13637-76-8
13637-76-8结构式
- 常用中文名：高氯酸铅(2+)
- 常用英文名：lead(2+),diperchlorate
- CAS号：13637-76-8
- 分子式：Cl2O8Pb
- 分子量：406.10100
- 发布时间：2018-04-04 08:00:00
- 更新时间：2024-01-14 13:42:53
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用作涂料中的耐腐蚀颜料，制造蓄电池、化学药品。
| 中文名 | 高氯酸铅(2+) |
|---|---|
| 英文名 | lead(2+),diperchlorate |
| 英文别名 |
Lead perchlorate,solid or solution
Lead diperchlorate Lead perchlorate UN1470 EINECS 237-125-7 |
| 分子式 | Cl2O8Pb |
|---|---|
| 分子量 | 406.10100 |
| 精确质量 | 405.87400 |
| PSA | 148.54000 |
| LogP | 0.04780 |
| 储存条件 | 储存注意事项 储存于阴凉、通风的库房。库温不超过30℃，相对湿度不超过80%。远离火种、热源。包装必须密封，切勿受潮。应与易（可）燃物、还原剂、食用化学品分开存放，切忌混储。储区应备有合适的材料收容泄漏物。 |
| 稳定性 | 1.稳定性 稳定 2.禁配物 还原剂、易燃或可燃物 3.避免接触的条件 受热 4.聚合危害 不聚合 5.分解产物 氧化铅 |
| 分子结构 | 1、摩尔折射率：无可用的 2、摩尔体积（cm3/mol）：无可用的 3、等张比容（90.2K）：无可用的 4、表面张力（dyne/cm）：无可用的 5、介电常数：无可用的 6、极化率：无可用的 |
| 计算化学 | 1.疏水参数计算参考值（XlogP）:无 2.氢键供体数量:0 3.氢键受体数量:8 4.可旋转化学键数量:0 5.互变异构体数量:无 6.拓扑分子极性表面积149 7.重原子数量:11 8.表面电荷:0 9.复杂度:95.8 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:3 |
| 更多 | 1.性状：白色斜方结晶，有潮解性。 2.熔点（分解，℃）：100 3.相对密度（水=1）：2.6 4.溶解性：易溶于冷水，溶于乙醇。 |
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Section 1. Chemical Product and Company Identification Lead perchlorateCatalog Common Name/ Number(s). Trade Name CAS#13637-76-8 Manufacturer
RTECSSC8100000 SPECTRUM CHEMICAL MFG. CORP. TSCATSCA 8(b) inventory: Lead perchlorate Commercial Name(s)Not available. CI# Not available. SynonymNot available. IN CASE OF EMERGENCY Chemical Name Chemical FamilyNot available.CALL (310) 516-8000 Pb(ClO4)2.3H2O Chemical Formula SPECTRUM CHEMICAL MFG. CORP. Section 2.Composition and Information on Ingredients Exposure Limits TWA (mg/m3)STEL (mg/m3) CEIL (mg/m3) NameCAS #% by Weight 1) Lead perchlorate13637-76-80.15 0.45 100 Toxicological DataLead perchlorate on IngredientsLD50: Not available. LC50: Not available. Section 3. Hazards Identification Potential Acute Health Effects Extremely hazardous in case of ingestion. Hazardous in case of skin contact (irritant), of eye contact (irritant), of inhalation. Prolonged exposure may result in skin burns and ulcerations. Over-exposure by inhalation may cause respiratory irritation. Severe over-exposure can result in death. Extremely hazardous in case of ingestion. Potential Chronic Health EffectsHazardous in case of skin contact (irritant), of eye contact (irritant), of inhalation. CARCINOGENIC EFFECTS: Classified 2B (Possible for human.) by IARC. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. The substance is toxic to blood, kidneys, the nervous system. Repeated or prolonged exposure to the substance can produce target organs damage. Repeated exposure to an Lead perchlorate highly toxic material may produce general deterioration of health by an accumulation in one or many human organs. Section 4. First Aid Measures Eye ContactCheck for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Cold water may be used. Do not use an eye ointment. Seek medical attention. Skin ContactAfter contact with skin, wash immediately with plenty of water. Gently and thoroughly wash the contaminated skin with running water and non-abrasive soap. Be particularly careful to clean folds, crevices, creases and groin. Cold water may be used. Cover the irritated skin with an emollient. If irritation persists, seek medical attention. Wash contaminated clothing before reusing. Serious Skin ContactWash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate medical attention. InhalationAllow the victim to rest in a well ventilated area. Seek immediate medical attention. Serious InhalationEvacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. If breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. WARNING: It may be hazardous to the person providing aid to give mouth-to-mouth resuscitation when the inhaled material is toxic, infectious or corrosive. Seek immediate medical attention. IngestionDo not induce vomiting. Examine the lips and mouth to ascertain whether the tissues are damaged, a possible indication that the toxic material was ingested; the absence of such signs, however, is not conclusive. Loosen tight clothing such as a collar, tie, belt or waistband. If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek