phrases mentioned in this Section, see Section 16 SECTION 4: First aid measures Description of first aid measures General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 Indication of any immediate medical attention and special treatment needed no data available SECTION 5: Firefighting measures Extinguishing media Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Special hazards arising from the substance or mixture Carbon oxides, nitrogen oxides (NOx) Advice for firefighters Wear self contained breathing apparatus for fire fighting if necessary. Further information Use water spray to cool unopened containers. SECTION 6: Accidental release measures Personal precautions, protective equipment and emergency procedures Wear respiratory protection. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. For personal protection see section 8. Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Methods and materials for containment and cleaning up Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations (see section 13). Reference to other sections For disposal see section 13. SECTION 7: Handling and storage Precautions for safe handling Avoid contact with skin and eyes. Avoid inhalation of vapour or mist. Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic charge. For precautions see section 2.2. Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Recommended storage temperature: 2 - 8 °C Specific end use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated SECTION 8: Exposure controls/personal protection Control parameters Components with workplace control parameters Exposure controls Appropriate engineering controls Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product. Personal protective equipment Eye/face protection Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Body Protection Complete suit protecting against chemicals, Flame retardant antistatic protective clothing, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Control of environmental exposure Prevent further leakage or spillage if safe to do so. Do not let product enter drains. SECTION 9: Physical and chemical properties Information on basic physical and chemical properties a) AppearanceForm: liquid Colour: yellow b) Odourno data available c) Odour Thresholdno data available d) pHno data available e) Melting point/freezingMelting point/range: -47 °C - lit. point f) Initial boiling point and 147 °C - lit. boiling range g) Flash point48 °C - closed cup h) Evapouration rateno data available i) Flammability (solid, gas) no data available j) Upper/lowerno data available flammability or explosive limits k) Vapour pressureno data available l) Vapour densityno data available m) Relative density1,06 g/cm3 at 25 °C n) Water solubilitysoluble o) Partition coefficient: n- log Pow: 0,769 at 25 °C octanol/water p) Auto-ignitionno data available temperature q) Decompositionno data available temperature r) Viscosityno data available s) Explosive propertiesno data available t) Oxidizing propertiesno data available Other safety information Bulk density1.470 kg/m3 SECTION 10: Stability and reactivity Reactivity no data available Chemical stability Stable under recommended storage conditions. Contains the following stabiliser(s): Phenothiazine (0,1 %) Possibility of hazardous reactions no data available Conditions to avoid Heat, flames and sparks. Incompatible materials Strong oxidizing agents Hazardous decomposition products Other decomposition products - no data available In the event of fire: see section 5 SECTION 11: Toxicological information Information on toxicological effects Acute toxicity no data available Skin corrosion/irritation no data available Serious eye damage/eye irritation no data available Respiratory or skin sensitisation no data available Germ cell mutagenicity no data available Carcinogenicity IARC:No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Reproductive toxicity no data available Specific target organ toxicity - single exposure no data available Specific target organ toxicity - repeated exposure no data available Aspiration hazard no data available Additional Information RTECS: Not available SECTION 12: Ecological information Toxicity no data available Persistence and degradability no data available Bioaccumulative potential no data available Mobility in soil no data available Results of PBT and vPvB assessment PBT/vPvB assessment not available as chemical safety assessment not required/not conducted Other adverse effects no data available SECTION 13: Disposal considerations Waste treatment methods Product Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting as this material is highly flammable. Offer surplus and non-recyclable solutions to a licensed disposal company. Contaminated packaging Dispose of as unused product. SECTION 14: Transport information UN number ADR/RID: 3384IMDG: 3384IATA: 3384 UN proper shipping name ADR/RID: TOXIC BY INHALATION LIQUID, FLAMMABLE, N.O.S. (2-Isopropenyl-2-oxazoline) IMDG: TOXIC BY INHALATION LIQUID, FLAMMABLE, N.O.S. (2-Isopropenyl-2-oxazoline) IATA:Toxic by inhalation liquid, flammable, n.o.s. (2-Isopropenyl-2-oxazoline) Passenger Aircraft: Not permitted for transport Cargo Aircraft: Not permitted for transport Transport hazard class(es) ADR/RID: 6.1 (3)IMDG: 6.1 (3)IATA: 6.1 (3) Packaging group ADR/RID: IIMDG: IIATA: - Environmental hazards ADR/RID: noIMDG Marine pollutant: noIATA: no Special precautions for user no data available SECTION 15 - REGULATORY INFORMATION N/A SECTION 16 - ADDITIONAL INFORMATION N/A |
| 符号 |
GHS02, GHS06 |
|---|---|
| 信号词 | Danger |
| 危害声明 | H226-H315-H319-H331-H335 |
| 警示性声明 | P261-P305 + P351 + P338-P311 |
| 个人防护装备 | Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter |
| 危害码 (欧洲) | T: Toxic; |
| 风险声明 (欧洲) | 10-23-36/37/38 |
| 安全声明 (欧洲) | 26-36-45 |
| 危险品运输编码 | UN 3384 6.1/PG 1 |
| 海关编码 | 2934999090 |
| 海关编码 | 2934999090 |
|---|---|
| 中文概述 | 2934999090. 其他杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0% |
| 申报要素 | 品名, 成分含量, 用途 |
| Summary | 2934999090. other heterocyclic compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0% |