376355-58-7

• 常用中文名：N,N-双((S)-1-苯乙基)二苯并[d,f][1,3,2]二氧杂磷杂环庚三烯-6-胺
• 常用英文名：N,N-Bis((S)-1-phenylethyl)dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine
• CAS号：376355-58-7
• 分子式：C₂₈H₂₆NO₂P
• 分子量：439.48500
• 发布时间：2018-12-23 21:45:54
• 更新时间：2024-01-09 07:17:40

名称

• 中文名: N,N-双-((S)-1-苯基乙基)二苯并[d,f][1,3,2]二氧杂膦-6-胺
• 英文名: N,N-bis[(1S)-1-phenylethyl]benzo[d][1,3,2]benzodioxaphosphepin-6-amine
• 英文别名: MFCD08277033

物化性质

• 沸点: 578.426ºC at 760 mmHg
• 熔点: 99-102ºC
• 分子式: C₂₈H₂₆NO₂P
• 分子量: 439.48500
• 闪点: 303.621ºC
• 精确质量: 439.17000
• PSA: 29.52000
• LogP: 8.75040
• 储存条件: 2-8°C，密闭，干燥

MSDS

Section 1: Product Identification Chemical Name:N,N-Bis[(1S)-(-)-phenylethyl]dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine CAS Registry Number:376355-58-7 Formula:C28H26NO2P EINECS Number:none Chemical Family:phosphine-amine ligand Synonym:(5,7-Dioxa-6-phospha-dibenzo[a,c]cyclohepten-6-yl)-bis-(1(S)-(-)--phenyl-ethyl)-amine Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title compound376355-58-7100%no datano data Section 3: Hazards Identification Emergency Overview:Irritating to skin, eyes and respiratory tract. Primary Routes of Exposure:Ingestion, inhalation Eye Contact:Causes slight to mild irritation of the eyes. Skin Contact:Causes slight to mild irritation of the skin. Inhalation:Irritating to the nose, mucous membranes and respiratory tract. Ingestion:No information available on the physiological effects of ingestion. May be harmful if swallowed. Acute Health Affects:Irritating to skin. Dust may be irritating to eyes and respiratory tract. Chronic Health Affects:No information on long-term chronic effects. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:none Autoignition Temperature:none Explosion Limits:none Extinguishing Medium:carbon dioxide, dry powder or foam If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure Special Fire Fighting Procedures: self-contained breathing apparatus and full protective clothing. Hazardous Combustion andIf involved in a fire this material may emit irritating fumes. Decomposion Products: Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures Spill and Leak Procedures:Small spills can be mixed with vermiculite or sodium carbonate and swept up. SECTION 7: Handling and Storage The material will degrade on prolonged exposure to moisture. Store under an inert atmosphere of nitrogen or Handling and Storage: argon. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear protective clothing and gloves. Ventilation:Handle the material in an efficient fume hood. If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Respirator: Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:Handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:white powder Molecular Weight:439.49 Melting Point:no data Boiling Point:no data Vapor Pressure:no data Specific Gravity:no data Odor:none Solubility in Water:insoluble SECTION 10: Stability and Reactivity Stability:moisture sensitive Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:prolonged exposure to moisture Incompatibility:oxidizing agents and halogens Decomposition Products:carbon dioxide, carbon monoxide, organic fumes, phosphorus oxides. SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files. Carcinogenic Effects:no data Mutagenic Effects:no data Tetratogenic Effects:no data SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Non-hazardous Hazard Class (CFR):NA Additional Hazard Class (CFR):NA Packaging Group (CFR):NA UN ID Number (CFR):NA Shipping Name (IATA):Non-hazardous Hazard Class (IATA):NA Additional Hazard Class (IATA):NA Packaging Group (IATA):NA UN ID Number (IATA):NA SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory SARA (Title 313):Title compound not listed Second Ingredient:none SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 危害码 (欧洲): Xi

合成路线

16611-68-0 21003-56-5 ~91% 376355-58-7

文献：Smith, Craig R.; Rajanbabu Organic Letters, 2008 , vol. 10, # 8 p. 1657 - 1659

1806-29-7 21003-56-5 ~% 376355-58-7

文献：Alexakis; Rosset; Allamand; March; Guillen; Benhaim Synlett, 2001 , # 9 p. 1375 - 1378 Title/Abstract Full Text View citing articles Show Details D'Augustin, Magali; Palais, Laeticia; Alexakis, Alexandre Angewandte Chemie - International Edition, 2005 , vol. 44, # 9 p. 1376 - 1378

1806-29-7 777067-25-1 ~% 376355-58-7

文献：Bournaud, Chloee; Falciola, Caroline; Thomas-Lecourt; Rosset, Stephane; Alexakis, Alexandre; Micouin, Laurent Organic Letters, 2006 , vol. 8, # 16 p. 3581 - 3584

21003-56-5 ~% 376355-58-7

文献：Monti, Chiara; Gennari, Cesare; Piarulli, Umberto Chemistry - A European Journal, 2007 , vol. 13, # 5 p. 1547 - 1558

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