immediate medical attention. Serious IngestionNot available. Section 5. Fire and Explosion Data Flammability of the Product Non-flammable. Auto-Ignition Temperature Not applicable. Flash PointsNot applicable. Flammable LimitsNot applicable. Products of CombustionNot available. Fire Hazards in Presence of Not applicable. Various Substances Explosion Hazards in Presence Risks of explosion of the product in presence of mechanical impact: Not available. of Various SubstancesRisks of explosion of the product in presence of static discharge: Not available. Fire Fighting MediaNot applicable. and Instructions Special Remarks onNot available. Fire Hazards Special Remarks on Explosion Not available. Hazards Lead perchlorate Section 6. Accidental Release Measures Small SpillUse appropriate tools to put the spilled solid in a convenient waste disposal container. Large Spill Oxidizing material. Stop leak if without risk. Avoid contact with a combustible material (wood, paper, oil, clothing...). Keep substance damp using water spray. Do not touch spilled material. Prevent entry into sewers, basements or confined areas; above TLV. Check TLV on the MSDS and with local authorities. Section 7. Handling and Storage PrecautionsKeep locked up Keep away from heat. Keep away from sources of ignition. Keep away from combustible material Do not ingest. Do not breathe dust. Wear suitable protective clothing In case of insufficient ventilation, wear suitable respiratory equipment If ingested, seek medical advice immediately and show the container or the label. Avoid contact with skin and eyes Keep away from incompatibles such as reducing agents, combustible materials, organic materials. StorageKeep container tightly closed. Keep in a cool, well-ventilated place. Highly toxic or infectious materials should be stored in a separate locked safety storage cabinet or room. Section 8. Exposure Controls/Personal Protection Engineering ControlsUse process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit. Personal ProtectionSplash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves. Personal Protection in Case of Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used a Large Spillto avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product. Exposure LimitsTWA: 0.15 CEIL: 0.45 (mg/m3) Consult local authorities for acceptable exposure limits. Section 9. Physical and Chemical Properties Physical state and appearance Solid. (Crystalline solid.)OdorNot available. TasteNot available. Molecular Weight406.09 g/mole White. Color Not available. pH (1% soln/water) Boiling PointNot available. Decomposes. (100°C or 212°F) Melting Point Critical TemperatureNot available. Specific Gravity2.6 (Water = 1) Vapor PressureNot applicable. Vapor DensityNot available. VolatilityNot available. Odor ThresholdNot available. Water/Oil Dist. Coeff.Not available. Ionicity (in Water)Not available. Dispersion PropertiesSee solubility in water, methanol. Lead perchlorate Easily soluble in cold water. Solubility Soluble in methanol. Section 10. Stability and Reactivity Data StabilityThe product is stable. Instability TemperatureNot available. Conditions of InstabilityNot available. Extremely reactive or incompatible with combustible materials, organic materials. Incompatibility with various substancesHighly reactive with reducing agents. Not available. Corrosivity Special Remarks onNot available. Reactivity Not available. Special Remarks on Corrosivity PolymerizationNo. Section 11. Toxicological Information Routes of EntryEye contact. Inhalation. Ingestion. Toxicity to AnimalsLD50: Not available. LC50: Not available. Chronic Effects on Humans CARCINOGENIC EFFECTS: Classified 2B (Possible for human.) by IARC. The substance is toxic to blood, kidneys, the nervous system. Other Toxic Effects onExtremely hazardous in case of ingestion. HumansHazardous in case of skin contact (irritant), of inhalation. Special Remarks onNot available. Toxicity to Animals Special Remarks onNot available. Chronic Effects on Humans Special Remarks on otherNot available. Toxic Effects on Humans Section 12. Ecological Information EcotoxicityNot available. BOD5 and CODNot