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| 中文名 | 碘化镍六胺络合物 |
|---|---|
| 英文名 | azane,diiodonickel |
| 中文别名 | 碘化镍(II)六胺络合物 |
| 英文别名 |
Nickel(2+),hexaammine-,diiodide,(OC-6-11)-(9CI)
Hexaamminenickel(II) iodide Hexaamminenickel(2+) diiodide MFCD00058808 Nickel(2+),hexaammine-,diiodide (8CI) Hexaamminenickeldiiodide (6CI,7CI) Hexaamminenickel iodide |
| 分子式 | H18I2N6Ni |
|---|---|
| 分子量 | 414.68500 |
| 精确质量 | 413.90400 |
| PSA | 19.44000 |
| 储存条件 | 常温密闭，阴凉通风干燥 |
| 稳定性 | 常温常压下稳定 避免的物料 氧化物 光 |
| 分子结构 | 1、摩尔折射率：无可用的 2、摩尔体积（cm3/mol）：无可用的 3、等张比容（90.2K）：无可用的 4、表面张力（dyne/cm）：无可用的 5、介电常数：无可用的 6、极化率（10-24cm3）：无可用的 7、单一同位素质量：413.903564 Da 8、标称质量：414 Da 9、平均质量：414.6855 Da |
| 计算化学 | 1.疏水参数计算参考值（XlogP）:无 2.氢键供体数量:6 3.氢键受体数量:6 4.可旋转化学键数量:0 5.互变异构体数量:无 6.拓扑分子极性表面积6 7.重原子数量:9 8.表面电荷:0 9.复杂度:2.8 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:7 |
| 更多 | 1. 性状：晶体 2. 密度（g/mL,25/4℃）：未确定 3. 相对蒸汽密度（g/mL,空气=1）：未确定 4. 熔点（ºC）：未确定 5. 沸点（ºC,常压）：未确定 6. 沸点（ºC,5.2kPa）：未确定 7. 折射率：未确定 8. 闪点（ºC）：未确定 9. 比旋光度（º）：未确定 10. 自燃点或引燃温度（ºC）：不适用的 11. 蒸气压（kPa,25ºC）：未确定 12. 饱和蒸气压（kPa,60ºC）：未确定 13. 燃烧热（KJ/mol）：未确定 14. 临界温度（ºC）：未确定 15. 临界压力（KPa）：未确定 16. 油水（辛醇/水）分配系数的对数值：未确定 17. 爆炸上限（%,V/V）：未确定 18. 爆炸下限（%,V/V）：未确定 19. 溶解性：未确定 |
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Section 1: Product Identification Chemical Name:Hexaamminenickel (II) iodide,98% CAS Registry Number:13859-68-2 Formula:[Ni(NH3)6]I2 EINECS Number:237-205-1 Chemical Family:metal-ammine complexes Synonym:Nickel, hexammine (II) iodide
Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title Compound13859-68-2100%0.1mg/m3 (as Ni)1mg/m3 (as Ni) Section 3: Hazards Identification Ingestion of nickel salts may cause intestinal disorders, convulsions, and asphyxia. Irritating to skin, eyes and Emergency Overview: respiratory tract. May cause cancer. Primary Routes of Exposure:Ingestion, inhalation of dust Eye Contact:Causes slight to mild irritation of the eyes. Skin Contact:Causes slight to mild irritation of the skin. Prolonged contact with nickel salts may lead to dermatitis. Inhalation:Irritating to the nose, mucous membranes and respiratory tract. Ingestion:Ingestion may lead to dizziness, abdominal cramps, vomiting, bloody diarrhea, weakness, and convulsions. Irritating to skin, eyes and respiratory tract. May cause intestinal disorders, convulsions, asphyxia, Acute Health Affects: sensitization dermatitis, allergic asthma and pneumonitis. Prolonged exposure to nickel and nickel compounds may lead to skin irritation and dermatitis, and affect Chronic Health Affects: kidney, liver, and lung function. May cause cancer. NTP:Yes IARC:Yes OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:not applicable Autoignition Temperature:none Explosion Limits:none Extinguishing Medium:carbon dioxide, foam or dry powder If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure Special Fire Fighting Procedures: self- contained breathing apparatus and full protective clothing. Hazardous Combustion andIf involved in a fire this material may emit toxic and corrosive fumes. Decomposion Products: Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and Spill and Leak Procedures: swept up. SECTION 7: Handling and Storage Handling and Storage:Store in a cool, dry place in a tightly sealed container. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear protective clothing and gloves. Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood. If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Respirator: Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:yellow pwdr. Molecular Weight:414.7 Melting Point:no data Boiling Point:no data Vapor Pressure:no data Specific Gravity:2.101 Odor:none Solubility in Water:soluble SECTION 10: Stability and Reactivity Stability:air and moisture stable Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:none Incompatibility:oxidizing agents Decomposition Products:nickel oxide, ammonia, and nickel iodide SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files. Carcinogenic Effects:Carcinogen (as Ni) Mutagenic Effects:No data Tetratogenic Effects:No data SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Non-hazardous Hazard Class (CFR):NA Additional Hazard Class (CFR):NA Packaging Group (CFR):NA UN ID Number (CFR):NA Shipping Name (IATA):Non-hazardous Hazard Class (IATA):NA Additional Hazard Class (IATA):NA Packaging Group (IATA):NA UN ID Number (IATA):NA SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory. SARA (Title 313):Title compound: See category code N495 for reporting. Second Ingredient:None SECTION 16 - ADDITIONAL INFORMATION N/A |
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毒理学数据: 1、急性毒性：主要的刺激性影响： 在皮肤上面：刺激皮肤和粘膜； 在眼睛上面：刺激的影响； 2、致敏作用：通过吸入可能造成敏化作用，通过皮肤接触可能造成敏化作用。 生态学数据: 对水体是极其有害的，即使小量产品也不能接触地下水，水道或污水系统, 若无政府许可，勿将材料排入周围环境
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| 危害码 (欧洲) | T: Toxic; |
|---|---|
| 风险声明 (欧洲) | 45-42/43 |
| 安全声明 (欧洲) | 53-36/37/39-45 |