376355-58-7

376355-58-7 structure
376355-58-7 structure

Name N,N-bis[(1S)-1-phenylethyl]benzo[d][1,3,2]benzodioxaphosphepin-6-amine
Synonyms MFCD08277033
Boiling Point 578.426ºC at 760 mmHg
Melting Point 99-102ºC
Molecular Formula C28H26NO2P
Molecular Weight 439.48500
Flash Point 303.621ºC
Exact Mass 439.17000
PSA 29.52000
LogP 8.75040

Section 1: Product Identification
Chemical Name:N,N-Bis[(1S)-(-)-phenylethyl]dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine
CAS Registry Number:376355-58-7
Formula:C28H26NO2P
EINECS Number:none
Chemical Family:phosphine-amine ligand
Synonym:(5,7-Dioxa-6-phospha-dibenzo[a,c]cyclohepten-6-yl)-bis-(1(S)-(-)--phenyl-ethyl)-amine

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title compound376355-58-7100%no datano data

Section 3: Hazards Identification
Emergency Overview:Irritating to skin, eyes and respiratory tract.
Primary Routes of Exposure:Ingestion, inhalation
Eye Contact:Causes slight to mild irritation of the eyes.
Skin Contact:Causes slight to mild irritation of the skin.
Inhalation:Irritating to the nose, mucous membranes and respiratory tract.
Ingestion:No information available on the physiological effects of ingestion. May be harmful if swallowed.
Acute Health Affects:Irritating to skin. Dust may be irritating to eyes and respiratory tract.
Chronic Health Affects:No information on long-term chronic effects.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:none
Autoignition Temperature:none
Explosion Limits:none
Extinguishing Medium:carbon dioxide, dry powder or foam
If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
Special Fire Fighting Procedures:
self-contained breathing apparatus and full protective clothing.
Hazardous Combustion andIf involved in a fire this material may emit irritating fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Spill and Leak Procedures:Small spills can be mixed with vermiculite or sodium carbonate and swept up.

SECTION 7: Handling and Storage
The material will degrade on prolonged exposure to moisture. Store under an inert atmosphere of nitrogen or
Handling and Storage:
argon.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing and gloves.
Ventilation:Handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:Handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:white powder
Molecular Weight:439.49
Melting Point:no data
Boiling Point:no data
Vapor Pressure:no data
Specific Gravity:no data
Odor:none
Solubility in Water:insoluble

SECTION 10: Stability and Reactivity
Stability:moisture sensitive
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:prolonged exposure to moisture
Incompatibility:oxidizing agents and halogens
Decomposition Products:carbon dioxide, carbon monoxide, organic fumes, phosphorus oxides.

SECTION 11: Toxicological Information
RTECS Data:No information available in the RTECS files.
Carcinogenic Effects:no data
Mutagenic Effects:no data
Tetratogenic Effects:no data

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:Not listed in the TSCA inventory
SARA (Title 313):Title compound not listed
Second Ingredient:none


SECTION 16 - ADDITIONAL INFORMATION
N/A
Hazard Codes Xi

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376355-58-7 structure

376355-58-7

Literature: Smith, Craig R.; Rajanbabu Organic Letters, 2008 , vol. 10, # 8 p. 1657 - 1659

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376355-58-7 structure

376355-58-7

Literature: Alexakis; Rosset; Allamand; March; Guillen; Benhaim Synlett, 2001 , # 9 p. 1375 - 1378 Title/Abstract Full Text View citing articles Show Details D'Augustin, Magali; Palais, Laeticia; Alexakis, Alexandre Angewandte Chemie - International Edition, 2005 , vol. 44, # 9 p. 1376 - 1378

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376355-58-7 structure

376355-58-7

Literature: Bournaud, Chloee; Falciola, Caroline; Thomas-Lecourt; Rosset, Stephane; Alexakis, Alexandre; Micouin, Laurent Organic Letters, 2006 , vol. 8, # 16 p. 3581 - 3584

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376355-58-7 structure

376355-58-7

Literature: Monti, Chiara; Gennari, Cesare; Piarulli, Umberto Chemistry - A European Journal, 2007 , vol. 13, # 5 p. 1547 - 1558
Precursor  3

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