available. Products of BiodegradationPossibly hazardous short term degradation products are not likely. However, long term degradation products may arise. Toxicity of the ProductsThe products of degradation are more toxic. of Biodegradation Special Remarks on theNot available. Products of Biodegradation Lead perchlorate Section 13. Disposal Considerations Waste Disposal Section 14. Transport Information DOT ClassificationCLASS 5.1: Oxidizing material. : Lead perchlorate : UN1470 PG: II Identification Marine Pollutant Special Provisions for Transport DOT (Pictograms) OXIDIZER 5.1 Section 15. Other Regulatory Information and Pictograms California prop. 65: This product contains the following ingredients for which the State of California has found to Federal and State cause cancer, birth defects or other reproductive harm, which would require a warning under the statute: Lead Regulations perchlorate California prop. 65: This product contains the following ingredients for which the State of California has found to cause reproductive harm (female) which would require a warning under the statute: Lead perchlorate California prop. 65: This product contains the following ingredients for which the State of California has found to cause reproductive harm (male) which would require a warning under the statute: Lead perchlorate California prop. 65: This product contains the following ingredients for which the State of California has found to cause birth defects which would require a warning under the statute: Lead perchlorate California prop. 65: This product contains the following ingredients for which the State of California has found to cause cancer which would require a warning under the statute: Lead perchlorate Pennsylvania RTK: Lead perchlorate Massachusetts RTK: Lead perchlorate TSCA 8(b) inventory: Lead perchlorate SARA 313 toxic chemical notification and release reporting: Lead perchlorate CERCLA: Hazardous substances.: Lead perchlorate CaliforniaCalifornia prop. 65: This product contains the following ingredients for which the State of California has found Proposition 65to cause cancer which would require a warning under the statute: Lead perchlorate Warnings California prop. 65: This product contains the following ingredients for which the State of California has found to cause birth defects which would require a warning under the statute: Lead perchlorate Other Regulations OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). CLASS C: Oxidizing material. Other ClassificationsWHMIS (Canada) CLASS D-1A: Material causing immediate and serious toxic effects (VERY TOXIC). CLASS D-2A: Material causing other toxic effects (VERY TOXIC). DSCL (EEC)R36/38- Irritating to eyes and skin. R40- Possible risks of irreversible effects. Health Hazard HMIS (U.S.A.)2 National Fire Protection 0 Flammability 0 Association (U.S.A.) Fire Hazard 2 0 Reactivity Health Reactivity 0 Specific hazard Personal Protection E Lead perchlorate WHMIS (Canada) (Pictograms) DSCL (Europe) (Pictograms) TDG (Canada) (Pictograms) 5.1 ADR (Europe) (Pictograms) Protective Equipment Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator when ventilation is inadequate. Lead perchlorate All chemicals may pose unknown hazards and should be used with caution. This Material Safety Data Sheet (MSDS) applies only to the material as packaged. If this product is combined with other materials, deteriorates, or becomes contaminated, it may pose hazards not mentioned in this MSDS. It shall be the user's responsibility to develop proper methods of handling and personal protection based on the actual conditions of use. While this MSDS is based on technical data judged to be reliable, Spectrum Quality Products, SECTION 16 - ADDITIONAL INFORMATION N/A |
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毒理学数据: 1.急性毒性 暂无资料 2.刺激性 暂无资料 3.致癌性 IARC致癌性评论：IARC将铅的无机化合物列为G2A，可疑人类致癌物。 生态学数据: 1.生态毒性 暂无资料 2.生物降解性 暂无资料 3.非生物降解性 暂无资料 CHEMICAL IDENTIFICATION
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| 危害码 (欧洲) | O: Oxidizing agent;T: Toxic;N: Dangerous for the environment; |
|---|---|
| 风险声明 (欧洲) | R61 |
| 安全声明 (欧洲) | 53-45-60-61 |
| 危险品运输编码 | UN 1470 |
| 包装等级 | II |
| 危险类别 | 5.1 |