106868-29-5

• 常用中文名：锂离子载体VII
• 常用英文名：6-dodecyl(14-crown-4)-6-ethanol diethylphosphate
• CAS号：106868-29-5
• 分子式：C₂₈H₅₇O₈P
• 分子量：552.72100
• 相关类别： 分析化学 分析试剂 常用分析试剂
• 发布时间：2017-07-13 02:28:53
• 更新时间：2024-01-10 11:18:52

名称

• 中文名: 锂离子载体VII
• 英文名: 2-(6-dodecyl-1,4,8,11-tetraoxacyclotetradec-6-yl)ethyl diethyl phosphate
• 英文别名: 6-Dodecyl(14-crown-4)-6-ethanol diethyl phosphate; Lithium ionophore VII; 6-[2-(Diethylphosphonooxy)ethyl]-6-dodecyl-14-crown-4; diethoxyphosphoryloxyethyl-dodecyl-14-crown-4

物化性质

• 分子式: C₂₈H₅₇O₈P
• 分子量: 552.72100
• 闪点: -4℃
• 精确质量: 552.37900
• PSA: 91.49000
• LogP: 7.34010
• 储存条件: 2-8°C

MSDS

Version 1.2 Regulation (EC) No 1907/2006 1 - Product and Company Information Product NameLITHIUM IONOPHORE VII (10 MG IN 0.1 ML HEPTANE) 2 - Hazards Identification SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT Highly flammable. 3 - Composition/Information on Ingredients Product NameCAS #EC noAnnex I Index Number 6-(2-(DIETH.PHOSPH.OXY)ETH.)6-DODE 106868-29-5 NoneNone CYL-14-CROWN-4 (10MG,SOLUTION) FormulaC28H57O8P Molecular Weight 552,7000 AMU 4 - First Aid Measures AFTER INHALATION If inhaled, remove to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen. AFTER INGESTION If swallowed, wash out mouth with water provided person is conscious. Call a physician. 5 - Fire Fighting Measures EXTINGUISHING MEDIA Suitable: Carbon dioxide, dry chemical powder, or appropriate foam. SPECIAL RISKS Specific Hazard(s): Flammable liquid. Vapor may travel considerable distance to source of ignition and flash back. Explosion Hazards: Vapor may travel considerable distance to FLUKAwww.molbase.com source of ignition and flash back. Container explosion may occur under fire conditions. Forms explosive mixtures in air. SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. SPECIFIC METHOD(S) OF FIRE FIGHTING Use water spray to cool fire-exposed containers. 6 - Accidental Release Measures PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL Evacuate area. Shut off all sources of ignition. PROCEDURE(S) OF PERSONAL PRECAUTION(S) Wear self-contained breathing apparatus, rubber boots, and heavy rubber gloves. METHODS FOR CLEANING UP Cover with an activated carbon adsorbent, take up and place in closed containers. Transport outdoors. Ventilate area and wash spill site after material pickup is complete. 7 - Handling and Storage HANDLING Directions for Safe Handling: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE Conditions of Storage: Keep tightly closed. Keep away from heat, sparks, and open flame. Store in a cool dry place. 8 - Exposure Controls / Personal Protection ENGINEERING CONTROLS Use nonsparking tools. Mechanical exhaust required. GENERAL HYGIENE MEASURES Wash thoroughly after handling. Remove and wash contaminated clothing promptly. PERSONAL PROTECTIVE EQUIPMENT Respiratory Protection: Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Hand Protection: Rubber gloves. Eye Protection: Chemical safety goggles. 9 - Physical and Chemical Properties AppearancePhysical State: Liquid PropertyValueAt Temperature or Pressure FLUKAwww.molbase.com pH N/A BP/BP RangeN/A MP/MP RangeN/A Flash PointN/A FlammabilityN/A Autoignition TempN/A Oxidizing Properties N/A Explosive Properties N/A Explosion LimitsN/A Vapor PressureN/A Partition Coefficient N/A ViscosityN/A Vapor DensityN/A Saturated Vapor Conc. N/A Evaporation RateN/A Bulk DensityN/A Decomposition Temp.N/A Solvent ContentN/A Water ContentN/A Surface TensionN/A ConductivityN/A Miscellaneous DataN/A SolubilityN/A 10 - Stability and Reactivity STABILITY Materials to Avoid: Oxidizing agents. HAZARDOUS DECOMPOSITION PRODUCTS Hazardous Decomposition Products: Carbon monoxide, Carbon dioxide, Phosphorous oxides. HAZARDOUS POLYMERIZATION Hazardous Polymerization: Will not occur 11 - Toxicological Information SIGNS AND SYMPTOMS OF EXPOSURE Narcotic effect. Nausea, dizziness, and headache. Exposure to large amounts can cause: ROUTE OF EXPOSURE Skin Contact: Prolonged or repeated exposure to skin causes defatting and dermatitis. Skin Absorption: May be harmful if absorbed through the skin. Multiple Routes: Vapor or mist is irritating to the eyes, mucous membranes, and upper respiratory tract. Harmful if inhaled or swallowed. 12 - Ecological Information No data available. 13 - Disposal Considerations SUBSTANCE DISPOSAL Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting as this material is FLUKAwww.molbase.com highly flammable. Observe all federal, state, and local environmental regulations. 14 - Transport Information RID/ADR UN#: 1206 Class: 3 PG: II Proper Shipping Name: Heptanes solution IMDG UN#: 1206 Class: 3 PG: II Proper Shipping Name: Heptanes solution Marine Pollutant: No Severe Marine Pollutant: No IATA UN#: 1206 Class: 3 PG: II Proper Shipping Name: Heptanes solution Inhalation Packing Group I: No 15 - Regulatory Information CLASSIFICATION AND LABELING ACCORDING TO EU DIRECTIVES INDICATION OF DANGER: F Highly Flammable. R-PHRASES: 11 Highly flammable. S-PHRASES: 16-23-24/25 Keep away from sources of ignition - no smoking. Do not breathe vapor. Avoid contact with skin and eyes. Caution: Substance not yet fully tested (EU). 16 - Other Information WARRANTY The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. Inc., shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. Copyright 2010 Co. License granted to make unlimitedpaper copies for internal use only. DISCLAIMER For R&D use only. Not for drug, household or other uses. FLUKAwww.molbase.com SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 符号: GHS02, GHS07, GHS08, GHS09
• 信号词: Danger
• 危害声明: H225-H304-H315-H336-H410
• 警示性声明: P210-P261-P273-P301 + P310-P331-P501
• 危害码 (欧洲): F: Flammable;
• 风险声明 (欧洲): 11
• 安全声明 (欧洲): 16-23-24/25
• 危险品运输编码: UN 1206 3/PG 2
• 海关编码: 2932999099

合成路线

92144-75-7 ~% 106868-29-5

文献：Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), , p. 1945 - 1952

106868-14-8 ~% 106868-29-5

文献：Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), , p. 1945 - 1952

106868-24-0 ~% 106868-29-5

文献：Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), , p. 1945 - 1952

814-49-3 106868-27-3 ~16% 106868-29-5

文献：Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), , p. 1945 - 1952

上下游产品

上游产品  2
814-49-3 106868-27-3
下游产品  0

海关

海关编码	2932999099
中文概述	2932999099. 其他仅含氧杂原子的杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%
申报要素	品名, 成分含量, 用途
Summary	2932999099. other heterocyclic compounds with oxygen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%