11070-19-2

• 常用中文名：四(二甲基磺酰)二氯化钌
• 常用英文名：cis-Tetrakis(dimethylsulfoxide)dichlororuthenium(II)
• CAS号：11070-19-2
• 分子式：C₈H₂₄Cl₂O₄RuS₄
• 分子量：484.51000
• 发布时间：2018-07-03 11:42:20
• 更新时间：2024-01-09 11:49:43

名称

• 中文名: 四(二甲基磺酰)二氯化钌
• 英文名: tetrakis(dimethylsulfoxide)dichlororuthenium (ii)
• 英文别名: dichlorotetrakis(dimethylsulfoxide)rutheniumii; dichlorotetrakis(methylsulfoxide)ruthenium; dichlorotetrakis(methylsulfoxide)-rutheniu; dichlorotetrakis(sulfinylbis(methane))-rutheniu; dichlorotetrakis(sulfinylbis(methane))ruthenium; Ruthenium,dichlorotetrakis(methylsulfoxide)

物化性质

• 沸点: 189ºC at 760 mmHg
• 分子式: C₈H₂₄Cl₂O₄RuS₄
• 分子量: 484.51000
• 闪点: 85ºC
• 精确质量: 483.89800
• PSA: 145.12000
• LogP: 4.82060
• 蒸汽压: 0.805mmHg at 25°C
• 储存条件:

  密闭于阴凉干燥环境中

• 稳定性:

  遵照规定使用和储存则不会分解。

• 分子结构:

  1、摩尔折射率：无可用

  2、 摩尔体积（cm³/mol）：无可用

  3、 等张比容（90.2K）：无可用

  4、 表面张力（dyne/cm）：无可用

  5、 极化率：无可用

• 计算化学:

  1.疏水参数计算参考值（XlogP）:无

  2.氢键供体数量:0

  3.氢键受体数量:8

  4.可旋转化学键数量:0

  5.互变异构体数量:无

  6.拓扑分子极性表面积145

  7.重原子数量:19

  8.表面电荷:0

  9.复杂度:31.8

  10.同位素原子数量:0

  11.确定原子立构中心数量:0

  12.不确定原子立构中心数量:0

  13.确定化学键立构中心数量:0

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:5

• 更多:

  1. 性状：无可用

  2. 密度（g/mL,25/4℃）：无可用

  3. 相对蒸汽密度（g/mL,空气=1）：无可用

  4. 熔点（ºC）：无可用

  5. 沸点（ºC,常压）：无可用

  6. 沸点（ºC,5.2kPa）：无可用

  7. 折射率：无可用

  8. 闪点（ºC）：无可用

  9. 比旋光度（º）：无可用

  10. 自燃点或引燃温度（ºC）：无可用

  11. 蒸气压（kPa,25ºC）：无可用

  12. 饱和蒸气压（kPa,60ºC）：无可用

  13. 燃烧热（KJ/mol）：无可用

  14. 临界温度（ºC）：无可用

  15. 临界压力（KPa）：无可用

  16. 油水（辛醇/水）分配系数的对数值：无可用

  17. 爆炸上限（%,V/V）：无可用

  18. 爆炸下限（%,V/V）：无可用

  19. 溶解性：无可用

MSDS

Section 1: Product Identification Chemical Name:cis-Tetrakis(dimethylsulfoxide)dichlororuthenium (II), 98% CAS Registry Number:11070-19-2 Formula:C8H24Cl2O4RuS4 EINECS Number:none Chemical Family: Synonym:Dichlorotetrakis(dimethyl sulfoxide)ruthenium (II), Dichlorotetrakis(methylsulfoxide)ruthenium Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title Compound11070-19-2100%no datano data Section 3: Hazards Identification Emergency Overview:Irritating to skin, eyes and respiratory tract. Possible risk of irreversible effects. Primary Routes of Exposure:Ingestion, eyes Eye Contact:Causes slight to mild irritation of the eyes. Skin Contact:Causes slight to mild irritation of the skin. Inhalation:Irritating to the nose, mucous membranes and respiratory tract. Ingestion:Ingestion may lead to dizziness, abdominal cramps, and vomiting. Acute Health Affects:Irritating to skin, eyes and respiratory tract. Possible risk of irreversible effects. Chronic Health Affects:Possible risk of irreversible effects. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:none Autoignition Temperature:none Explosion Limits:none Extinguishing Medium:carbon dioxide, dry powder or foam Fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus Special Fire Fighting Procedures: and full protective clothing. Hazardous Combustion andIf involved in a fire this material may emit irritating fumes. Decomposion Products: Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures Spill and Leak Procedures:Small spills can be mixed with vermiculite or sodium carbonate and swept up. SECTION 7: Handling and Storage Handling and Storage:Store in a tightly sealed container. Keep away from heat, air and direct sunlight. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove. Ventilation:If possible, handle the material in an efficient fume hood. If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Respirator: Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:If possible, handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:yellow powder Molecular Weight:484.49 Melting Point:no data Boiling Point:no data Vapor Pressure:no data Specific Gravity:no data Odor:none Solubility in Water:insoluble SECTION 10: Stability and Reactivity Stability:air and moisture stable Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:strong oxidizing agents Incompatibility:oxidizing agents, halogens and active metals Decomposition Products:carbon monoxide, carbon dioxide, organic fumes, and ruthenium oxide SECTION 11: Toxicological Information Intraperitoneal (mouse); LD50: 1gm/kg. Mutation in microorganisms (bacteria-Salmonella typhimurium): RTECS Data: 250ug/plate. Cytogenic analysis (hamster ovary); 6mmol/L Carcinogenic Effects:no data Mutagenic Effects:Possible mutagen Tetratogenic Effects:no data SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to federal, state, and local regulations. SECTION 14: Transportation Shipping Name (CFR):Non-hazardous Hazard Class (CFR):NA Additional Hazard Class (CFR):NA Packaging Group (CFR):NA UN ID Number (CFR):NA Shipping Name (IATA):Non-hazardous Hazard Class (IATA):NA Additional Hazard Class (IATA):NA Packaging Group (IATA):NA UN ID Number (IATA):NA SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory. SARA (Title 313):Title compound not listed. Second Ingredient:none SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

生态学数据: 该物质对环境可能有危害，对水体应给予特别注意。 CHEMICAL IDENTIFICATION RTECS NUMBER : VM2651450 CHEMICAL NAME : Ruthenium, dichlorotetrakis(methylsulfoxide)- CAS REGISTRY NUMBER : 11070-19-2 LAST UPDATED : 199410 DATA ITEMS CITED : 4 MOLECULAR FORMULA : C8-H24-Cl2-O4-Ru-S4 MOLECULAR WEIGHT : 484.53 WISWESSER LINE NOTATION : OS1&1 4 &.RU..G2 HEALTH HAZARD DATA ACUTE TOXICITY DATA TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 1 gm/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value MUTATION DATA TYPE OF TEST : Cytogenetic analysis TEST SYSTEM : Rodent - hamster Ovary DOSE/DURATION : 6 mmol/L REFERENCE : CBINA8 Chemico-Biological Interactions. (Elsevier Scientific Pub. Ireland Ltd., POB 85, Limerick, Ireland) V.1- 1969- Volume(issue)/page/year: 59,247,1986

安全

• 风险声明 (欧洲): R36/37/38
• 安全声明 (欧洲): S26-36/37/39